{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,23]],"date-time":"2026-08-23T09:16:59Z","timestamp":1787476619764,"version":"build-2736575974"},"reference-count":64,"publisher":"American Chemical Society (ACS)","issue":"17","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Inorg. Chem."],"published-print":{"date-parts":[[2006,8,1]]},"DOI":"10.1021\/ic060544n","type":"journal-article","created":{"date-parts":[[2006,7,27]],"date-time":"2006-07-27T09:00:29Z","timestamp":1153990829000},"page":"6965-6978","source":"Crossref","is-referenced-by-count":44,"title":["M\u2212P versus MM Bonds as Protonation Sites in the Organophosphide-Bridged Complexes [M<sub>2<\/sub>Cp<sub>2<\/sub>(\u03bc-PR<sub>2<\/sub>)(\u03bc-PR\u2018<sub>2<\/sub>)(CO)<sub>2<\/sub>], (M = Mo, W; R, R\u2018 = Ph, Et, Cy)"],"prefix":"10.1021","volume":"45","author":[{"given":"M. Angeles","family":"Alvarez","sequence":"first","affiliation":[{"name":"Departamento de Qu\u00edmica Org\u00e1nica e Inorg\u00e1nica\/IUQOEM, Universidad de Oviedo, E-33071 Oviedo, Spain, and Laboratoire de Chimie Inorganique et Mat\u00e9riaux Mol\u00e9culaires, Universit\u00e9 P. et M. Curie, 4 Place Jussieu, 75252 Paris, Cedex 05, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"M. Esther","family":"Garc\u00eda","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Org\u00e1nica e Inorg\u00e1nica\/IUQOEM, Universidad de Oviedo, E-33071 Oviedo, Spain, and Laboratoire de Chimie Inorganique et Mat\u00e9riaux Mol\u00e9culaires, Universit\u00e9 P. et M. Curie, 4 Place Jussieu, 75252 Paris, Cedex 05, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"M. Eugenia","family":"Mart\u00ednez","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Org\u00e1nica e Inorg\u00e1nica\/IUQOEM, Universidad de Oviedo, E-33071 Oviedo, Spain, and Laboratoire de Chimie Inorganique et Mat\u00e9riaux Mol\u00e9culaires, Universit\u00e9 P. et M. Curie, 4 Place Jussieu, 75252 Paris, Cedex 05, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alberto","family":"Ramos","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Org\u00e1nica e Inorg\u00e1nica\/IUQOEM, Universidad de Oviedo, E-33071 Oviedo, Spain, and Laboratoire de Chimie Inorganique et Mat\u00e9riaux Mol\u00e9culaires, Universit\u00e9 P. et M. Curie, 4 Place Jussieu, 75252 Paris, Cedex 05, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Miguel A.","family":"Ruiz","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Org\u00e1nica e Inorg\u00e1nica\/IUQOEM, Universidad de Oviedo, E-33071 Oviedo, Spain, and Laboratoire de Chimie Inorganique et Mat\u00e9riaux Mol\u00e9culaires, Universit\u00e9 P. et M. Curie, 4 Place Jussieu, 75252 Paris, Cedex 05, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"David","family":"S\u00e1ez","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Org\u00e1nica e Inorg\u00e1nica\/IUQOEM, Universidad de Oviedo, E-33071 Oviedo, Spain, and Laboratoire de Chimie Inorganique et Mat\u00e9riaux Mol\u00e9culaires, Universit\u00e9 P. et M. Curie, 4 Place Jussieu, 75252 Paris, Cedex 05, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jacqueline","family":"Vaissermann","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Org\u00e1nica e Inorg\u00e1nica\/IUQOEM, Universidad de Oviedo, E-33071 Oviedo, Spain, and Laboratoire de Chimie Inorganique et Mat\u00e9riaux