{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T01:40:01Z","timestamp":1791250801447,"version":"4.1.0"},"reference-count":86,"publisher":"American Chemical Society (ACS)","issue":"16","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Inorg. Chem."],"published-print":{"date-parts":[[2011,8,15]]},"DOI":"10.1021\/ic2011315","type":"journal-article","created":{"date-parts":[[2011,7,14]],"date-time":"2011-07-14T13:29:04Z","timestamp":1310650144000},"page":"7650-7661","source":"Crossref","is-referenced-by-count":61,"title":["Group 6 Complexes with Iron and Zinc Heterometals: Understanding the Structural, Spectroscopic, and Electrochemical Properties of a Complete Series of MM\u00b7\u00b7\u00b7M\u2032 Compounds"],"prefix":"10.1021","volume":"50","author":[{"given":"Michael","family":"Nippe","sequence":"first","affiliation":[{"name":"Department of Chemistry, University of Wisconsin\u2014Madison, 1101 University Ave., Madison, Wisconsin 53706, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eckhard","family":"Bill","sequence":"additional","affiliation":[{"name":"Max-Planck-Institut f\u00fcr Bioanorganische Chemie, Stiftstrasse 34-36\rD-45470 M\u00fclheim an der Ruhr, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"John F.","family":"Berry","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Wisconsin\u2014Madison, 1101 University Ave., Madison, Wisconsin 53706, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2011,7,14]]},"reference":[{"key":"ref1\/cit1","volume-title":"Struct. Bonding (Berlin)","volume":"136","author":"Berry J. F.","year":"2010"},{"key":"ref2\/cit2a","doi-asserted-by":"crossref","first-page":"123","DOI":"10.1021\/ja108575t","volume":"133","author":"Harris T. D.","year":"2011","journal-title":"J. Am. Chem. Soc."},{"key":"ref2\/cit2b","doi-asserted-by":"crossref","first-page":"9336","DOI":"10.1021\/ja020552c","volume":"124","author":"Liao Y.","year":"2002","journal-title":"J. Am. Chem. Soc."},{"key":"ref2\/cit2c","doi-asserted-by":"crossref","unstructured":"Verdaguer, M.; Girolami, G. S.InMagnetism Molecules to Materials V;Springer-Verlag: Berlin, 2005; pp283.","DOI":"10.1002\/9783527620548.ch9d"},{"key":"ref3\/cit3","doi-asserted-by":"crossref","first-page":"692","DOI":"10.1021\/ja109128r","volume":"133","author":"Navulla A.","year":"2011","journal-title":"J. Am. Chem. Soc."},{"key":"ref4\/cit4","doi-asserted-by":"crossref","first-page":"6945","DOI":"10.1021\/ic9010357","volume":"48","author":"Stavila V.","year":"2009","journal-title":"Inorg. Chem."},{"key":"ref5\/cit5a","doi-asserted-by":"crossref","first-page":"1352","DOI":"10.1021\/ar1000605","volume":"43","author":"Diaconescu P. L.","year":"2010","journal-title":"Acc. Chem. Res."},{"key":"ref5\/cit5b","doi-asserted-by":"crossref","first-page":"5790","DOI":"10.1039\/c0cc01272f","volume":"46","author":"Thomas C. M.","year":"2010","journal-title":"Chem. Commun."},{"key":"ref6\/cit6a","doi-asserted-by":"crossref","first-page":"567","DOI":"10.1021\/om020780f","volume":"22","author":"Shafir A.","year":"2003","journal-title":"Organometallics"},{"key":"ref6\/cit6b","doi-asserted-by":"crossref","first-page":"248","DOI":"10.1021\/ar9001729","volume":"43","author":"Mandal S. K.","year":"2010","journal-title":"Acc. Chem. Res."},{"key":"ref6\/cit6c","doi-asserted-by":"crossref","first-page":"3615","DOI":"10.1002\/ejic.201000365","author":"Hildebrandt A.","year":"2010","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref6\/cit6d","doi-asserted-by":"crossref","first-page":"4149","DOI":"10.1039\/b710470g","author":"Nikiforov G. B.","year":"2007","journal-title":"Dalton Trans."