{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,24]],"date-time":"2026-02-24T11:32:42Z","timestamp":1771932762614,"version":"3.50.1"},"reference-count":19,"publisher":"American Chemical Society (ACS)","issue":"24","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Inorg. Chem."],"published-print":{"date-parts":[[2004,11,1]]},"DOI":"10.1021\/ic0489589","type":"journal-article","created":{"date-parts":[[2004,11,22]],"date-time":"2004-11-22T05:22:09Z","timestamp":1101100929000},"page":"7576-7578","source":"Crossref","is-referenced-by-count":69,"title":["Superloading of Tin Ligands into Rhodium and Iridium Carbonyl Cluster Complexes"],"prefix":"10.1021","volume":"43","author":[{"given":"Richard D.","family":"Adams","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Burjor","family":"Captain","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jack L.","family":"Smith","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Michael B.","family":"Hall","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chad L.","family":"Beddie","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Charles Edwin","family":"Webster","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"316","published-online":{"date-parts":[[2004,10,23]]},"reference":[{"key":"ic0489589b00001\/ic0489589b00001_1","doi-asserted-by":"crossref","first-page":"11","DOI":"10.1021\/cr00091a002","volume":"89","author":"Holt M. S.","year":"1989","journal-title":"Chem. Rev."},{"key":"ic0489589b00001\/ic0489589b00001_2","doi-asserted-by":"crossref","first-page":"45","DOI":"10.1016\/S0926-860X(99)00525-6","volume":"199","author":"Coup\u00e9 J. N.","year":"2000","journal-title":"J. Appl. Catal. A"},{"key":"ic0489589b00002\/ic0489589b00002_1","doi-asserted-by":"crossref","first-page":"1211","DOI":"10.1002\/1521-3773(20010401)40:7<1211::AID-ANIE1211>3.0.CO;2-P","volume":"40","author":"Hermans S.","year":"2001","journal-title":"Angew. Chem., Int. Ed."},{"key":"ic0489589b00003\/ic0489589b00003_1","doi-asserted-by":"crossref","first-page":"1955","DOI":"10.1039\/b004585n","author":"Hermans S.","year":"2000","journal-title":"Chem. Commun."},{"key":"ic0489589b00004\/ic0489589b00004_1","first-page":"71","volume-title":"Metal Clusters in Chemistry","volume":"1","author":"Cardin D.","year":"1999"},{"key":"ic0489589b00005\/ic0489589b00005_1","doi-asserted-by":"crossref","first-page":"2302","DOI":"10.1021\/ic011321u","volume":"41","author":"Adams R. D.","year":"2002","journal-title":"Inorg. Chem."},{"key":"ic0489589b00006\/ic0489589b00006_1","unstructured":"Ph3SnH (210 mg, 0.60 mmol) was allowed to react with Rh4(CO)12(30 mg, 0.040 mmol) in hexane (50 mL) for 2 h at 25 \u00b0C. The color turned from red to brown. Cooling to \u221280 \u00b0C yielded a red precipitate that was collected by filtration and recrystallized from hexane\/ CH2Cl2to give 80.0 mg (85%) of bright red1. Spectral data for1:\u2009 IR \u03bdCO(CH2Cl2, cm-1) 2026 (m), 2002 (s);1H NMR (CD2Cl2, ppm) \u03b4 = 7.40 (t, 6H, Ph), 7.19 (t, 12H, Ph), 7.00 (d, 12H, Ph), 6.94 (t, 9H, Ph), 6.80 (d, 18H, Ph), 6.80 (t, 18H, Ph). A mixture of Ph3SnH (100 mg, 0.28 mmol) and Ir4(CO)12(15 mg, 0.014 mmol) in 20 mL of octane was heated to reflux for 5 h. The product was separated by TLC by using a 2:1 hexane\/methylene chloride solvent mixture to give 12.6 mg of orange2in 27% yield. Spectral data for2:\u2009 IR \u03bdCO(CH2Cl2, cm-1) 2032 (m), 1999 (s);1H NMR (CD2Cl2, ppm) \u03b4 = 7.40 (t, 6H, Ph), 7.20 (t, 12H, Ph), 6.99 (d, 12H, Ph), 6.95 (t, 9H, Ph), 6.85 (d, 18H, Ph), 6.75 (t, 18H, Ph)."