Mol\u00e9culaires, Universit\u00e9 P. et M. Curie, 4 Place Jussieu, 75252 Paris, Cedex 05, France"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2006,7,27]]},"reference":[{"key":"ic060544nb00001\/ic060544nb00001_1","doi-asserted-by":"crossref","first-page":"759","DOI":"10.1016\/S0277-5387(00)86883-7","volume":"6","author":"Curtis M. D.","year":"1987","journal-title":"Polyhedron"},{"key":"ic060544nb00001\/ic060544nb00001_2","doi-asserted-by":"crossref","first-page":"101","DOI":"10.1016\/S0065-3055(08)60353-6","volume":"29","author":"Winter M.","year":"1989","journal-title":"J. Adv. Organomet. Chem."},{"key":"ic060544nb00002\/ic060544nb00002_1","doi-asserted-by":"crossref","first-page":"1156","DOI":"10.1002\/anie.199311561","volume":"32","author":"Alvarez M. A.","year":"1993","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"ic060544nb00002\/ic060544nb00002_2","doi-asserted-by":"crossref","first-page":"4509","DOI":"10.1021\/om990135h","volume":"18","author":"Alvarez M. A.","year":"1999","journal-title":"Organometallics"},{"key":"ic060544nb00002\/ic060544nb00002_3","doi-asserted-by":"crossref","first-page":"456","DOI":"10.1021\/om020669+","volume":"22","author":"Alvarez M. A.","year":"2003","journal-title":"Organometallics"},{"key":"ic060544nb00002\/ic060544nb00002_4","doi-asserted-by":"crossref","first-page":"433","DOI":"10.1021\/om034053b","volume":"23","author":"Alvarez M. A.","year":"2004","journal-title":"Organometallics"},{"key":"ic060544nb00002\/ic060544nb00002_5","doi-asserted-by":"crossref","first-page":"3950","DOI":"10.1021\/om049763b","volume":"23","author":"Alvarez M. A.","year":"2004","journal-title":"Organometallics"},{"key":"ic060544nb00002\/ic060544nb00002_6","doi-asserted-by":"crossref","first-page":"2452","DOI":"10.1021\/om0490839","volume":"24","author":"Alvarez M. A.","year":"2005","journal-title":"Organometallics"},{"key":"ic060544nb00003\/ic060544nb00003_1","doi-asserted-by":"crossref","first-page":"415","DOI":"10.1039\/cs9831200415","volume":"12","author":"Moore D. S.","year":"1983","journal-title":"Chem. Soc. Rev."},{"key":"ic060544nb00003\/ic060544nb00003_2","unstructured":"(b) Crabtree, R. H. Organometallic Chemistry of the Transition Metals, 2nd ed.; John Wiley and Sons:\u2009 New York, 1994; Chapter 13, p 335."},{"key":"ic060544nb00004\/ic060544nb00004_1","doi-asserted-by":"crossref","first-page":"2530","DOI":"10.1021\/om961103m","volume":"16","author":"Heinekey D. M.","year":"1997","journal-title":"Organometallics"},{"key":"ic060544nb00004\/ic060544nb00004_2","doi-asserted-by":"crossref","first-page":"3749","DOI":"10.1021\/om020266+","volume":"21","author":"Fujita K.","year":"2002","journal-title":"Organometallics"},{"key":"ic060544nb00004\/ic060544nb00004_3","doi-asserted-by":"crossref","first-page":"12368","DOI":"10.1021\/ja036929b","volume":"125","author":"Fujita K.","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"ic060544nb00004\/ic060544nb00004_4","doi-asserted-by":"crossref","first-page":"144","DOI":"10.1016\/S0022-328X(01)00777-X","volume":"628","author":"B\u00f6ttcher H. C.","year":"2001","journal-title":"J. Organomet. Chem."