},{"key":"ref6\/cit6e","doi-asserted-by":"crossref","first-page":"5287","DOI":"10.1016\/j.tet.2007.03.140","volume":"63","author":"Belokon Y. N.","year":"2007","journal-title":"Tetrahedron"},{"key":"ref6\/cit6f","doi-asserted-by":"crossref","first-page":"62","DOI":"10.1007\/s10562-007-9074-0","volume":"115","author":"Kawthekar R. B.","year":"2007","journal-title":"Catal. Lett."},{"key":"ref6\/cit6g","author":"Zhou W.","year":"2011","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref7\/cit7a","doi-asserted-by":"crossref","first-page":"2310","DOI":"10.1021\/bi900044e","volume":"48","author":"Groysman S.","year":"2009","journal-title":"Biochemistry"},{"key":"ref7\/cit7b","doi-asserted-by":"crossref","first-page":"1077","DOI":"10.1021\/cr0206162","volume":"104","author":"Kim E.","year":"2004","journal-title":"Chem. Rev."},{"key":"ref7\/cit7c","doi-asserted-by":"crossref","first-page":"1135","DOI":"10.1021\/cr0206216","volume":"104","author":"Lee S. C.","year":"2004","journal-title":"Chem. Rev."},{"key":"ref7\/cit7d","doi-asserted-by":"crossref","first-page":"2239","DOI":"10.1021\/cr9500390","volume":"96","author":"Holm R. H.","year":"1996","journal-title":"Chem. Rev."},{"key":"ref8\/cit8a","doi-asserted-by":"crossref","first-page":"5668","DOI":"10.1002\/ejic.201000896","author":"Pal K.","year":"2010","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref8\/cit8b","doi-asserted-by":"crossref","first-page":"299","DOI":"10.1246\/bcsj.20090281","volume":"83","author":"Mashima K.","year":"2010","journal-title":"Bull. Chem. Soc. Jpn."},{"key":"ref8\/cit8c","doi-asserted-by":"crossref","first-page":"1879","DOI":"10.1021\/ic801398f","volume":"48","author":"Mashima K.","year":"2009","journal-title":"Inorg. Chem."},{"key":"ref8\/cit8d","doi-asserted-by":"crossref","first-page":"235","DOI":"10.1002\/ejic.200601018","author":"Mashima K.","year":"2007","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref9\/cit9","doi-asserted-by":"crossref","first-page":"6702","DOI":"10.1021\/ic062474q","volume":"46","author":"Ohashi M.","year":"2007","journal-title":"Inorg. Chem."},{"key":"ref10\/cit10","doi-asserted-by":"crossref","first-page":"577","DOI":"10.1039\/B817032K","author":"Liu I. P. C.","year":"2009","journal-title":"Chem. Commun."},{"key":"ref11\/cit11","doi-asserted-by":"crossref","first-page":"1767","DOI":"10.1002\/ejic.200701159","author":"Huang G. C.","year":"2008","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref12\/cit12","doi-asserted-by":"crossref","first-page":"543","DOI":"10.1002\/zaac.201100061","volume":"637","author":"Aydin-Canturk D.","year":"2011","journal-title":"Z. Anorg. Allg. Chem."},{"key":"ref13\/cit13","doi-asserted-by":"crossref","first-page":"14261","DOI":"10.1021\/ja106510g","volume":"132","author":"Nippe M.","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"ref14\/cit14","doi-asserted-by":"crossref","first-page":"12684","DOI":"10.1021\/ja076337j","volume":"129","author":"Nippe M.","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"ref15\/cit15","doi-asserted-by":"crossref","first-page":"5569","DOI":"10.1002\/ejic.200801001","author":"Nippe M.","year":"2008","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref16\/cit16a","unstructured":"Berry, J. F.InMultiple Bonds Between Metal Atoms,3rd ed.Cotton, F. A.; Murillo, C. A.; Walton, R. A., Eds.Springer Science and Business Media, Inc.:New York, 2005; pp669."