{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T07:49:55Z","timestamp":1791186595303,"version":"4.1.0"},"reference-count":86,"publisher":"American Chemical Society (ACS)","issue":"17","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Inorg. Chem."],"published-print":{"date-parts":[[2010,9,6]]},"DOI":"10.1021\/ic1010693","type":"journal-article","created":{"date-parts":[[2010,8,9]],"date-time":"2010-08-09T13:27:56Z","timestamp":1281360476000},"page":"8045-8055","source":"Crossref","is-referenced-by-count":13,"title":["Sulfur-Based Redox Reactions in Mo<sub>3<\/sub>S<sub>7<\/sub><sup>4+<\/sup> and Mo<sub>3<\/sub>S<sub>4<\/sub><sup>4+<\/sup> Clusters Bearing Halide and 1,2-Dithiolene Ligands: a Mass Spectrometric and Density Functional Theory Study"],"prefix":"10.1021","volume":"49","author":[{"given":"Rosa","family":"Llusar","sequence":"first","affiliation":[{"name":"Departament de Qu\u00edmica F\u00edsica i Anal\u00edtica, Universitat Jaume I, Av. Sos Baynat s\/n, 12071 Castell\u00f3, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Victor","family":"Polo","sequence":"additional","affiliation":[{"name":"Instituto de Biocomputaci\u00f3n y F\u00edsica de los Sistemas Complejos (BIFI), Edificio Cervantes, Corona de Arag\u00f3n 42, Zaragoza 50009, Spain"},{"name":"Departamento de Qu\u00edmica Org\u00e1nica y Qu\u00edmica F\u00edsica, Universidad de Zaragoza, c\/Pedro Cerbuna s\/n, 50009 Zaragoza, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ederley","family":"Velez","sequence":"additional","affiliation":[{"name":"Departament de Qu\u00edmica F\u00edsica i Anal\u00edtica, Universitat Jaume I, Av. Sos Baynat s\/n, 12071 Castell\u00f3, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cristian","family":"Vicent","sequence":"additional","affiliation":[{"name":"Serveis Centrals d\u2019Instrumentaci\u00f3 Cient\u00edfica, Universitat Jaume I, Avda. Sos Baynat s\/n, E-12071, Castell\u00f3, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2010,8,9]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"crossref","unstructured":"Stiefel, E. I.Transition Metal Sulfur Chemistry: Biological and Industrial Significance;Stiefel, E. I. and Matsumoto, K., Eds.American Chemical Society:Washington, DC, 1996; Vol.653, p2.","DOI":"10.1021\/bk-1996-0653.ch001"},{"key":"ref2\/cit2a","doi-asserted-by":"crossref","first-page":"211","DOI":"10.1016\/S0010-8545(99)00031-4","volume":"188","author":"Allen A. E.","year":"1999","journal-title":"Coord. Chem. Rev."},{"key":"ref2\/cit2b","doi-asserted-by":"crossref","first-page":"143","DOI":"10.1016\/S0010-8545(01)00423-4","volume":"226","author":"Matsubayashi G.","year":"2002","journal-title":"Coord. Chem. Rev."},{"key":"ref2\/cit2c","first-page":"399","volume":"52","author":"Faulmann C.","year":"2004","journal-title":"Prog. Inorg. Chem."},{"key":"ref2\/cit2d","first-page":"315","volume":"52","author":"Cummings S. D.","year":"2004","journal-title":"Prog. Inorg. Chem."},{"key":"ref3\/cit3a","doi-asserted-by":"crossref","first-page":"2757","DOI":"10.1021\/cr950061t","volume":"96","author":"Hille R.","year":"1996","journal-title":"Chem. Rev."},{"key":"ref3\/cit3b","doi-asserted-by":"crossref","first-page":"2817","DOI":"10.1021\/cr950063d","volume":"96","author":"Johnson M. K.","year":"1996","journal-title":"Chem. Rev."},{"key":"ref3\/cit3c","first-page":"539","volume":"52","author":"McMaster J.","year":"2004","journal-title":"Prog. Inorg. Chem."},{"key":"ref4\/cit4","doi-asserted-by":"crossref","first-page":"1562","DOI":"10.1016\/j.jinorgbio.2007.06.040","volume":"101","author":"Young C. G.","year":"2007","journal-title":"J. Inorg. Biochem."