},{"key":"ic060544nb00005\/ic060544nb00005_1","doi-asserted-by":"crossref","first-page":"634","DOI":"10.1021\/om9806601","volume":"18","author":"Alvarez M. A.","year":"1999","journal-title":"Organometallics"},{"key":"ic060544nb00006\/ic060544nb00006_1","doi-asserted-by":"crossref","first-page":"5515","DOI":"10.1021\/om020573f","volume":"21","author":"Garc\u00eda M. E.","year":"2002","journal-title":"Organometallics"},{"key":"ic060544nb00007\/ic060544nb00007_1","doi-asserted-by":"crossref","first-page":"1555","DOI":"10.1039\/DT9890001555","author":"Adatia T.","year":"1989","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ic060544nb00008\/ic060544nb00008_1","first-page":"25","volume":"30","author":"Albinati A.","year":"1991","journal-title":"Inorg. Chem."},{"key":"ic060544nb00008\/ic060544nb00008_2","doi-asserted-by":"crossref","first-page":"1702","DOI":"10.1021\/om00029a031","volume":"12","author":"Leoni P.","year":"1993","journal-title":"Organometallics"},{"key":"ic060544nb00008\/ic060544nb00008_3","doi-asserted-by":"crossref","first-page":"4017","DOI":"10.1021\/om00022a044","volume":"13","author":"Leoni P.","year":"1994","journal-title":"Organometallics"},{"key":"ic060544nb00008\/ic060544nb00008_4","unstructured":"(d) Leoni, P.; Vichi, E.; Leonci, S.; Pasquali, M.; Chiarentin, E.; Albinati, A.Organometallics2000,19, 3062"},{"key":"ic060544nb00009\/ic060544nb00009_1","doi-asserted-by":"crossref","first-page":"2346","DOI":"10.1039\/B408081E","author":"Leoni P.","year":"2004","journal-title":"Chem. Commun."},{"key":"ic060544nb00010\/ic060544nb00010_1","doi-asserted-by":"crossref","first-page":"4750","DOI":"10.1021\/om049574t","volume":"23","author":"Alvarez C. M.","year":"2004","journal-title":"Organometallics"},{"key":"ic060544nb00011\/ic060544nb00011_1","doi-asserted-by":"crossref","first-page":"2600","DOI":"10.1246\/bcsj.57.2600","volume":"57","author":"Nishida H.","year":"1984","journal-title":"Bull. Chem. Soc. Jpn."},{"key":"ic060544nb00011\/ic060544nb00011_2","doi-asserted-by":"crossref","first-page":"3920","DOI":"10.1021\/om00059a071","volume":"11","author":"Brookhart M.","year":"1992","journal-title":"Organometallics"},{"key":"ic060544nb00012\/ic060544nb00012_1","volume-title":"Metal Carbonyl Spectra","author":"Braterman P. S.","year":"1975"},{"key":"ic060544nb00013\/ic060544nb00013_1","volume-title":"Phosphorus-31 NMR Spectroscopy in Stereochemical Analysis","author":"Jameson C.","year":"1987"},{"key":"ic060544nb00014\/ic060544nb00014_1","first-page":"1965","author":"Davies J. E.","year":"2000","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ic060544nb00015\/ic060544nb00015_1","doi-asserted-by":"crossref","first-page":"125","DOI":"10.1016\/0022-328X(90)80090-M","volume":"399","author":"Wrackmeyer B.","year":"1990","journal-title":"J. Organomet. Chem."},{"key":"ic060544nb00016\/ic060544nb00016_1","doi-asserted-by":"crossref","first-page":"5852","DOI":"10.1021\/ja00723a007","volume":"92","author":"Faller J. W.","year":"1970","journal-title":"J. Am. Chem. Soc."},{"key":"ic060544nb00017\/ic060544nb00017_1","doi-asserted-by":"crossref","first-page":"33","DOI":"10.1021\/cr60307a002","volume":"77","author":"Tolman C. A.","year":"1977","journal-title":"Chem. Rev."},{"key":"ic060544nb00017\/ic060544nb00017_2","doi-asserted-by":"crossref","first-page":"5673","DOI":"10.1021\/ja00253a018","volume":"109","author":"Stahl L.","year":"1987","journal-title":"J. Am. Chem. Soc."