{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T21:22:50Z","timestamp":1790112170716,"version":"4.0.1"},"reference-count":47,"publisher":"American Chemical Society (ACS)","issue":"15","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Environ. Sci. Technol."],"published-print":{"date-parts":[[2009,8,1]]},"DOI":"10.1021\/es9006433","type":"journal-article","created":{"date-parts":[[2009,7,8]],"date-time":"2009-07-08T17:52:03Z","timestamp":1247075523000},"page":"5619-5625","source":"Crossref","is-referenced-by-count":69,"title":["Atacama Perchlorate as an Agricultural Contaminant in Groundwater: Isotopic and Chronologic Evidence from Long Island, New York"],"prefix":"10.1021","volume":"43","author":[{"given":"John Karl","family":"B\u00f6hlke","sequence":"first","affiliation":[{"name":"U.S. Geological Survey, 431 National Center, Reston, Virginia 20192, Shaw Environmental, Inc., Lawrenceville, New Jersey 08648, Department of Earth and Environmental Sciences, University of Illinois at Chicago, Chicago, Illinois 60607, Environmental Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37381, and U.S. Geological Survey, Coram, New York 11727"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Paul B.","family":"Hatzinger","sequence":"additional","affiliation":[{"name":"U.S. Geological Survey, 431 National Center, Reston, Virginia 20192, Shaw Environmental, Inc., Lawrenceville, New Jersey 08648, Department of Earth and Environmental Sciences, University of Illinois at Chicago, Chicago, Illinois 60607, Environmental Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37381, and U.S. Geological Survey, Coram, New York 11727"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Neil C.","family":"Sturchio","sequence":"additional","affiliation":[{"name":"U.S. Geological Survey, 431 National Center, Reston, Virginia 20192, Shaw Environmental, Inc., Lawrenceville, New Jersey 08648, Department of Earth and Environmental Sciences, University of Illinois at Chicago, Chicago, Illinois 60607, Environmental Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37381, and U.S. Geological Survey, Coram, New York 11727"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Baohua","family":"Gu","sequence":"additional","affiliation":[{"name":"U.S. Geological Survey, 431 National Center, Reston, Virginia 20192, Shaw Environmental, Inc., Lawrenceville, New Jersey 08648, Department of Earth and Environmental Sciences, University of Illinois at Chicago, Chicago, Illinois 60607, Environmental Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37381, and U.S. Geological Survey, Coram, New York 11727"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Irene","family":"Abbene","sequence":"additional","affiliation":[{"name":"U.S. Geological Survey, 431 National Center, Reston, Virginia 20192, Shaw Environmental, Inc., Lawrenceville, New Jersey 08648, Department of Earth and Environmental Sciences, University of Illinois at Chicago, Chicago, Illinois 60607, Environmental Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37381, and U.S. Geological Survey, Coram, New York 11727"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Stanley J.","family":"Mroczkowski","sequence":"additional","affiliation":[{"name":"U.S. Geological Survey, 431 National Center, Reston, Virginia 20192, Shaw Environmental, Inc., Lawrenceville, New Jersey 08648, Department of Earth and Environmental Sciences, University of Illinois at Chicago, Chicago, Illinois 60607, Environmental Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37381, and U.S. Geological Survey, Coram, New York 11727"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2009,7,8]]},"reference":[{"issue":"1","key":"ref1\/cit1","doi-asserted-by":"crossref","first-page":"4","DOI":"10.1016\/j.aca.2006.03.047","volume":"567","author":"Kirk A. B.","year":"2006","journal-title":"Anal. Chim. Acta"},{"key":"ref2\/cit2","doi-asserted-by":"crossref","first-page":"6608","DOI":"10.1021\/es061321z","volume":"40","author":"Dasgupta P. K.","year":"2006","journal-title":"Environ. Sci. Technol."