},{"key":"ref5\/cit5","doi-asserted-by":"crossref","first-page":"14","DOI":"10.1021\/ic00326a005","volume":"29","author":"Coyle C. L.","year":"1990","journal-title":"Inorg. Chem."},{"key":"ref6\/cit6","doi-asserted-by":"crossref","first-page":"4334","DOI":"10.1021\/ic990204k","volume":"38","author":"Wang K.","year":"1999","journal-title":"Inorg. Chem."},{"key":"ref7\/cit7","doi-asserted-by":"crossref","first-page":"889","DOI":"10.1351\/pac199870040889","volume":"70","author":"Stiefel E. I.","year":"1998","journal-title":"Pure Appl. Chem."},{"key":"ref8\/cit8","doi-asserted-by":"crossref","first-page":"6437","DOI":"10.1021\/ja00280a079","volume":"108","author":"Halbert T. R.","year":"1986","journal-title":"J. Am. Chem. Soc."},{"key":"ref9\/cit9a","doi-asserted-by":"crossref","first-page":"841","DOI":"10.1021\/ic00108a015","volume":"34","author":"Murray H. H.","year":"1995","journal-title":"Inorg. Chem."},{"key":"ref9\/cit9b","doi-asserted-by":"crossref","first-page":"964","DOI":"10.1021\/ic980674z","volume":"38","author":"McConnachie C. A.","year":"1999","journal-title":"Inorg. Chem."},{"key":"ref9\/cit9c","doi-asserted-by":"crossref","first-page":"234","DOI":"10.1023\/A:1013916126612","volume":"27","author":"Dessapt R.","year":"2002","journal-title":"Trans. Met. Chem."},{"key":"ref10\/cit10","doi-asserted-by":"crossref","first-page":"4546","DOI":"10.1039\/B307753E","author":"Garriga J. M.","year":"2003","journal-title":"Dalton Trans."},{"key":"ref11\/cit11a","doi-asserted-by":"crossref","first-page":"12076","DOI":"10.1021\/ja0474244","volume":"126","author":"Llusar R.","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"ref11\/cit11b","doi-asserted-by":"crossref","first-page":"3440","DOI":"10.1039\/b703551a","volume":"17","author":"Alberola A.","year":"2007","journal-title":"J. Mater. Chem."},{"key":"ref12\/cit12","doi-asserted-by":"crossref","first-page":"9400","DOI":"10.1021\/ic8009546","volume":"47","author":"Llusar R.","year":"2008","journal-title":"Inorg. Chem."},{"key":"ref13\/cit13","doi-asserted-by":"crossref","first-page":"341","DOI":"10.1016\/S0277-5387(00)84931-1","volume":"5","author":"Harmer M. A.","year":"1986","journal-title":"Polyhedron"},{"key":"ref14\/cit14a","doi-asserted-by":"crossref","first-page":"195","DOI":"10.1002\/mas.10005","volume":"20","author":"Alcami M.","year":"2001","journal-title":"Mass Spectrom. Rev."},{"key":"ref14\/cit14b","doi-asserted-by":"crossref","first-page":"289","DOI":"10.1016\/S1387-3806(03)00087-3","volume":"227","author":"Armentrout P. B.","year":"2003","journal-title":"Int. J. Mass Spectrom."},{"key":"ref14\/cit14c","doi-asserted-by":"crossref","first-page":"2336","DOI":"10.1002\/anie.200461698","volume":"44","author":"Bohme D. K.","year":"2005","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref14\/cit14d","first-page":"1","volume":"22","author":"Schr\u00f6der D.","year":"2007","journal-title":"Top. Organomet. Chem."},{"key":"ref14\/cit14e","doi-asserted-by":"crossref","first-page":"18108","DOI":"10.1073\/pnas.0801539105","volume":"105","author":"Johnson G. E.","year":"2008","journal-title":"Proc. Natl. Acad. Sci. U.S.A."},{"key":"ref14\/cit14f","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.cplett.2009.04.003","volume":"475","author":"Johnson G. E.","year":"2009","journal-title":"Chem. Phys. Lett."},{"key":"ref14\/cit14g","doi-asserted-by":"crossref","first-page":"666","DOI":"10.1016\/j.ccr.2008.06.007","volume":"253","author":"Roithova J.","year":"2009","journal-title":"Coord. Chem. Rev."},{"key":"ref14\/cit14h","doi-asserted-by":"crossref","first-page":"1170","DOI":"10.1021\/cr900183p","volume":"110","author":"Roithova J.","year":"2010","journal-title":"Chem. Rev."