},{"key":"ic060544nb00017\/ic060544nb00017_3","doi-asserted-by":"crossref","first-page":"1286","DOI":"10.1021\/ic00033a029","volume":"31","author":"Brown T. L.","year":"1992","journal-title":"Inorg. Chem."},{"key":"ic060544nb00017\/ic060544nb00017_4","doi-asserted-by":"crossref","first-page":"533","DOI":"10.1007\/BF00136415","volume":"20","author":"Muller T. E.","year":"1995","journal-title":"Transition Met. Chem."},{"key":"ic060544nb00017\/ic060544nb00017_5","doi-asserted-by":"crossref","first-page":"131","DOI":"10.1016\/S0022-328X(96)06591-6","volume":"530","author":"Smith J. M.","year":"1997","journal-title":"J. Organomet. Chem."},{"key":"ic060544nb00018\/ic060544nb00018_1","doi-asserted-by":"crossref","first-page":"737","DOI":"10.1016\/0010-8545(94)80082-0","volume":"135","author":"Dias P. B.","year":"1994","journal-title":"Coord. Chem. Rev."},{"key":"ic060544nb00018\/ic060544nb00018_2","doi-asserted-by":"crossref","first-page":"3408","DOI":"10.1021\/om00007a047","volume":"14","author":"Drago R. S.","year":"1995","journal-title":"Organometallics"},{"key":"ic060544nb00019\/ic060544nb00019_1","doi-asserted-by":"crossref","DOI":"10.1007\/b113929","volume-title":"Metal Dihydrogen and \u03c3-Bond Complexes","author":"Kubas G. J.","year":"2001"},{"key":"ic060544nb00020\/ic060544nb00020_1","unstructured":"Calculated using the modified Eyring equation \u0394G#= 19.14Tc[9.97 + log(Tc\/\u0394\u03bd)] (in Jmol-1). See:\u2009 G\u00fcnter, H.NMR Spectroscopy; John Wiley:\u2009 Chichester, U.K., 1980; p 243."},{"key":"ic060544nb00021\/ic060544nb00021_1","doi-asserted-by":"crossref","first-page":"805","DOI":"10.1021\/ic00226a016","volume":"25","author":"Crabtree R. H.","year":"1986","journal-title":"Inorg. Chem."},{"key":"ic060544nb00022\/ic060544nb00022_1","doi-asserted-by":"crossref","first-page":"5034","DOI":"10.1021\/ja00484a020","volume":"100","author":"Klinger R. J.","year":"1978","journal-title":"J. Am. Chem. Soc."},{"key":"ic060544nb00022\/ic060544nb00022_2","doi-asserted-by":"crossref","first-page":"354","DOI":"10.1021\/om960714b","volume":"16","author":"Alvarez M. A.","year":"1997","journal-title":"Organometallics"},{"key":"ic060544nb00023\/ic060544nb00023_1","doi-asserted-by":"crossref","first-page":"1641","DOI":"10.1021\/ja00031a016","volume":"114","author":"Simpson C. Q.","year":"1992","journal-title":"J. Am. Chem. Soc."},{"key":"ic060544nb00024\/ic060544nb00024_1","doi-asserted-by":"crossref","first-page":"7","DOI":"10.1021\/om0491948","volume":"24","author":"Alvarez C. M.","year":"2005","journal-title":"Organometallics"},{"key":"ic060544nb00025\/ic060544nb00025_1","volume-title":"Multiple Bonds Between Metal Atoms","author":"Cotton F. A.","year":"1993","edition":"2"},{"key":"ic060544nb00026\/ic060544nb00026_1","doi-asserted-by":"crossref","first-page":"3722","DOI":"10.1021\/ja00377a031","volume":"104","author":"Hoyano J. K.","year":"1982","journal-title":"J. Am. Chem. Soc."},{"key":"ic060544nb00026\/ic060544nb00026_2","doi-asserted-by":"crossref","first-page":"679","DOI":"10.1039\/c39840000679","author":"Forrow W. J.","year":"1984","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"ic060544nb00026\/ic060544nb00026_3","doi-asserted-by":"crossref","first-page":"2569","DOI":"10.1021\/om00054a014","volume":"10","author":"Kang B. S.","year":"1991","journal-title":"Organometallics"},{"key":"ic060544nb00026\/ic060544nb00026_4","doi-asserted-by":"crossref","first-page":"1009","DOI":"10.1002\/1099-0682(200205)2002:5<1009::AID-EJIC1009>3.0.CO;2-0","author":"Suzuki H.","year":"2002","journal-title":"Eur. J. Inorg. Chem."