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Y.","year":"2010"},{"key":"ref2\/cit2","doi-asserted-by":"crossref","first-page":"3479","DOI":"10.1021\/cr900093s","volume":"10","author":"Mizuhata Y.","year":"2009","journal-title":"Chem. Rev."},{"key":"ref3\/cit3","doi-asserted-by":"crossref","DOI":"10.1002\/0470857188","volume-title":"The Chemistry of Organo Germanium, Tin, and Lead Compounds","volume":"2","author":"Rappoport Z.","year":"2002"},{"key":"ref4\/cit4","volume-title":"The Chemistry of Organosilicon Compounds","volume":"3","author":"Rappoport Z.","year":"2001"},{"key":"ref5\/cit5","doi-asserted-by":"crossref","first-page":"3877","DOI":"10.1021\/cr100133q","volume":"110","author":"Asay M.","year":"2010","journal-title":"Chem. Rev."},{"key":"ref6\/cit6","doi-asserted-by":"crossref","first-page":"317","DOI":"10.1039\/c3973000317a","author":"Davidson P. J.","year":"1973","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"ref7\/cit7a","doi-asserted-by":"crossref","first-page":"895","DOI":"10.1039\/C39740000895","author":"Harris D. H.","year":"1974","journal-title":"Chem. Commun."},{"key":"ref7\/cit7b","doi-asserted-by":"crossref","first-page":"7160","DOI":"10.1021\/ja00829a086","volume":"96","author":"Schaeffer C. D.","year":"1974","journal-title":"J. Am. Chem. Soc."},{"key":"ref8\/cit8","doi-asserted-by":"crossref","first-page":"1343","DOI":"10.1126\/science.214.4527.1343","volume":"214","author":"West R.","year":"1981","journal-title":"Science"},{"key":"ref9\/cit9","doi-asserted-by":"crossref","first-page":"6500","DOI":"10.1021\/ja301042u","volume":"134","author":"Protchenko A. V.","year":"2012","journal-title":"J. Am. Chem. Soc."},{"key":"ref10\/cit10","doi-asserted-by":"crossref","first-page":"6504","DOI":"10.1021\/ja301091v","volume":"134","author":"Rekken B. D.","year":"2012","journal-title":"J. Am. Chem. Soc."},{"key":"ref11\/cit11","doi-asserted-by":"crossref","first-page":"3524","DOI":"10.1021\/ja993346m","volume":"122","author":"Pu L.","year":"2000","journal-title":"J. Am. Chem. Soc."},{"key":"ref12\/cit12a","doi-asserted-by":"crossref","first-page":"1755","DOI":"10.1126\/science.1102209","volume":"305","author":"Sekiguchi A.","year":"2004","journal-title":"Science"},{"key":"ref12\/cit12b","doi-asserted-by":"crossref","first-page":"1327","DOI":"10.1002\/zaac.200400177","volume":"630","author":"Wiberg N.","year":"2004","journal-title":"Z. Anorg. Allg. Chem."},{"key":"ref12\/cit12c","doi-asserted-by":"crossref","first-page":"1023","DOI":"10.1021\/ja057205y","volume":"128","author":"Sugiyama Y.","year":"2006","journal-title":"J. Am. Chem. Soc."},{"key":"ref12\/cit12d","doi-asserted-by":"crossref","first-page":"5930","DOI":"10.1021\/ja0257164","volume":"124","author":"Phillips A. D.","year":"2002","journal-title":"J. Am. Chem. Soc."},{"key":"ref12\/cit12e","doi-asserted-by":"crossref","first-page":"1785","DOI":"10.1002\/1521-3773(20020517)41:10<1785::AID-ANIE1785>3.0.CO;2-6","volume":"41","author":"Stender M.","year":"2002","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref13\/cit13a","doi-asserted-by":"crossref","first-page":"12232","DOI":"10.1021\/ja053247a","volume":"127","author":"Spikes G. H.","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"ref13\/cit13b","unstructured":"As noted in this paper, hydrogen does, however, react with some main-group elements such as fluorine, although not (at that time) with main-group compounds. See:Greenwood, N. N.; Earnshaw, A.Chemistry of the Elements,2nded.Butterworth Heinemann:Oxford, U.K., 1997; p43."