},{"key":"ref15\/cit15","doi-asserted-by":"crossref","first-page":"1469","DOI":"10.1039\/b516348j","author":"O'Hair R. A. J.","year":"2006","journal-title":"Chem. Commun"},{"key":"ref16\/cit16a","doi-asserted-by":"crossref","first-page":"2832","DOI":"10.1002\/anie.200200560","volume":"42","author":"Chen P.","year":"2003","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref16\/cit16b","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.ijms.2004.12.015","volume":"243","author":"Bernhardt T. M.","year":"2005","journal-title":"Int. J. Mass Spectrom."},{"key":"ref17\/cit17a","doi-asserted-by":"crossref","first-page":"3384","DOI":"10.1021\/ja028839x","volume":"125","author":"Waters T.","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"ref17\/cit17b","doi-asserted-by":"crossref","first-page":"4010","DOI":"10.1039\/b410336j","author":"Feyel S.","year":"2004","journal-title":"Dalton Trans."},{"key":"ref17\/cit17c","doi-asserted-by":"crossref","first-page":"10089","DOI":"10.1021\/jp047592i","volume":"108","author":"Yang X.","year":"2004","journal-title":"J. Phys. Chem. A"},{"key":"ref17\/cit17d","doi-asserted-by":"crossref","first-page":"3356","DOI":"10.1021\/ic050288z","volume":"44","author":"Waters T.","year":"2005","journal-title":"Inorg. Chem."},{"key":"ref17\/cit17e","doi-asserted-by":"crossref","first-page":"10512","DOI":"10.1021\/jp055122y","volume":"109","author":"Zhai H. J.","year":"2005","journal-title":"J. Phys. Chem. A"},{"key":"ref17\/cit17f","doi-asserted-by":"crossref","first-page":"11771","DOI":"10.1021\/jp054666x","volume":"109","author":"Waters T.","year":"2005","journal-title":"J. Phys. Chem. A"},{"key":"ref17\/cit17g","doi-asserted-by":"crossref","first-page":"10737","DOI":"10.1021\/jp063594m","volume":"110","author":"Waters T.","year":"2006","journal-title":"J. Phys. Chem. A"},{"key":"ref17\/cit17h","doi-asserted-by":"crossref","first-page":"12550","DOI":"10.1021\/jp804263q","volume":"112","author":"Vicent C.","year":"2008","journal-title":"J. Phys. Chem. A"},{"key":"ref17\/cit17i","doi-asserted-by":"crossref","first-page":"177","DOI":"10.1007\/s10876-008-0228-z","volume":"20","author":"Llusar R.","year":"2009","journal-title":"J. Clust. Sci."},{"key":"ref17\/cit17j","doi-asserted-by":"crossref","first-page":"598","DOI":"10.1021\/ic8016326","volume":"48","author":"Ma M. T.","year":"2009","journal-title":"Inorg. Chem."},{"key":"ref17\/cit17k","doi-asserted-by":"crossref","first-page":"5452","DOI":"10.1002\/anie.200901348","volume":"48","author":"Vila-Nadal L.","year":"2009","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref18\/cit18a","doi-asserted-by":"crossref","first-page":"6425","DOI":"10.1021\/ic0342907","volume":"42","author":"Dessapt R.","year":"2003","journal-title":"Inorg. Chem."},{"key":"ref18\/cit18b","doi-asserted-by":"crossref","first-page":"190","DOI":"10.1039\/b311151b","volume":"2","author":"Waters T.","year":"2004","journal-title":"Org. Biomol. Chem."},{"key":"ref18\/cit18c","doi-asserted-by":"crossref","first-page":"5119","DOI":"10.1021\/ja039652o","volume":"126","author":"Waters T.","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"ref18\/cit18d","doi-asserted-by":"crossref","first-page":"205","DOI":"10.1016\/j.ijms.2005.03.002","volume":"243","author":"Lavanant H.","year":"2005","journal-title":"Int. J. Mass Spectrom."},{"key":"ref19\/cit19","doi-asserted-by":"crossref","first-page":"8937","DOI":"10.1021\/ic0508728","volume":"44","author":"Llusar R.","year":"2005","journal-title":"Inorg. Chem."},{"key":"ref20\/cit20a","unstructured":"aSakane, G. and Shibahara, T.Transition Metal Sulfur Chemistry: Biological and Industrial Significance;Stiefel, E. I. and Matsumoto, K., Eds.American Chemical Society:Washington, DC, 1996; Vol.653, p225;"},{"key":"ref20\/cit20b","doi-asserted-by":"crossref","first-page":"45","DOI":"10.1016\/S0898-8838(08)60128-2","volume":"44","author":"Saito T.","year":"1997","journal-title":"Adv. Inorg. Chem."