{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,8]],"date-time":"2025-10-08T21:52:17Z","timestamp":1759960337111},"reference-count":14,"publisher":"American Chemical Society (ACS)","issue":"26","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Inorg. Chem."],"published-print":{"date-parts":[[2005,12,1]]},"DOI":"10.1021\/ic0513944","type":"journal-article","created":{"date-parts":[[2005,12,19]],"date-time":"2005-12-19T05:56:56Z","timestamp":1134971816000},"page":"9622-9624","source":"Crossref","is-referenced-by-count":13,"title":["Reduction of the Host Cationic Framework Charge by Isoelectronic Substitution:\u2009 Synthesis and Structure of Hg<sub>7<\/sub>Ag<sub>2<\/sub>P<sub>8<\/sub>X<sub>6<\/sub> (X = Br, I) and Hg<sub>6<\/sub>Ag<sub>4<\/sub>P<sub>8<\/sub>Br<sub>6<\/sub>"],"prefix":"10.1021","volume":"44","author":[{"given":"Olga S.","family":"Oleneva","sequence":"first","affiliation":[{"name":"Inorganic Synthesis Laboratory, Department of Chemistry, Moscow State University, 119992 Moscow, Russia, Department of Materials Sciences, Moscow State University, 119992, Moscow, Russia, and Department of Chemistry, University at Albany, Albany, New York 12222"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Andrei V.","family":"Olenev","sequence":"additional","affiliation":[{"name":"Inorganic Synthesis Laboratory, Department of Chemistry, Moscow State University, 119992 Moscow, Russia, Department of Materials Sciences, Moscow State University, 119992, Moscow, Russia, and Department of Chemistry, University at Albany, Albany, New York 12222"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tatiana A.","family":"Shestimerova","sequence":"additional","affiliation":[{"name":"Inorganic Synthesis Laboratory, Department of Chemistry, Moscow State University, 119992 Moscow, Russia, Department of Materials Sciences, Moscow State University, 119992, Moscow, Russia, and Department of Chemistry, University at Albany, Albany, New York 12222"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alexey I.","family":"Baranov","sequence":"additional","affiliation":[{"name":"Inorganic Synthesis Laboratory, Department of Chemistry, Moscow State University, 119992 Moscow, Russia, Department of Materials Sciences, Moscow State University, 119992, Moscow, Russia, and Department of Chemistry, University at Albany, Albany, New York 12222"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Evgeny V.","family":"Dikarev","sequence":"additional","affiliation":[{"name":"Inorganic Synthesis Laboratory, Department of Chemistry, Moscow State University, 119992 Moscow, Russia, Department of Materials Sciences, Moscow State University, 119992, Moscow, Russia, and Department of Chemistry, University at Albany, Albany, New York 12222"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Andrei V.","family":"Shevelkov","sequence":"additional","affiliation":[{"name":"Inorganic Synthesis Laboratory, Department of Chemistry, Moscow State University, 119992 Moscow, Russia, Department of Materials Sciences, Moscow State University, 119992, Moscow, Russia, and Department of Chemistry, University at Albany, Albany, New York 12222"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"316","published-online":{"date-parts":[[2005,11,30]]},"reference":[{"key":"ic0513944b00001\/ic0513944b00001_1","first-page":"2361","volume":"34","author":"M\u00fcller A.","year":"1995","journal-title":"Angew. Chem., Int. Ed. Engl"},{"key":"ic0513944b00002\/ic0513944b00002_1","first-page":"3208","volume":"3201","author":"Olenev A. V.","year":"2003","journal-title":"Chem. Eur. J"},{"key":"ic0513944b00003\/ic0513944b00003_1","first-page":"1057","volume":"1053","author":"Olenev A. V.","year":"2003","journal-title":"Eur. J. Inorg. Chem"},{"key":"ic0513944b00004\/ic0513944b00004_1","first-page":"4010","volume":"4006","author":"Oleneva O. S.","year":"2004","journal-title":"Eur. J. Inorg. Chem"},{"key":"ic0513944b00005\/ic0513944b00005_1","doi-asserted-by":"crossref","first-page":"2354","DOI":"10.1002\/1521-3773(20010618)40:12<2353::AID-ANIE2353>3.0.CO;2-9","volume":"40","author":"Olenev A. V.","year":"2001","journal-title":"Angew. Chem., Int. Ed"},{"key":"ic0513944b00006\/ic0513944b00006_1","first-page":"1626","volume":"626","author":"Beck J.","year":"2000","journal-title":"Z. Anorg. Allg. Chem"},{"key":"ic0513944b00007\/ic0513944b00007_1","doi-asserted-by":"crossref","first-page":"1701","DOI":"10.1002\/zaac.200500059","volume":"631","author":"Olenev A. V.","year":"2005","journal-title":"Z. Anorg. Allg. Chem"},{"key":"ic0513944b00008\/ic0513944b00008_1","volume-title":"Structural Inorganic Chemistry","author":"Wells A. F.","year":"1986","edition":"5"},{"key":"ic0513944b00010\/ic0513944b00010_1","unstructured":"Crystal data for Hg7Ag2P8Br6:\u2009Mr= 2347.08,C2\/m(no. 12),a= 12.8660(17) \u00c5,b= 10.9562(17) \u00c5,c= 8.0792(12) \u00c5,\u03b2= 100.902(3)\u00b0,V= 1118.3(3) \u00c53,Z= 2,T= 173(2) K,\u03bc(Mo K\u03b1) = 60.842 mm-1, 4749\/1382 reflns measured\/unique (Rint= 0.0644). The final R1 = 0.0374, wR2 = 0.0968 for all data. For Hg7Ag2P8I6:\u2009Mr= 2629.04,C2\/m(no. 12),a= 13.1464(17) \u00c5,b= 11.0370(14) \u00c5,c= 8.3358(11) \u00c5,\u03b2= 102.210(2)\u00b0,V= 1182.1(3) \u00c53,Z= 2,T= 173(2) K,\u03bc(Mo K\u03b1) = 55.252 mm-1, 5071\/1447 reflns measured\/unique (Rint= 0.0299). The final R1 = 0.0388, wR2 = 0.0924 for all data. For Hg6Ag4P8Br6:\u2009Mr= 2362.24,R3\u0304m(no. 166),a= 10.8320(4) \u00c5,c= 16.5125(12) \u00c5,V= 1677.88(15) \u00c53,Z= 3,T= 173(2) K,\u03bc(Mo K\u03b1) = 55.70 mm-1, 4858\/521 reflns measured\/unique (Rint= 0.0292). The final R1 = 0.0463, wR2 = 0.1657 for all data."},{"key":"ic0513944b00011\/ic0513944b00011_1","first-page":"273","volume":"88","author":"von Schnering H.-G.","year":"1988","journal-title":"Chem. Rev"},{"key":"ic0513944b00012\/ic0513944b00012_1","doi-asserted-by":"crossref","first-page":"18","DOI":"10.1006\/jssc.1998.7977","volume":"142","author":"Olenev A. V.","year":"1999","journal-title":"J. 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