},{"key":"ref14\/cit14","doi-asserted-by":"crossref","DOI":"10.1007\/b113929","volume-title":"Metal Dihydrogen and \u03c3-Bond Complexes","author":"Kubas G. J.","year":"2001"},{"key":"ref15\/cit15a","doi-asserted-by":"crossref","first-page":"2091","DOI":"10.1039\/b212224c","volume":"17","author":"Power P. P.","year":"2003","journal-title":"Chem Commun."},{"key":"ref15\/cit15b","doi-asserted-by":"crossref","first-page":"4362","DOI":"10.1021\/om700365p","volume":"26","author":"Power P. P.","year":"2007","journal-title":"Organometallics"},{"key":"ref15\/cit15c","doi-asserted-by":"crossref","first-page":"10047","DOI":"10.1021\/ic700813h","volume":"46","author":"Rivard E.","year":"2007","journal-title":"Inorg. Chem."},{"key":"ref15\/cit15d","doi-asserted-by":"crossref","first-page":"238","DOI":"10.1002\/tcr.201100016","volume":"12","author":"Power P. P.","year":"2011","journal-title":"Chem. Rec."},{"key":"ref15\/cit15e","doi-asserted-by":"crossref","first-page":"627","DOI":"10.1021\/ar2000875","volume":"44","author":"Power P. P.","year":"2011","journal-title":"Acc. Chem. Res."},{"key":"ref15\/cit15f","doi-asserted-by":"crossref","first-page":"238","DOI":"10.1002\/tcr.201100016","volume":"12","author":"Power P. P.","year":"2012","journal-title":"Chem. Record"},{"key":"ref16\/cit16a","doi-asserted-by":"crossref","first-page":"1124","DOI":"10.1126\/science.1134230","volume":"314","author":"Welch G. C.","year":"2006","journal-title":"Science"},{"key":"ref16\/cit16b","doi-asserted-by":"crossref","first-page":"1880","DOI":"10.1021\/ja067961j","volume":"129","author":"Welch G. C.","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"ref16\/cit16c","doi-asserted-by":"crossref","first-page":"8526","DOI":"10.1039\/c0cc03313h","volume":"46","author":"Stephan D. W.","year":"2010","journal-title":"Chem. Commun."},{"key":"ref17\/cit17","doi-asserted-by":"crossref","first-page":"439","DOI":"10.1126\/science.1141474","volume":"316","author":"Frey G. D.","year":"2007","journal-title":"Science"},{"key":"ref18\/cit18","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1038\/nature08634","volume":"463","author":"Power P. P.","year":"2010","journal-title":"Nature"},{"key":"ref19\/cit19a","doi-asserted-by":"crossref","first-page":"451","DOI":"10.1021\/ja00314a049","volume":"106","author":"Kubas G. J.","year":"1984","journal-title":"J. Am. Chem. Soc."},{"key":"ref19\/cit19b","doi-asserted-by":"crossref","first-page":"120","DOI":"10.1021\/ar00147a005","volume":"21","author":"Kubas G. J.","year":"1988","journal-title":"Acc. Chem. Res."},{"key":"ref19\/cit19c","doi-asserted-by":"crossref","first-page":"95","DOI":"10.1021\/ar00172a001","volume":"23","author":"Crabtree R. H.","year":"1990","journal-title":"Acc. Chem. Res."},{"key":"ref19\/cit19d","doi-asserted-by":"crossref","first-page":"155","DOI":"10.1016\/0010-8545(92)80067-2","volume":"121","author":"Jessop P. G.","year":"1982","journal-title":"Coord. Chem. 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A.","year":"2013","journal-title":"Organometallics"},{"key":"ref22\/cit22","doi-asserted-by":"crossref","first-page":"8354","DOI":"10.1002\/anie.201103576","volume":"50","author":"Al-Rafia S. M. I.","year":"2011","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref23\/cit23","doi-asserted-by":"crossref","first-page":"777","DOI":"10.1021\/ja1106223","volume":"133","author":"Al-Rafia S. M. I.","year":"2011","journal-title":"J. Am. Chem. Soc."