},{"key":"ref20\/cit20c","doi-asserted-by":"crossref","unstructured":"cLlusar, R. and Vicent, C.Trinuclear Molybdenum and Tungsten Cluster Chalcogenides: From Solid State to Molecular Materials. Inorganic Chemistry in Focus III;Meyer, G., Naumann, D., and Wesemann, L., Eds.Wiley-VCH Verlag:Weinheim, Germany, 2006; p105;","DOI":"10.1002\/9783527609932.ch7"},{"key":"ref20\/cit20d","doi-asserted-by":"crossref","first-page":"529","DOI":"10.1070\/RC2007v076n06ABEH003707","volume":"76","author":"Fedorov V. E.","year":"2007","journal-title":"Russ. Chem. Rev."},{"key":"ref20\/cit20e","doi-asserted-by":"crossref","first-page":"1534","DOI":"10.1016\/j.ccr.2009.12.026","volume":"254","author":"Llusar R.","year":"2010","journal-title":"Coord. Chem. Rev."},{"key":"ref21\/cit21a","doi-asserted-by":"crossref","first-page":"7334","DOI":"10.1021\/ja0034085","volume":"123","author":"Jiao H.","year":"2001","journal-title":"J. Am. Chem. Soc."},{"key":"ref21\/cit21b","doi-asserted-by":"crossref","first-page":"67","DOI":"10.1016\/j.theochem.2005.02.073","volume":"726","author":"Yao X.-Q.","year":"2005","journal-title":"J. Mol. Struct. TEOCHEM"},{"key":"ref21\/cit21c","doi-asserted-by":"crossref","first-page":"81","DOI":"10.1016\/j.theochem.2005.02.074","volume":"726","author":"Yao X.-Q.","year":"2005","journal-title":"J. Mol. Struct. TEOCHEM"},{"key":"ref21\/cit21d","doi-asserted-by":"crossref","first-page":"13704","DOI":"10.1021\/jp0518153","volume":"109","author":"Zeng T.","year":"2005","journal-title":"J. Phys. Chem. B"},{"key":"ref21\/cit21e","doi-asserted-by":"crossref","first-page":"2778","DOI":"10.1021\/jp065646d","volume":"111","author":"Murugan P.","year":"2007","journal-title":"J. Phys. Chem. A"},{"key":"ref22\/cit22","doi-asserted-by":"crossref","first-page":"973","DOI":"10.1007\/BF02252166","volume":"35","author":"Tkachenko S. E.","year":"1999","journal-title":"Chem. Heterocycl. Compd."},{"key":"ref23\/cit23","doi-asserted-by":"crossref","first-page":"39","DOI":"10.1016\/S0020-1693(00)83936-5","volume":"167","author":"Fedin V. P.","year":"1990","journal-title":"Inorg. Chim. Acta"},{"key":"ref24\/cit24","doi-asserted-by":"crossref","first-page":"275","DOI":"10.1016\/S0020-1693(00)80312-6","volume":"174","author":"Fedin V. P.","year":"1990","journal-title":"Inorg. Chim. Acta"},{"key":"ref25\/cit25","doi-asserted-by":"crossref","first-page":"2419","DOI":"10.1016\/S0277-5387(89)80005-1","volume":"8","author":"Fedin V. P.","year":"1989","journal-title":"Polyhedron"},{"key":"ref26\/cit26a","volume-title":"SAINT","year":"2001"},{"key":"ref26\/cit26b","volume-title":"SADABS, empirical absorption program","author":"Sheldrick G. M.","year":"2001"},{"key":"ref27\/cit27","volume-title":"SHELXTL","author":"Sheldrick G. M.","year":"1997"},{"key":"ref28\/cit28","volume-title":"Gaussian03","author":"Frisch M. J.","year":"2003"},{"key":"ref29\/cit29a","doi-asserted-by":"crossref","first-page":"3098","DOI":"10.1103\/PhysRevA.38.3098","volume":"38","author":"Becke A. D.","year":"1988","journal-title":"Phys. Rev. A."},{"key":"ref29\/cit29b","doi-asserted-by":"crossref","first-page":"785","DOI":"10.1103\/PhysRevB.37.785","volume":"37","author":"Lee C. T.","year":"1988","journal-title":"Phys. Rev. B"},{"key":"ref29\/cit29c","doi-asserted-by":"crossref","first-page":"1372","DOI":"10.1063\/1.464304","volume":"98","author":"Becke A. D.","year":"1993","journal-title":"J. Chem. Phys."},{"key":"ref30\/cit30","doi-asserted-by":"crossref","first-page":"2257","DOI":"10.1063\/1.1677527","volume":"56","author":"Hehre W. J.","year":"1972","journal-title":"J. Chem. Phys."