},{"key":"ref3\/cit3","doi-asserted-by":"crossref","first-page":"616","DOI":"10.1021\/es801737u","volume":"43","author":"Rajagopalan S.","year":"2009","journal-title":"Environ. Sci. Technol."},{"key":"ref4\/cit4","doi-asserted-by":"crossref","first-page":"4522","DOI":"10.1021\/es062853i","volume":"41","author":"Rao B.","year":"2007","journal-title":"Environ. Sci. Technol."},{"key":"ref5\/cit5","doi-asserted-by":"crossref","first-page":"1757","DOI":"10.1021\/es051739h","volume":"40","author":"Plummer L. N.","year":"2006","journal-title":"Environ. Sci. Technol."},{"key":"ref6\/cit6","doi-asserted-by":"crossref","first-page":"3156","DOI":"10.1021\/es052155i","volume":"40","author":"Rajagopalan S.","year":"2006","journal-title":"Environ. Sci. Technol."},{"key":"ref7\/cit7","doi-asserted-by":"crossref","first-page":"5073","DOI":"10.1021\/es049516z","volume":"38","author":"Bao H.","year":"2004","journal-title":"Environ. Sci. Technol."},{"key":"ref8\/cit8","doi-asserted-by":"crossref","first-page":"7838","DOI":"10.1021\/ac051360d","volume":"77","author":"B\u00f6hlke J. K.","year":"2005","journal-title":"Anal. Chem."},{"key":"ref9\/cit9","doi-asserted-by":"crossref","first-page":"93","DOI":"10.1007\/0-387-31113-0_5","volume-title":"Perchlorate: Environmental Occurrence, Interactions and Treatment","author":"Sturchio N. C.","year":"2006"},{"key":"ref10\/cit10","first-page":"13","volume-title":"Long Island Ground-Water Symposium","author":"Pokorny J. M.","year":"2003"},{"key":"ref11\/cit11","unstructured":"Schubert, C. E.; Bova, R. G.; Misut, P. E.Hydrogeologic Framework of the North Fork and Surrounding Areas, Long Island, New York;U.S. Geological Survey Water-Resources Investigations Report 02\u22124284;U.S. Geological Survey:Coram, NY, 2004; p24."},{"key":"ref12\/cit12","doi-asserted-by":"crossref","unstructured":"Bohn-Buxton, D. E.; Buxton, H. T.; Eagen, V. K.Simulation of Ground-Water Flow Paths and Traveltime in Relation to Tritium and Aldicarb Concentrations in the Upper Glacial Aquifer on the North Fork, Long Island, New York.;U.S. Geological Survey Open-File Report 95\u2212761;U.S. Geological Survey:Coram, NY, 1996; p36.","DOI":"10.3133\/ofr95761"},{"issue":"10","key":"ref13\/cit13","first-page":"1","volume":"38","author":"B\u00f6hlke J. K.","year":"2002","journal-title":"Water Resour. Res."},{"key":"ref14\/cit14","doi-asserted-by":"crossref","first-page":"2319","DOI":"10.1029\/95WR01584","volume":"31","author":"B\u00f6hlke J. K.","year":"1995","journal-title":"Water Resour. Res."},{"key":"ref15\/cit15","doi-asserted-by":"crossref","first-page":"152","DOI":"10.1016\/j.apgeochem.2006.08.019","volume":"22","author":"B\u00f6hlke J. K.","year":"2007","journal-title":"Appl. Geochem."},{"key":"ref16\/cit16","doi-asserted-by":"crossref","first-page":"44","DOI":"10.1071\/EN09008","volume":"6","author":"Hatzinger P. B.","year":"2009","journal-title":"Environ. Chem."},{"key":"ref17\/cit17","volume-title":"Chemistry of Pyrotechnics. Basic Principles and Theory","author":"Conklin J. A.","year":"1985"},{"key":"ref18\/cit18","doi-asserted-by":"crossref","first-page":"4023","DOI":"10.1016\/j.gca.2004.04.009","volume":"68","author":"Michalski G.","year":"2004","journal-title":"Geochim. Cosmochim. Acta"},{"key":"ref19\/cit19","doi-asserted-by":"crossref","first-page":"135","DOI":"10.1016\/S0009-2541(96)00124-6","volume":"136","author":"B\u00f6hlke J. K.","year":"1997","journal-title":"Chem. Geol."