},{"key":"ref16\/cit16b","volume-title":"Redox Systems under Nano-Space Control","author":"Yeh C. Y.","year":"2006"},{"key":"ref17\/cit17a","doi-asserted-by":"crossref","first-page":"2418","DOI":"10.1021\/ic0262740","volume":"42","author":"Berry J. F.","year":"2003","journal-title":"Inorg. Chem."},{"key":"ref17\/cit17b","doi-asserted-by":"crossref","first-page":"7082","DOI":"10.1021\/ja049055h","volume":"126","author":"Berry J. F.","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"ref18\/cit18a","doi-asserted-by":"crossref","first-page":"53","DOI":"10.1016\/j.theochem.2006.08.040","volume":"777","author":"Lopez X.","year":"2006","journal-title":"THEOCHEM"},{"key":"ref18\/cit18b","doi-asserted-by":"crossref","first-page":"3932","DOI":"10.1021\/ic051799o","volume":"45","author":"Benard M.","year":"2006","journal-title":"Inorg. Chem."},{"key":"ref18\/cit18c","doi-asserted-by":"crossref","first-page":"333","DOI":"10.1023\/A:1020546915168","volume":"13","author":"Rohmer M. M.","year":"2002","journal-title":"J. Cluster Sci."},{"key":"ref18\/cit18d","doi-asserted-by":"crossref","first-page":"9126","DOI":"10.1021\/ja0103142","volume":"123","author":"Rohmer M. M.","year":"2001","journal-title":"J. Am. Chem. Soc."},{"key":"ref19\/cit19","doi-asserted-by":"crossref","first-page":"2368","DOI":"10.1039\/b106100n","author":"Benbellat N.","year":"2001","journal-title":"Chem. Commun."},{"key":"ref20\/cit20a","doi-asserted-by":"crossref","first-page":"608","DOI":"10.1039\/B715021K","author":"Pantazis D. A.","year":"2008","journal-title":"Dalton Trans."},{"key":"ref20\/cit20b","doi-asserted-by":"crossref","first-page":"4128","DOI":"10.1021\/ja0581402","volume":"128","author":"Pantazis D. A.","year":"2006","journal-title":"J. Am. Chem. Soc."},{"key":"ref21\/cit21","doi-asserted-by":"crossref","first-page":"165","DOI":"10.1021\/nl0519027","volume":"6","author":"Chae D. H.","year":"2006","journal-title":"Nano Lett."},{"key":"ref22\/cit22a","doi-asserted-by":"crossref","first-page":"3641","DOI":"10.1021\/jp907893q","volume":"114","author":"Tsai T. W.","year":"2010","journal-title":"J. Phys. Chem. C"},{"key":"ref22\/cit22b","doi-asserted-by":"crossref","first-page":"1338","DOI":"10.1039\/b916677g","volume":"46","author":"Shih K. N.","year":"2010","journal-title":"Chem. Commun."},{"key":"ref22\/cit22c","doi-asserted-by":"crossref","first-page":"5814","DOI":"10.1002\/anie.200600800","volume":"45","author":"Chen I. W. P.","year":"2006","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref22\/cit22d","doi-asserted-by":"crossref","first-page":"959","DOI":"10.1021\/jp035415w","volume":"108","author":"Lin S. Y.","year":"2004","journal-title":"J. Phys. Chem. B"},{"key":"ref23\/cit23","doi-asserted-by":"crossref","first-page":"5591","DOI":"10.1021\/ic100493t","volume":"49","author":"Georgiev V. P.","year":"2010","journal-title":"Inorg. Chem."},{"key":"ref24\/cit24","doi-asserted-by":"crossref","first-page":"7082","DOI":"10.1021\/ja049055h","volume":"126","author":"Berry J. F.","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"ref25\/cit25","doi-asserted-by":"crossref","first-page":"6226","DOI":"10.1021\/ja000515q","volume":"122","author":"Clerac R.","year":"2000","journal-title":"J. Am. Chem. Soc."},{"key":"ref26\/cit26","doi-asserted-by":"crossref","first-page":"11889","DOI":"10.1021\/ic901965b","volume":"48","author":"Nippe M.","year":"2009","journal-title":"Inorg. Chem."