{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,9]],"date-time":"2026-03-09T03:11:33Z","timestamp":1773025893286,"version":"3.50.1"},"reference-count":56,"publisher":"American Chemical Society (ACS)","issue":"21","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Inorg. Chem."],"published-print":{"date-parts":[[2004,10,1]]},"DOI":"10.1021\/ic049474f","type":"journal-article","created":{"date-parts":[[2004,10,11]],"date-time":"2004-10-11T04:24:00Z","timestamp":1097468640000},"page":"6786-6792","source":"Crossref","is-referenced-by-count":46,"title":["Terminal Titanium-Ligand Multiple Bonds. Cleavages of CO and CS Double Bonds with Ti Imido Complexes"],"prefix":"10.1021","volume":"43","author":[{"given":"Shih-Hsien","family":"Hsu","sequence":"first","affiliation":[{"name":"Department of Chemistry, National Changhua University of Education, Changhua, Taiwan 500, and Department of Chemistry, National Taiwan University, Taipei, Taiwan 106"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jr-Chiuan","family":"Chang","sequence":"additional","affiliation":[{"name":"Department of Chemistry, National Changhua University of Education, Changhua, Taiwan 500, and Department of Chemistry, National Taiwan University, Taipei, Taiwan 106"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chun-Liang","family":"Lai","sequence":"additional","affiliation":[{"name":"Department of Chemistry, National Changhua University of Education, Changhua, Taiwan 500, and Department of Chemistry, National Taiwan University, Taipei, Taiwan 106"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ching-Han","family":"Hu","sequence":"additional","affiliation":[{"name":"Department of Chemistry, National Changhua University of Education, Changhua, Taiwan 500, and Department of Chemistry, National Taiwan University, Taipei, Taiwan 106"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hon Man","family":"Lee","sequence":"additional","affiliation":[{"name":"Department of Chemistry, National Changhua University of Education, Changhua, Taiwan 500, and Department of Chemistry, National Taiwan University, Taipei, Taiwan 106"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Gene-Hsiang","family":"Lee","sequence":"additional","affiliation":[{"name":"Department of Chemistry, National Changhua University of Education, Changhua, Taiwan 500, and Department of Chemistry, National Taiwan University, Taipei, Taiwan 106"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Shie-Ming","family":"Peng","sequence":"additional","affiliation":[{"name":"Department of Chemistry, National Changhua University of Education, Changhua, Taiwan 500, and Department of Chemistry, National Taiwan University, Taipei, Taiwan 106"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jui-Hsien","family":"Huang","sequence":"additional","affiliation":[{"name":"Department of Chemistry, National Changhua University of Education, Changhua, Taiwan 500, and Department of Chemistry, National Taiwan University, Taipei, Taiwan 106"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"316","published-online":{"date-parts":[[2004,9,15]]},"reference":[{"key":"ic049474fb00001\/ic049474fb00001_1","volume-title":"Metal\u2212Ligand Multiple Bonds","author":"Nugent W. A.","year":"1988"},{"key":"ic049474fb00001\/ic049474fb00001_2","doi-asserted-by":"crossref","first-page":"1031","DOI":"10.1016\/S0277-5387(96)00411-1","volume":"16","author":"Trnka T. M.","year":"1997","journal-title":"Polyhedron"},{"key":"ic049474fb00001\/ic049474fb00001_3","first-page":"239","volume":"42","author":"Wigley D. E.","year":"1994","journal-title":"Prog. Inorg. Chem."},{"key":"ic049474fb00001\/ic049474fb00001_4","doi-asserted-by":"crossref","first-page":"158","DOI":"10.1021\/ar00173a007","volume":"23","author":"Schrock R. R.","year":"1990","journal-title":"Acc. Chem. Res."},{"key":"ic049474fb00001\/ic049474fb00001_5","first-page":"213","volume":"591","author":"Mountford P.","year":"1999","journal-title":"J. Organomet. Chem."