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Chem."},{"key":"ic050308xb00016\/ic050308xb00016_1","doi-asserted-by":"crossref","first-page":"294","DOI":"10.1016\/0022-2313(84)90027-9","volume":"29","author":"Brittain H. G.","year":"1984","journal-title":"J. Lumin."},{"key":"ic050308xb00017\/ic050308xb00017_1","doi-asserted-by":"crossref","first-page":"2838","DOI":"10.1021\/ic50211a072","volume":"19","author":"Wester D. W.","year":"1980","journal-title":"Inorg. Chem."},{"key":"ic050308xb00019\/ic050308xb00019_1","doi-asserted-by":"crossref","first-page":"1256","DOI":"10.1021\/ja00395a062","volume":"103","author":"Strom E. T.","year":"1981","journal-title":"J. Am. Chem. Soc."},{"key":"ic050308xb00021\/ic050308xb00021_1","first-page":"91","volume":"9","author":"Lincoln S. F.","year":"1977","journal-title":"Prog. React. Kinet."},{"key":"ic050308xb00022\/ic050308xb00022_1","doi-asserted-by":"crossref","first-page":"320","DOI":"10.1063\/1.1701321","volume":"37","author":"Swift T. J.","year":"1962","journal-title":"J. Chem. Phys."},{"key":"ic050308xb00023\/ic050308xb00023_1","doi-asserted-by":"crossref","first-page":"370","DOI":"10.1016\/S0010-8545(00)80128-9","volume":"2","author":"Stengle T. R.","year":"1967","journal-title":"Coord. Chem. Rev."},{"key":"ic050308xb00024\/ic050308xb00024_1","doi-asserted-by":"crossref","first-page":"867","DOI":"10.1021\/ja00733a011","volume":"93","author":"Letter J. E.","year":"1971","journal-title":"J. Am. Chem. Soc."},{"key":"ic050308xb00025\/ic050308xb00025_1","doi-asserted-by":"crossref","first-page":"199","DOI":"10.1021\/ic50107a050","volume":"11","author":"Rusnak L.","year":"1972","journal-title":"Inorg. Chem."},{"key":"ic050308xb00026\/ic050308xb00026_1","unstructured":"From Figure 2, it is reasonable to conclude that the transverse relaxation time of free CO\n                      3\n                      2\n                      -\n                      in the temperature range from 273 to 303 K is mainly controlled by \u03c4\n                      \n                        M\n                      \n                      \n                        -\n                      \n                      1\n                      . Therefore, from the Eyring plot, we could estimate \u0394\n                      H\n                      \u29e7\n                      and \u0394\n                      S\n                      \u29e7\n                      as 61.8 kJ\u00b7mol\n                      -\n                      1\n                      and 20 J\u00b7mol\n                      -\n                      1\n                      \u00b7K\n                      -\n                      1\n                      , respectively. These values are consistent with those obtained by fitting. The nonlinear least-squares fit to eq 2 gave a minimum error value, when the values of\n                      C\n                      \n                        M\n                      \n                      and\n                      E\n                      \n                        M\n                      \n                      were fixed to 2.57 \u00d7 10\n                      3\n                      s\n                      -\n                      1\n                      and 4.80 kJ\u00b7mol\n                      -\n                      1\n                      , respectively. The \u0394\u03c9\n                      \n                        M\n                      \n                      value was found to have no influence on the fit even in \u0394\u03c9\n                      \n                        M\n                      \n                      = 0. This means that the line-widths in the range from 273 to 333 K in Figure 2 are independent of \u0394\u03c9\n                      \n                        M\n                      \n                      . Furthermore, the values of \u0394\n                      H\n                      \u29e7\n                      and \u0394\n                      S\n                      \u29e7\n                      were calculated by changing\n                      C\n                      \n                        M\n                      \n                      and\n                      E\n                      \n                        M\n                      \n                      values in the ranges of (2.35\u22122.70) \u00d7 10\n                      -\n                      3\n                      s\n                      -\n                      1\n                      and 3.6\u22124.9 kJ\u00b7mol\n                      -\n                      1\n                      , respectively. As a result, the variations of \u0394\n                      H\n                      \u29e7\n                      and \u0394\n                      S\n                      \u29e7\n                      values were found to be \u00b10.7 and \u00b13, respectively."},{"key":"ic050308xb00027\/ic050308xb00027_1","unstructured":"Normalized standard deviation = [\u03a3{(\n                      y\n                      o\n                      \u2212\n                      y\n                      p\n                      )\/\n                      y\n                      o\n                      }\n                      2\n                      \/(\n                      q\n                      \u2212\n                      r\n                      )]\n                      1\/2\n                      , where\n                      y\n                      o\n                      and\n                      y\n                      p\n                      are the observed and predicted values of (\n                      T\n                      2obs\n                      -\n                      1\n                      \u2212\n                      T\n                      2\n                      \n                        n\n                      \n                      \n                        -\n                      \n                      1\n                      )\n                      P\n                      \n                        L\n                      \n                      \/\n                      P\n                      \n                        M\n                      \n                      ,\n                      q\n                      is the number of observed values, and\n                      r\n                      is the number of variable parameters used in the fit."},{"key":"ic050308xb00028\/ic050308xb00028_1","doi-asserted-by":"crossref","first-page":"12008","DOI":"10.1021\/ja015935+","volume":"123","author":"Vallet V.","year":"2001","journal-title":"J. Am. Chem. Soc."},{"key":"ic050308xb00028\/ic050308xb00028_2","doi-asserted-by":"crossref","first-page":"7767","DOI":"10.1021\/ja0483544","volume":"126","author":"Vallet V.","year":"2004","journal-title":"J. Am. Chem. Soc."}],"container-title":["Inorganic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/ic050308x","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2021,9,20]],"date-time":"2021-09-20T11:13:33Z","timestamp":1632136413000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/ic050308x"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2005,6,1]]},"references-count":32,"journal-issue":{"issue":"13","published-print":{"date-parts":[[2005,6,1]]}},"alternative-id":["10.1021\/ic050308x"],"URL":"https:\/\/doi.org\/10.1021\/ic050308x","relation":{},"ISSN":["0020-1669","1520-510X"],"issn-type":[{"value":"0020-1669","type":"print"},{"value":"1520-510X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2005,6,1]]}}}