},{"key":"ref27\/cit27","doi-asserted-by":"crossref","DOI":"10.1007\/b136230","volume-title":"Multiple Bonds between Metal Atoms","author":"Cotton F. A.","year":"2005","edition":"3"},{"key":"ref28\/cit28","doi-asserted-by":"crossref","first-page":"82","DOI":"10.1016\/S0020-1693(99)00049-3","volume":"288","author":"Suen M. C.","year":"1999","journal-title":"Inorg. Chim. Acta"},{"key":"ref29\/cit29a","doi-asserted-by":"crossref","first-page":"789","DOI":"10.1039\/dt9930000789","author":"Edema J. J. H.","year":"1993","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ref29\/cit29b","doi-asserted-by":"crossref","first-page":"6856","DOI":"10.1021\/ja9912675","volume":"121","author":"Cotton F. A.","year":"1999","journal-title":"J. Am. Chem. Soc."},{"key":"ref30\/cit30","doi-asserted-by":"crossref","first-page":"1394","DOI":"10.1021\/ic50184a002","volume":"17","author":"Long G. J.","year":"1978","journal-title":"Inorg. Chem."},{"key":"ref31\/cit31a","doi-asserted-by":"crossref","first-page":"4633","DOI":"10.1021\/ic025617r","volume":"41","author":"Gebbink R.","year":"2002","journal-title":"Inorg. Chem."},{"key":"ref31\/cit31b","doi-asserted-by":"crossref","first-page":"4642","DOI":"10.1021\/ic025616z","volume":"41","author":"Goldsmith C. R.","year":"2002","journal-title":"Inorg. Chem."},{"key":"ref31\/cit31c","doi-asserted-by":"crossref","first-page":"4578","DOI":"10.1039\/b507687k","author":"Wong E. L. M.","year":"2005","journal-title":"Chem. Commun."},{"key":"ref32\/cit32a","doi-asserted-by":"crossref","first-page":"1353","DOI":"10.1002\/ejic.200501022","author":"Quesada M.","year":"2006","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref32\/cit32b","doi-asserted-by":"crossref","first-page":"1073","DOI":"10.1002\/ejic.200601034","author":"Neville S. M.","year":"2007","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref33\/cit33","doi-asserted-by":"crossref","first-page":"2004","DOI":"10.1021\/ic50185a063","volume":"17","author":"Cotton F. A.","year":"1978","journal-title":"Inorg. Chem."},{"key":"ref34\/cit34","doi-asserted-by":"crossref","first-page":"176","DOI":"10.1021\/ic50179a034","volume":"17","author":"Cotton F. A.","year":"1978","journal-title":"Inorg. Chem."},{"key":"ref35\/cit35","doi-asserted-by":"crossref","first-page":"1292","DOI":"10.1021\/ic50218a065","volume":"20","author":"Cotton F. A.","year":"1981","journal-title":"Inorg. Chem."},{"key":"ref36\/cit36","doi-asserted-by":"crossref","first-page":"3450","DOI":"10.1021\/ic00190a005","volume":"23","author":"Ardon M.","year":"1984","journal-title":"Inorg. Chem."},{"key":"ref38\/cit38","doi-asserted-by":"crossref","first-page":"235","DOI":"10.1021\/cr9900275","volume":"100","author":"Solomon E. I.","year":"2000","journal-title":"Chem. Rev."},{"key":"ref39\/cit39","doi-asserted-by":"crossref","first-page":"3425","DOI":"10.1021\/ic50213a042","volume":"19","author":"Rice S. F.","year":"1980","journal-title":"Inorg. Chem."},{"key":"ref40\/cit40","doi-asserted-by":"crossref","first-page":"1664","DOI":"10.1107\/S0567740871004527","volume":"27","author":"Cotton F. A.","year":"1971","journal-title":"Acta Crystallogr., Sect. B"},{"key":"ref41\/cit41","doi-asserted-by":"crossref","first-page":"483","DOI":"10.1021\/ar980116o","volume":"33","author":"Cotton F. A.","year":"2000","journal-title":"Acc. Chem. Res."},{"key":"ref42\/cit42","doi-asserted-by":"crossref","first-page":"8476","DOI":"10.1021\/ic050406i","volume":"44","author":"Ferrante F.","year":"2005","journal-title":"Inorg. Chem."},{"key":"ref43\/cit43","doi-asserted-by":"crossref","first-page":"3022","DOI":"10.1039\/B305304K","author":"Cl\u00e9rac R.","year":"2003","journal-title":"Dalton Trans."