{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T21:07:25Z","timestamp":1787000845205,"version":"build-2736575974"},"reference-count":23,"publisher":"American Chemical Society (ACS)","issue":"18","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Inorg. Chem."],"published-print":{"date-parts":[[2006,9,1]]},"DOI":"10.1021\/ic060533u","type":"journal-article","created":{"date-parts":[[2006,8,9]],"date-time":"2006-08-09T06:44:27Z","timestamp":1155105867000},"page":"7035-7037","source":"Crossref","is-referenced-by-count":32,"title":["Heterotopic Helicand for Designing Heterometallic Helicates"],"prefix":"10.1021","volume":"45","author":[{"given":"Paula","family":"Cucos","sequence":"first","affiliation":[{"name":"Inorganic Chemistry Laboratory, Faculty of Chemistry, University of Bucharest, Str. 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J.","year":"2004","journal-title":"J. Supramol. Chem."},{"key":"ic060533ub00006\/ic060533ub00006_1","first-page":"1635","author":"For","year":"2002","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ic060533ub00007\/ic060533ub00007_1","doi-asserted-by":"crossref","first-page":"705","DOI":"10.1016\/j.ccr.2004.08.023","volume":"249","author":"Piguet C.","year":"2005","journal-title":"Coord. Chem. Rev."},{"key":"ic060533ub00008\/ic060533ub00008_1","volume-title":"DMSO-d6, 298 K):\u2009 \u03b4 8.97 (1H, s), 8.16 (1H, dd, J = 7.8 and 1.7 Hz), 7.96 (1H, dd, J = 7.8 and 1.7 Hz), 8.16 (1H, t, J = 7.8 Hz). Elem anal. Calcd:\u2009 C, 58.54","author":"To 0."},{"key":"ic060533ub00009\/ic060533ub00009_1","unstructured":"To a stirred suspension of H\n                      4\n                      L (0.3 mmol) in EtOH\u2212H\n                      2\n                      O (1:1, 40 mL) was added an aqueous solution (10 mL) of Na\n                      2\n                      CO\n                      3\n                      \u00b710H\n                      2\n                      O (0.6 mmol). The formed clear light-yellow solution was reacted with a mixture of Fe(ClO\n                      4\n                      )\n                      3\n                      \u00b76H\n                      2\n                      O (0.2 mmol) and Co(ClO\n                      4\n                      )\n                      2\n                      \u00b76H\n                      2\n                      O (0.2 mmol) in EtOH\u2212H\n                      2\n                      O (1:1, 10 mL). The resulting red solution was allowed to evaporate slowly, and red squarelike crystals formed after 1 week, which were isolated by filtration, washed with ethanol, and dried in air. Yield:\u2009 42%. IR data (KBr, cm\n                      -\n                      1\n                      ):\u2009 3451br, 1605vs, 1555vs, 1460s, 1432s, 1382m, 1341s, 1228m, 1082w, 879w, 764m. Elem anal. Calcd:\u2009 C, 42.55; H, 3.41; N, 5.73; Co, 7.77; Fe, 7.63; Na, 3.14. Found:\u2009 C, 41.40; H, 2.90; N, 6.04; Co, 8.47; Fe, 8.02; Na, 3.30. FAB-MS:\u2009 found\n                      m\n                      \/\n                      z\n                      1248.747 [L\n                      3\n                      Fe\n                      2\n                      Co\n                      2\n                      Na\n                      2\n                      + H]\n                      +\n                      ; calcd\n                      m\n                      \/\n                      z\n                      1249.278."},{"key":"ic060533ub00011\/ic060533ub00011_1","doi-asserted-by":"crossref","unstructured":"Reid, S. D.; Blake, A. J.; Wilson, C.; Love, J. B.\n                      Inorg. Chem.\n                      2006\n                      ,\n                      45\n                      , 636 [cobalt(II) helicates].","DOI":"10.1021\/ic051433b"},{"key":"ic060533ub00012\/ic060533ub00012_1","doi-asserted-by":"crossref","unstructured":"Sreerama, S. G.; Pal, S.\n                      Inorg. Chem.\n                      2005\n                      ,\n                      44\n                      , 6299 [iron(III) helicates].","DOI":"10.1021\/ic050704f"},{"key":"ic060533ub00013\/ic060533ub00013_1","doi-asserted-by":"crossref","first-page":"421","DOI":"10.1246\/cl.1998.421","volume":"27","author":"Mikuriya M.","year":"1998","journal-title":"Chem. Lett."},{"key":"ic060533ub00014\/ic060533ub00014_1","first-page":"173","volume":"206","author":"Abragam A.","year":"1951","journal-title":"Proc. R. Soc. London"},{"key":"ic060533ub00015\/ic060533ub00015_1","doi-asserted-by":"crossref","first-page":"632","DOI":"10.1039\/B314355D","author":"Mossin S.","year":"2004","journal-title":"Dalton Trans."}],"container-title":["Inorganic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/ic060533u","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,3,13]],"date-time":"2023-03-13T13:48:25Z","timestamp":1678715305000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/ic060533u"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2006,8,9]]},"references-count":23,"journal-issue":{"issue":"18","published-print":{"date-parts":[[2006,9,1]]}},"alternative-id":["10.1021\/ic060533u"],"URL":"https:\/\/doi.org\/10.1021\/ic060533u","relation":{},"ISSN":["0020-1669","1520-510X"],"issn-type":[{"value":"0020-1669","type":"print"},{"value":"1520-510X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2006,8,9]]}}}