},{"key":"ref20\/cit20","doi-asserted-by":"crossref","first-page":"569","DOI":"10.1038\/nrmicro926","volume":"2","author":"Coates J. D.","year":"2004","journal-title":"Nat. Rev., Microbiol."},{"key":"ref21\/cit21","doi-asserted-by":"crossref","first-page":"65","DOI":"10.1080\/10889860902902016","volume":"13","author":"Farhan Y.","year":"2009","journal-title":"Biorem. J."},{"key":"ref22\/cit22","doi-asserted-by":"crossref","unstructured":"Cook, P. G.; Herczeg, A. L.Environmental Tracers in Subsurface Hydrology;Kluwer Academic Publishers:Boston, 2000; p529.","DOI":"10.1007\/978-1-4615-4557-6"},{"key":"ref23\/cit23","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1007\/978-1-4615-4557-6","volume-title":"Environmental Tracers in Subsurface Hydrology","author":"Cook P. G.","year":"2000"},{"key":"ref24\/cit24","unstructured":"Misut, P. E.; Schubert, C. E.; Bova, R. G.; Colabufo, S. R.Simulated Effects of Pumping and Drought on Ground-Water Levels and the Freshwater-Saltwater Interface on the North Fork, Long Island, New York;U.S. Geological Survey Water-Resources Investigations Report 03\u22124184;U.S. Geological Survey:Coram, NY, 2004; p58."},{"key":"ref25\/cit25","doi-asserted-by":"crossref","first-page":"145","DOI":"10.1016\/0022-1694(85)90190-8","volume":"79","author":"Steenhuis T. S.","year":"1985","journal-title":"J. Hydrol."},{"key":"ref26\/cit26","unstructured":"Eckhardt, D. A.; Flipse, W. J.; Oaksford, E. T.Relation between Land Use and Ground-Water Quality in the Upper Glacial aquifer in Nassau and Suffolk Counties, Long Island, New York;U.S. Geological Survey Water Resources Investigations Report 86\u22124142;U.S. Geological Survey:Syosset, NY, 1989; p35."},{"key":"ref27\/cit27","doi-asserted-by":"crossref","unstructured":"LeaMond, C. E.; Haefner, R. J.; Cauller, S. J.; Stackelberg, P. E.Ground-water Quality in Five Areas of Differing Land Use in Nassau and Suffolk Counties, Long Island, New York, 1987\u221288;U.S. Geological Survey Open-File Report 91\u2212180;U.S. Geological Survey:Syosset, NY, 1992; p67.","DOI":"10.3133\/ofr91180"},{"key":"ref28\/cit28","doi-asserted-by":"crossref","unstructured":"Pearsall, K. A.Comparison of Native Ground-Water Quality with Water Quality in Agricultural and Residential Areas of Long Island, New York;U.S. Geological Survey Open-File Report 95\u2212401;U.S. Geological Survey:Coram, NY, 1996; p11.","DOI":"10.3133\/ofr95401"},{"key":"ref29\/cit29","doi-asserted-by":"crossref","first-page":"217","DOI":"10.1111\/j.1745-6584.1995.tb00276.x","volume":"33","author":"Hamilton P. A.","year":"1995","journal-title":"Ground Water"},{"key":"ref30\/cit30","unstructured":"B\u00f6hlke, J. K.Sources, Transport, and Reaction of Nitrate in Ground Water. InResidence Times and Nitrate Transport in Ground Water Discharging to Streams in the Chesapeake Bay Watershed;\u2009U.S. Geological Survey Water Resources Investigations Report 03\u22124035;Lindsey, B. D., Ed.U.S. Geological Survey:New Cumberland, PA, 2003; p.25\u221239."},{"key":"ref31\/cit31","unstructured":"NASS. Census of Agriculture;National Agricultural Statistics Service:Washington, D.C., 2007."},{"key":"ref32\/cit32","doi-asserted-by":"crossref","unstructured":"Ruddy, B. C.; Lorenz, D. L.; Mueller, D. K.County-Level Estimates of Nutrient Inputs to the Land Surface of the Conterminous United States, 1982\u22122001;U.S. Geological Survey Scientific Investigations Report 2006\u22125012;U.S. Geological Survey:Reston, VA, 2006; p17.","DOI":"10.3133\/sir20065012"},{"key":"ref33\/cit33","unstructured":"Lindsey, B. D.; Phillips, S. W.; Donnelly, C. A.; Speiran, G. K.; Plummer, L. N.; B\u00f6hlke, J. K.; Focazio, M. J.; Burton, W. C.; Busenberg, E.,Residence Times and Nitrate Transport in Ground Water Discharging to Streams in the Chesapeake Bay Watershed;U.S. Geological Survey Water-Resources Investigations Report 03\u22124035;U.S. Geological Survey:New Cumberland, PA, 2003; p201."