},{"key":"ic049474fb00001\/ic049474fb00001_6","first-page":"1","volume":"47","author":"Parkin G.","year":"1998","journal-title":"Prog. Inorg. Chem."},{"key":"ic049474fb00002\/ic049474fb00002_1","doi-asserted-by":"crossref","first-page":"761","DOI":"10.1021\/om00038a040","volume":"11","author":"Carney M. J.","year":"1992","journal-title":"Organometallics"},{"key":"ic049474fb00002\/ic049474fb00002_2","doi-asserted-by":"crossref","first-page":"1040","DOI":"10.1021\/ic981367w","volume":"38","author":"Jacob J.","year":"1999","journal-title":"Inorg. Chem."},{"key":"ic049474fb00002\/ic049474fb00002_3","doi-asserted-by":"crossref","first-page":"391","DOI":"10.1021\/ja00183a072","volume":"111","author":"Parkin G.","year":"1989","journal-title":"J. Am. Chem. Soc."},{"key":"ic049474fb00003\/ic049474fb00003_1","volume-title":"Modern Catalytic Methods for Organic Synthesis with Diazo Compounds","author":"Doyle M. P.","year":"1998"},{"key":"ic049474fb00003\/ic049474fb00003_2","doi-asserted-by":"crossref","first-page":"7408","DOI":"10.1021\/ja00258a026","volume":"109","author":"Devore D. D.","year":"1987","journal-title":"J. Am. Chem. Soc."},{"key":"ic049474fb00003\/ic049474fb00003_3","doi-asserted-by":"crossref","first-page":"11238","DOI":"10.1021\/ja026852b","volume":"124","author":"Jenkins D. M.","year":"2002","journal-title":"J. Am. Chem. Soc."},{"key":"ic049474fb00004\/ic049474fb00004_1","doi-asserted-by":"crossref","first-page":"307","DOI":"10.1021\/om960864m","volume":"16","author":"Kawaguchi H.","year":"1997","journal-title":"Organometallics"},{"key":"ic049474fb00004\/ic049474fb00004_2","doi-asserted-by":"crossref","first-page":"2083","DOI":"10.1002\/anie.199720831","volume":"36","author":"Goodman J. T.","year":"1997","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"ic049474fb00004\/ic049474fb00004_3","doi-asserted-by":"crossref","first-page":"3885","DOI":"10.1021\/ja00118a032","volume":"117","author":"Kawaguchi H.","year":"1995","journal-title":"J. Am. Chem. Soc."},{"key":"ic049474fb00004\/ic049474fb00004_4","doi-asserted-by":"crossref","first-page":"2983","DOI":"10.1021\/cr950055x","volume":"96","author":"Burgess B. K.","year":"1996","journal-title":"J. Chem. Rev."},{"key":"ic049474fb00004\/ic049474fb00004_5","doi-asserted-by":"crossref","first-page":"2965","DOI":"10.1021\/cr9500545","volume":"96","author":"Howard J. B.","year":"1996","journal-title":"Chem. Rev."},{"key":"ic049474fb00005\/ic049474fb00005_1","doi-asserted-by":"crossref","first-page":"2127","DOI":"10.1039\/a704194b","author":"Mountford P.","year":"1997","journal-title":"Chem. Commun."},{"key":"ic049474fb00005\/ic049474fb00005_2","doi-asserted-by":"crossref","first-page":"4175","DOI":"10.1039\/b207184c","author":"Boyd C. L.","year":"2002","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ic049474fb00005\/ic049474fb00005_3","doi-asserted-by":"crossref","first-page":"1549","DOI":"10.1039\/a607735h","author":"Blake A. J.","year":"1997","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ic049474fb00006\/ic049474fb00006_1","doi-asserted-by":"crossref","first-page":"3602","DOI":"10.1021\/ic00317a041","volume":"28","author":"Hill J. E.","year":"1989","journal-title":"Inorg. Chem."},{"key":"ic049474fb00006\/ic049474fb00006_2","doi-asserted-by":"crossref","first-page":"606","DOI":"10.1021\/om980888o","volume":"18","author":"Crescenzi R.","year":"1999","journal-title":"Organometallics"},{"key":"ic049474fb00006\/ic049474fb00006_3","doi-asserted-by":"crossref","first-page":"1355","DOI":"10.1021\/om970933c","volume":"17","author":"Hagadorn J. R.","year":"1998","journal-title":"Organometallics"},{"key":"ic049474fb00006\/ic049474fb00006_4","doi-asserted-by":"crossref","first-page":"2462","DOI":"10.1021\/ic00089a025","volume":"33","author":"Jeske P.","year":"1994","journal-title":"Inorg. Chem."