},{"key":"ref44\/cit44a","doi-asserted-by":"crossref","first-page":"3847","DOI":"10.1016\/j.ica.2004.02.041","volume":"357","author":"Berry J. F.","year":"2004","journal-title":"Inorg. Chim. Acta"},{"key":"ref44\/cit44b","doi-asserted-by":"crossref","first-page":"69","DOI":"10.1016\/S0020-1693(00)00115-8","volume":"305","author":"Cotton F. A.","year":"2000","journal-title":"Inorg. Chim. Acta"},{"key":"ref44\/cit44c","doi-asserted-by":"crossref","first-page":"2678","DOI":"10.1021\/ic0514795","volume":"45","author":"Muller-Buschbaum K.","year":"2006","journal-title":"Inorg. Chem."},{"key":"ref45\/cit45","doi-asserted-by":"crossref","first-page":"8980","DOI":"10.1021\/ja00049a031","volume":"114","author":"Cotton F. A.","year":"1992","journal-title":"J. Am. Chem. Soc."},{"key":"ref46\/cit46","doi-asserted-by":"crossref","first-page":"394","DOI":"10.1002\/zaac.19976230163","volume":"623","author":"Dashti A.","year":"2004","journal-title":"Z. Anorg. Allg. Chem."},{"key":"ref47\/cit47","doi-asserted-by":"crossref","first-page":"816","DOI":"10.1107\/S010827018801337X","volume":"45","author":"Bottomley F.","year":"1989","journal-title":"Acta Crystallogr., Sect. C"},{"key":"ref48\/cit48a","doi-asserted-by":"crossref","first-page":"11","DOI":"10.1016\/S0020-1693(00)85366-9","volume":"179","author":"Cotton F. A.","year":"1991","journal-title":"Inorg. Chim. Acta"},{"key":"ref48\/cit48b","doi-asserted-by":"crossref","first-page":"281","DOI":"10.1006\/jssc.2001.9157","volume":"159","author":"Zhao H.","year":"2001","journal-title":"J. Solid State Chem."},{"key":"ref49\/cit49","doi-asserted-by":"crossref","first-page":"2856","DOI":"10.1021\/ja1114248","volume":"133","author":"Nippe M.","year":"2011","journal-title":"J. Am. Chem. Soc."},{"key":"ref50\/cit50a","doi-asserted-by":"crossref","first-page":"1388","DOI":"10.1021\/ic0260670","volume":"42","author":"Cotton F. A.","year":"2003","journal-title":"Inorg. Chem."},{"key":"ref50\/cit50b","doi-asserted-by":"crossref","first-page":"317","DOI":"10.1021\/ic010925v","volume":"41","author":"Cotton F. A.","year":"2002","journal-title":"Inorg. Chem."},{"key":"ref51\/cit51","unstructured":"Nippe, M.; Berry, J. F.Unpublished results."},{"key":"ref52\/cit52","doi-asserted-by":"crossref","first-page":"186","DOI":"10.1002\/chem.200800987","volume":"15","author":"Pyykko P.","year":"2009","journal-title":"Chem.\u2014Eur. J."},{"key":"ref53\/cit53","volume-title":"SMART","year":"2009"},{"key":"ref54\/cit54","doi-asserted-by":"crossref","first-page":"339","DOI":"10.1107\/S0021889808042726","volume":"42","author":"Dolomanov O. V.","year":"2009","journal-title":"J. Appl. Crystallogr."},{"key":"ref55\/cit55","doi-asserted-by":"crossref","first-page":"7","DOI":"10.1107\/S0021889802022112","volume":"36","author":"Spek A. L.","year":"2003","journal-title":"J. Appl. Crystallogr."}],"container-title":["Inorganic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/ic2011315","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,4,6]],"date-time":"2023-04-06T15:23:50Z","timestamp":1680794630000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/ic2011315"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2011,7,14]]},"references-count":86,"journal-issue":{"issue":"16","published-print":{"date-parts":[[2011,8,15]]}},"alternative-id":["10.1021\/ic2011315"],"URL":"https:\/\/doi.org\/10.1021\/ic2011315","relation":{},"ISSN":["0020-1669","1520-510X"],"issn-type":[{"value":"0020-1669","type":"print"},{"value":"1520-510X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2011,7,14]]}}}