},{"key":"ref34\/cit34","doi-asserted-by":"crossref","first-page":"137","DOI":"10.1111\/j.1745-6592.2005.0009.x","volume":"25","author":"Jackson W. A.","year":"2005","journal-title":"Ground Water Monit. Rem."},{"key":"ref35\/cit35","first-page":"149","author":"Munster J.","year":"2008","journal-title":"Water, Air, Soil Pollut."},{"key":"ref36\/cit36","doi-asserted-by":"crossref","first-page":"3469","DOI":"10.1021\/es990577k","volume":"33","author":"Susarla S.","year":"1999","journal-title":"Environ. Sci. Technol."},{"key":"ref37\/cit37","doi-asserted-by":"crossref","first-page":"224","DOI":"10.1021\/es992029c","volume":"34","author":"Susarla S.","year":"2000","journal-title":"Environ. Sci. Technol."},{"key":"ref38\/cit38","doi-asserted-by":"crossref","first-page":"4452","DOI":"10.1021\/es0011515","volume":"34","author":"Urbansky E. T.","year":"2000","journal-title":"Environ. Sci. Technol."},{"key":"ref39\/cit39","doi-asserted-by":"crossref","unstructured":"Orris, G. J.; Harvey, G. J.; Tsui, D. T.; Eldridge, J. E.Preliminary Analyses for Perchlorate in Selected Natural Materials and Their Derivative Products;U.S. Geological Survey Open-File Report 03\u2212314;U.S. Geological Survey:Reston, VA, 2003; p6.","DOI":"10.3133\/ofr03314"},{"key":"ref40\/cit40","unstructured":"Urbansky, E. T.; Collette, T. W.; Robarge, W. P.; Hall, W. L.; Skillen, J. M.; Kane, P. F.Survey of Fertilizers and Related Materials for Perchlorate (ClO4\u2212;EPA\/600\/R-01\/046;U.S. Environmental Protection Agency:Cincinnati, OH, 2001; p26."},{"key":"ref41\/cit41","first-page":"153","volume":"10","author":"B\u00f6hlke J. K.","year":"2002","journal-title":"Hydrol. J."},{"key":"ref42\/cit42","doi-asserted-by":"crossref","first-page":"2796","DOI":"10.1021\/es0621849","volume":"41","author":"Sturchio N. C.","year":"2007","journal-title":"Environ. Sci. Technol."},{"key":"ref43\/cit43","doi-asserted-by":"crossref","first-page":"2533","DOI":"10.4319\/lo.2008.53.6.2533","volume":"53","author":"Granger J.","year":"2008","journal-title":"Limnol. Oceanogr."},{"key":"ref44\/cit44","doi-asserted-by":"crossref","first-page":"413","DOI":"10.1016\/0022-1694(90)90068-9","volume":"114","author":"B\u00f6ttcher J.","year":"1990","journal-title":"J. Hydrol."},{"key":"ref45\/cit45","doi-asserted-by":"crossref","unstructured":"Alexander, R. B.; Smith, R. A.County-Level Estimates of Nitrogen and Phosphorus Use in the United States;U.S. Geological Survey Open-File Report 90\u2212130;U.S. Geological Survey:Reston, VA, 1990; p12.","DOI":"10.3133\/ofr90130"},{"key":"ref46\/cit46","unstructured":"USDA-ERS. Fertilizer Consumption and Use by Year;U.S. Department of Agriculture, Economic Research Service:Washington, D.C., 2007."},{"key":"ref47\/cit47","unstructured":"Freeze, R. A.; Cherry, J. A.Groundwater;Prentice-Hall: Englewood Cliffs,NJ, 1979."}],"container-title":["Environmental Science &amp; Technology"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/es9006433","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,3,7]],"date-time":"2023-03-07T10:16:33Z","timestamp":1678184193000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/es9006433"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2009,7,8]]},"references-count":47,"journal-issue":{"issue":"15","published-print":{"date-parts":[[2009,8,1]]}},"alternative-id":["10.1021\/es9006433"],"URL":"https:\/\/doi.org\/10.1021\/es9006433","relation":{},"ISSN":["0013-936X","1520-5851"],"issn-type":[{"value":"0013-936X","type":"print"},{"value":"1520-5851","type":"electronic"}],"subject":[],"published":{"date-parts":[[2009,7,8]]}}}