},{"key":"ref31\/cit31","doi-asserted-by":"crossref","first-page":"5852","DOI":"10.1021\/j100124a012","volume":"97","author":"Dolg M.","year":"1993","journal-title":"J. Phys. Chem."},{"key":"ref32\/cit32","doi-asserted-by":"crossref","first-page":"4336","DOI":"10.1021\/ic00023a010","volume":"30","author":"Zimmermann H.","year":"1991","journal-title":"Inorg. Chem."},{"key":"ref33\/cit33","doi-asserted-by":"crossref","first-page":"362","DOI":"10.1002\/mas.10008","volume":"20","author":"Cech N. B.","year":"2001","journal-title":"Mass Spectrom. Rev."},{"key":"ref34\/cit34","doi-asserted-by":"crossref","first-page":"873","DOI":"10.1021\/ic00004a056","volume":"30","author":"Hegetschweiler K.","year":"1991","journal-title":"Inorg. Chem."},{"key":"ref35\/cit35","doi-asserted-by":"crossref","first-page":"1659","DOI":"10.1002\/hlca.19920750521","volume":"75","author":"Hegetschweiler K.","year":"1992","journal-title":"Helv. Chim. Acta"},{"key":"ref36\/cit36a","doi-asserted-by":"crossref","first-page":"10359","DOI":"10.1021\/jp027674b","volume":"107","author":"Lightstone J. M.","year":"2003","journal-title":"J. Phys. Chem. B"},{"key":"ref36\/cit36b","doi-asserted-by":"crossref","first-page":"429","DOI":"10.1016\/j.cplett.2005.07.109","volume":"413","author":"Lightstone J. M.","year":"2005","journal-title":"Chem. Phys. Lett."},{"key":"ref36\/cit36c","doi-asserted-by":"crossref","first-page":"161","DOI":"10.1007\/s00339-005-3345-7","volume":"82","author":"Gemming S.","year":"2006","journal-title":"Appl. Phys. A: Mater. Sci. Process."},{"key":"ref36\/cit36d","doi-asserted-by":"crossref","first-page":"12011","DOI":"10.1021\/jp807318c","volume":"112","author":"Patterson M. J.","year":"2008","journal-title":"J. Phys. Chem. A"},{"key":"ref37\/cit37a","doi-asserted-by":"crossref","first-page":"157","DOI":"10.1016\/S0020-1693(00)83826-8","volume":"213","author":"Meienberger M. D.","year":"1993","journal-title":"Inorg. Chim. Acta"},{"key":"ref37\/cit37b","doi-asserted-by":"crossref","first-page":"8116","DOI":"10.1021\/ic050962c","volume":"44","author":"Sokolov M. N.","year":"2005","journal-title":"Inorg. Chem."},{"key":"ref38\/cit38","doi-asserted-by":"crossref","first-page":"1329","DOI":"10.1002\/anie.200301728","volume":"43","author":"Schr\u00f6der D.","year":"2004","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref39\/cit39","doi-asserted-by":"crossref","first-page":"3520","DOI":"10.1002\/anie.200600640","volume":"45","author":"Sugimoto H.","year":"2006","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref40\/cit40","doi-asserted-by":"crossref","first-page":"9372","DOI":"10.1021\/ja00024a055","volume":"113","author":"Pilato R. S.","year":"1991","journal-title":"J. Am. Chem. Soc."},{"key":"ref41\/cit41","doi-asserted-by":"crossref","first-page":"2625","DOI":"10.1021\/ja9841761","volume":"121","author":"George G. N.","year":"1999","journal-title":"J. Am. Chem. Soc."},{"key":"ref42\/cit42","first-page":"162","volume":"33","author":"Fedin V. P.","year":"2001","journal-title":"Inorg. Synth."}],"container-title":["Inorganic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/ic1010693","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,4,5]],"date-time":"2023-04-05T12:49:43Z","timestamp":1680698983000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/ic1010693"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2010,8,9]]},"references-count":86,"journal-issue":{"issue":"17","published-print":{"date-parts":[[2010,9,6]]}},"alternative-id":["10.1021\/ic1010693"],"URL":"https:\/\/doi.org\/10.1021\/ic1010693","relation":{},"ISSN":["0020-1669","1520-510X"],"issn-type":[{"value":"0020-1669","type":"print"},{"value":"1520-510X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2010,8,9]]}}}