},{"key":"ic060544nb00027\/ic060544nb00027_1","doi-asserted-by":"crossref","first-page":"4122","DOI":"10.1021\/om050550b","volume":"24","author":"Alvarez M. A.","year":"2005","journal-title":"Organometallics"},{"key":"ic060544nb00028\/ic060544nb00028_1","doi-asserted-by":"crossref","first-page":"1960","DOI":"10.1021\/ja9818203","volume":"121","author":"Garc\u00eda M. E.","year":"1999","journal-title":"J. Am. Chem. Soc."},{"key":"ic060544nb00029\/ic060544nb00029_1","volume-title":"Purification of Laboratory Chemicals","author":"Perrin D. D.","year":"1988"},{"key":"ic060544nb00030\/ic060544nb00030_1","volume-title":"Crystals Issue 10","author":"Watkin D. J.","year":"1996"},{"key":"ic060544nb00031\/ic060544nb00031_1","volume-title":"International Tables for X-ray Crystallography","author":"Cromer D. T.","year":"1974"},{"key":"ic060544nb00032\/ic060544nb00032_1","volume-title":"Program for Crystal Structures Solution","author":"Sheldrick G. M.","year":"1986"},{"key":"ic060544nb00033\/ic060544nb00033_1","unstructured":"SMART & SAINT Software Reference Manuals, Version 5.051(Windows NT Version); Bruker Analytical X-ray Instruments:\u2009 Madison, WI, 1998."},{"key":"ic060544nb00034\/ic060544nb00034_1","volume-title":"Program for Empirical Absorption Correction","author":"Sheldrick G. M. SADABS","year":"1996"},{"key":"ic060544nb00035\/ic060544nb00035_1","volume-title":"The DIRDIF Program System","author":"Beurkens P. T.","year":"1999"},{"key":"ic060544nb00036\/ic060544nb00036_1","volume-title":"Germany","author":"Sheldrick G. M.","year":"1997"},{"key":"ic060544nb00037\/ic060544nb00037_1","doi-asserted-by":"crossref","first-page":"2509","DOI":"10.1039\/dt9800002509","author":"Orpen A. G.","year":"1980","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ic060544nb00038\/ic060544nb00038_1","doi-asserted-by":"crossref","first-page":"194","DOI":"10.1107\/S0108767389011189","volume":"46","author":"Van der Sluis P.","year":"1990","journal-title":"Acta Crystallogr., Sect. A"},{"key":"ic060544nb00039\/ic060544nb00039_1","first-page":"C34","volume":"46","author":"Spek A. L.","year":"1990","journal-title":"Acta Crystallogr., Sect. A"},{"key":"ic060544nb00039\/ic060544nb00039_2","volume-title":"A Multipurpose Crystallographic Tool","author":"Spek A. L. PLATON","year":"1998"},{"key":"ic060544nb00040\/ic060544nb00040_1","volume-title":"Twinning Solution Program Suite","author":"GEMINI","year":"2000"}],"container-title":["Inorganic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/ic060544n","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2021,10,13]],"date-time":"2021-10-13T04:10:47Z","timestamp":1634098247000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/ic060544n"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2006,7,27]]},"references-count":64,"journal-issue":{"issue":"17","published-print":{"date-parts":[[2006,8,1]]}},"alternative-id":["10.1021\/ic060544n"],"URL":"https:\/\/doi.org\/10.1021\/ic060544n","relation":{},"ISSN":["0020-1669","1520-510X"],"issn-type":[{"value":"0020-1669","type":"print"},{"value":"1520-510X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2006,7,27]]}}}