},{"key":"ic049474fb00007\/ic049474fb00007_1","doi-asserted-by":"crossref","first-page":"5502","DOI":"10.1021\/om9907876","volume":"18","author":"Sweeney Z. K.","year":"1999","journal-title":"Organometallics"},{"key":"ic049474fb00007\/ic049474fb00007_2","doi-asserted-by":"crossref","first-page":"4543","DOI":"10.1021\/ja970168t","volume":"119","author":"Sweeney Z. K.","year":"1997","journal-title":"J. Am. Chem. Soc."},{"key":"ic049474fb00007\/ic049474fb00007_3","volume-title":"Their Properties and Applications","author":"Weisser O.","year":"1973"},{"key":"ic049474fb00008\/ic049474fb00008_1","doi-asserted-by":"crossref","first-page":"2363","DOI":"10.1021\/om00030a053","volume":"12","author":"Howard W. A.","year":"1993","journal-title":"Organometallics"},{"key":"ic049474fb00008\/ic049474fb00008_2","doi-asserted-by":"crossref","first-page":"2267","DOI":"10.1021\/ic00113a003","volume":"34","author":"Mandimutsira B. S.","year":"1995","journal-title":"Inorg. Chem."},{"key":"ic049474fb00009\/ic049474fb00009_1","doi-asserted-by":"crossref","first-page":"761","DOI":"10.1021\/om00038a040","volume":"11","author":"Carney M. J.","year":"1992","journal-title":"Organometallics"},{"key":"ic049474fb00010\/ic049474fb00010_1","doi-asserted-by":"crossref","first-page":"3631","DOI":"10.1021\/om960358x","volume":"15","author":"Lundmark P. J.","year":"1996","journal-title":"Organometallics"},{"key":"ic049474fb00011\/ic049474fb00011_1","doi-asserted-by":"crossref","first-page":"2928","DOI":"10.1021\/ic970413+","volume":"36","author":"Hagadorn J. R.","year":"1997","journal-title":"Inorg. Chem."},{"key":"ic049474fb00012\/ic049474fb00012_1","doi-asserted-by":"crossref","first-page":"293","DOI":"10.1002\/anie.198802931","volume":"27","author":"M\u00fcller U.","year":"1988","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"ic049474fb00013\/ic049474fb00013_1","doi-asserted-by":"crossref","first-page":"6450","DOI":"10.1021\/ic025785j","volume":"41","author":"Yu R.-C.","year":"2002","journal-title":"Inorg. Chem."},{"key":"ic049474fb00014\/ic049474fb00014_1","doi-asserted-by":"crossref","first-page":"2495","DOI":"10.1021\/ic00114a003","volume":"34","author":"Gallo E.","year":"1995","journal-title":"Inorg. Chem."},{"key":"ic049474fb00014\/ic049474fb00014_2","doi-asserted-by":"crossref","first-page":"379","DOI":"10.1039\/a806827e","author":"Blake A. J.","year":"1999","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ic049474fb00014\/ic049474fb00014_3","doi-asserted-by":"crossref","first-page":"2253","DOI":"10.1039\/a802686f","author":"Swallow D.","year":"1998","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ic049474fb00014\/ic049474fb00014_4","doi-asserted-by":"crossref","first-page":"5970","DOI":"10.1021\/ic9806986","volume":"37","author":"McInnes J. M.","year":"1998","journal-title":"Inorg. Chem."},{"key":"ic049474fb00014\/ic049474fb00014_5","doi-asserted-by":"crossref","first-page":"2520","DOI":"10.1021\/ic00038a039","volume":"31","author":"De Angelis S.","year":"1992","journal-title":"Inorg. Chem."},{"key":"ic049474fb00015\/ic049474fb00015_1","doi-asserted-by":"crossref","first-page":"10170","DOI":"10.1021\/ja036559r","volume":"125","author":"Basuli F.","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"ic049474fb00016\/ic049474fb00016_1","doi-asserted-by":"crossref","first-page":"2150","DOI":"10.1021\/ic981304d","volume":"38","author":"Hansen H. D.","year":"1999","journal-title":"Inorg. Chem."},{"key":"ic049474fb00016\/ic049474fb00016_2","doi-asserted-by":"crossref","first-page":"7661","DOI":"10.1021\/ja00390a048","volume":"104","author":"Maresca L.","year":"1982","journal-title":"J. Am. Chem. Soc."},{"key":"ic049474fb00016\/ic049474fb00016_3","doi-asserted-by":"crossref","first-page":"3776","DOI":"10.1021\/ic00167a021","volume":"22","author":"Camenzind M. J.","year":"1983","journal-title":"Inorg. Chem."