},{"key":"ic0489589b00008\/ic0489589b00008_1","doi-asserted-by":"crossref","first-page":"39","DOI":"10.1023\/A:1009000428525","volume":"11","author":"Farrugia L. J.","year":"2000","journal-title":"J. Cluster Sci."},{"key":"ic0489589b00009\/ic0489589b00009_1","doi-asserted-by":"crossref","first-page":"3528","DOI":"10.1021\/ic50190a040","volume":"17","author":"Churchill M. R.","year":"1978","journal-title":"Inorg. Chem."},{"key":"ic0489589b00010\/ic0489589b00010_1","doi-asserted-by":"crossref","first-page":"768","DOI":"10.1021\/ic50110a022","volume":"11","author":"Hall M. B.","year":"1972","journal-title":"Inorg. Chem."},{"key":"ic0489589b00010\/ic0489589b00010_2","volume-title":"JIMP Development Version 0.1 (built for Windows PC and Redhat Linux 7.3)","author":"Manson J.","year":"2003"},{"key":"ic0489589b00010\/ic0489589b00010_3","volume-title":"version 2.0","author":"Lichtenberger D. L.","year":"1993"},{"key":"ic0489589b00011\/ic0489589b00011_1","volume-title":"Spectral data for 3:\u2009 IR \u03bdCO (CH2Cl2, cm-1) 1976 (s)","author":"Ph"},{"key":"ic0489589b00012\/ic0489589b00012_1","unstructured":"Crystal data for3\u00b71\/4C6H14:\u2009Mr= 2388.52, triclinic, space groupP1\u0304,a= 14.3214(8) \u00c5,b= 24.7842(13) \u00c5,c= 27.6995(15) \u00c5, \u03b1 = 86.430(1)\u00b0, \u03b2 = 87.730(1)\u00b0, \u03b3 = 89.733(1)\u00b0,V= 9805.0(9) \u00c53,Z= 4,T= 296 \u00b0C, Mo K\u03b1 = 0.71073 \u00c5,\u03bc= 6.23 mm, R1(F2) = 0.0894 for 19923 reflectionsI> 2\u03c3(I)."},{"key":"ic0489589b00013\/ic0489589b00013_1","doi-asserted-by":"crossref","first-page":"5593","DOI":"10.1021\/ic0204169","volume":"41","author":"Adams R. D.","year":"2002","journal-title":"Inorg. Chem."},{"key":"ic0489589b00014\/ic0489589b00014_1","doi-asserted-by":"crossref","first-page":"1142","DOI":"10.1021\/ja00056a045","volume":"115","author":"Zebrowski J. P.","year":"1993","journal-title":"J. Am. Chem. Soc."},{"key":"ic0489589b00015\/ic0489589b00015_1","doi-asserted-by":"crossref","first-page":"20","DOI":"10.1021\/ar990017q","volume":"36","author":"Thomas J. M.","year":"2003","journal-title":"Acc. Chem. Res."},{"key":"ic0489589b00015\/ic0489589b00015_2","unstructured":"(b) Braunstein, P.; Rose, J. InCatalysis byDi- and Polynuclear Metal Cluster Complexes; Adams, R. D., Cotton, F. A., Eds.; VCH:\u2009 New York, 1998; Chapter 13, p 443."},{"key":"ic0489589b00015\/ic0489589b00015_3","doi-asserted-by":"crossref","first-page":"1179","DOI":"10.1039\/a805753b","author":"Toshima N.","year":"1998","journal-title":"New J. Chem."}],"container-title":["Inorganic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/ic0489589","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2021,10,17]],"date-time":"2021-10-17T03:48:18Z","timestamp":1634442498000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/ic0489589"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2004,10,23]]},"references-count":19,"journal-issue":{"issue":"24","published-print":{"date-parts":[[2004,11,1]]}},"alternative-id":["10.1021\/ic0489589"],"URL":"https:\/\/doi.org\/10.1021\/ic0489589","relation":{},"ISSN":["0020-1669","1520-510X"],"issn-type":[{"value":"0020-1669","type":"print"},{"value":"1520-510X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2004,10,23]]}}}