},{"key":"ic049474fb00016\/ic049474fb00016_4","doi-asserted-by":"crossref","first-page":"189","DOI":"10.1016\/S0020-1693(98)00410-1","volume":"286","author":"Escuer A.","year":"1999","journal-title":"Inorg. Chim. Acta"},{"key":"ic049474fb00017\/ic049474fb00017_1","doi-asserted-by":"crossref","first-page":"152","DOI":"10.1039\/DT9790000152","author":"Anderson S. J.","year":"1979","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ic049474fb00017\/ic049474fb00017_2","doi-asserted-by":"crossref","first-page":"718","DOI":"10.1021\/om970815p","volume":"17","author":"Blake R. E.","year":"1998","journal-title":"Organometallics"},{"key":"ic049474fb00017\/ic049474fb00017_3","doi-asserted-by":"crossref","first-page":"47","DOI":"10.1021\/ic00079a010","volume":"33","author":"Jeske P.","year":"1994","journal-title":"Inorg. Chem."},{"key":"ic049474fb00017\/ic049474fb00017_4","doi-asserted-by":"crossref","first-page":"11649","DOI":"10.1021\/ja981340b","volume":"120","author":"Kaplan A. W.","year":"1998","journal-title":"J. Am. Chem. Soc."},{"key":"ic049474fb00018\/ic049474fb00018_1","doi-asserted-by":"crossref","first-page":"4863","DOI":"10.1021\/ic00025a036","volume":"30","author":"Duchateau R.","year":"1991","journal-title":"Inorg. Chem."},{"key":"ic049474fb00018\/ic049474fb00018_2","doi-asserted-by":"crossref","first-page":"1357","DOI":"10.1515\/znb-1991-1014","volume":"466","author":"Bai Y.","year":"1991","journal-title":"Z. Naturforsch."},{"key":"ic049474fb00018\/ic049474fb00018_3","doi-asserted-by":"crossref","first-page":"2007","DOI":"10.1039\/C39940002007","author":"Dunn S. C.","year":"1994","journal-title":"J. Chem. Soc. Chem. Commun."},{"key":"ic049474fb00018\/ic049474fb00018_4","doi-asserted-by":"crossref","first-page":"895","DOI":"10.1002\/jccs.200000121","volume":"47","author":"Huang J.-H.","year":"2000","journal-title":"J. Chin. Chem. Soc."},{"key":"ic049474fb00019\/ic049474fb00019_1","doi-asserted-by":"crossref","first-page":"988","DOI":"10.1039\/b201702d","author":"Komuro T.","year":"2002","journal-title":"Chem. Comm."},{"key":"ic049474fb00020\/ic049474fb00020_1","doi-asserted-by":"crossref","first-page":"5648","DOI":"10.1063\/1.464913","volume":"98","author":"Becke A. D.","year":"1993","journal-title":"J. Chem. Phys."},{"key":"ic049474fb00020\/ic049474fb00020_2","doi-asserted-by":"crossref","first-page":"785","DOI":"10.1103\/PhysRevB.37.785","volume":"37","author":"Lee C.","year":"1988","journal-title":"Phys. Rev. B"},{"key":"ic049474fb00021\/ic049474fb00021_1","unstructured":"Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Zakrzewski, V. G.; Montgomery, J. A., Jr.; Stratmann, R. E.; Burant, J. C.; Dapprich, S.; Millam, J. M.; Daniels, A. D.; Kudin, K. N.; Strain, M. C.; Farkas, O.; Tomasi, J.; Barone, V.; Cossi, M.; Cammi, R.; Mennucci, B.; Pomelli, C.; Adamo, C.; Clifford, S.; Ochterski, J.; Petersson, G. A.; Ayala, P. Y.; Cui, Q.; Morokuma, K.; Malick, D. K.; Rabuck, A. D.; Raghavachari, K.; Foresman, J. B.; Cioslowski, J.; Ortiz, J. V.; Stefanov, B. B.; Liu, G.; Liashenko, A.; Piskorz, P.; Komaromi, I.; Gomperts, R.; Martin, R. L.; Fox, D. J.; Keith, T.; Al-Laham, M. A.; Peng, C. Y.; Nanayakkara, A.; Gonzalez, C.; Challacombe, M.; Gill, P. M. W.; Johnson, B.; Chen, W.; Wong, M. W.; Andres, J. L.; Gonzalez, C.; Head-Gordon, M.; Replogle, E. S.; Pople, J. A. Guassian, Revision A.12 ed.; Gaussian, Inc.\u2009 Pittsburgh, PA, 2001."}],"container-title":["Inorganic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/ic049474f","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2021,9,21]],"date-time":"2021-09-21T03:17:27Z","timestamp":1632194247000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/ic049474f"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2004,9,15]]},"references-count":56,"journal-issue":{"issue":"21","published-print":{"date-parts":[[2004,10,1]]}},"alternative-id":["10.1021\/ic049474f"],"URL":"https:\/\/doi.org\/10.1021\/ic049474f","relation":{},"ISSN":["0020-1669","1520-510X"],"issn-type":[{"value":"0020-1669","type":"print"},{"value":"1520-510X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2004,9,15]]}}}