},{"key":"ref24\/cit24a","doi-asserted-by":"crossref","first-page":"1542","DOI":"10.1021\/om0610086","volume":"26","author":"Escudie J.","year":"2007","journal-title":"Organometallics"},{"key":"ref24\/cit24b","doi-asserted-by":"crossref","first-page":"4569","DOI":"10.1021\/om1007665","volume":"29","author":"Hudnall T. W.","year":"2010","journal-title":"Organometallics"},{"key":"ref24\/cit24c","doi-asserted-by":"crossref","first-page":"2763","DOI":"10.1021\/jo100427g","volume":"75","author":"Hudnall T. W.","year":"2010","journal-title":"J. Org. 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Soc."},{"key":"ref34\/cit34","doi-asserted-by":"crossref","first-page":"85","DOI":"10.1039\/B612202G","volume":"43","author":"Spikes G. H.","year":"2007","journal-title":"Chem. Commun."},{"key":"ref35\/cit35","doi-asserted-by":"crossref","first-page":"943","DOI":"10.1039\/b919828h","volume":"46","author":"Peng Y.","year":"2010","journal-title":"Chem. Commun."},{"key":"ref36\/cit36","doi-asserted-by":"crossref","first-page":"16848","DOI":"10.1021\/ja807974a","volume":"130","author":"Takeuchi K.","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"ref37\/cit37","doi-asserted-by":"crossref","first-page":"390","DOI":"10.1002\/poc.1617","volume":"23","author":"Takeuchi K.","year":"2010","journal-title":"J. Phys. Org. Chem."},{"key":"ref38\/cit38","doi-asserted-by":"crossref","first-page":"2954","DOI":"10.1021\/ja212065a","volume":"134","author":"Takeuchi K.","year":"2012","journal-title":"J. Am. Chem. Soc."},{"key":"ref39\/cit39a","doi-asserted-by":"crossref","first-page":"5534","DOI":"10.1021\/ja00384a065","volume":"104","author":"Seyferth D.","year":"1982","journal-title":"J. Am. Chem. Soc."},{"key":"ref39\/cit39b","doi-asserted-by":"crossref","first-page":"10419","DOI":"10.1021\/ja0165638","volume":"123","author":"Song Q.","year":"2001","journal-title":"J. Am. Chem. Soc."},{"key":"ref39\/cit39c","doi-asserted-by":"crossref","first-page":"199","DOI":"10.2533\/chimia.1976.199","volume":"30","author":"Sprangers W. J. J. M.","year":"1976","journal-title":"Chimia"},{"key":"ref39\/cit39d","doi-asserted-by":"crossref","first-page":"1895","DOI":"10.1039\/p29760001895","author":"Sprangers W. J. J. M.","year":"1976","journal-title":"J. Chem. Soc., Perkin Trans. 2"},{"key":"ref39\/cit39e","doi-asserted-by":"crossref","first-page":"65","DOI":"10.1021\/ar50015a001","volume":"2","author":"Brown H. C.","year":"1969","journal-title":"Acc. Chem. Res."},{"key":"ref39\/cit39f","doi-asserted-by":"crossref","first-page":"11812","DOI":"10.1021\/ja046411n","volume":"126","author":"Mason M. R.","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"ref39\/cit39g","doi-asserted-by":"crossref","first-page":"1763","DOI":"10.1039\/b601056c","author":"Li X.","year":"2006","journal-title":"Chem. Commun."},{"key":"ref39\/cit39h","doi-asserted-by":"crossref","first-page":"3332","DOI":"10.1016\/j.ica.2007.11.021","volume":"361","author":"Mason M. R.","year":"2008","journal-title":"Inorg. Chim. Acta"},{"key":"ref40\/cit40","doi-asserted-by":"crossref","first-page":"3368","DOI":"10.1021\/om050261n","volume":"24","author":"Nakata N.","year":"2005","journal-title":"Organometallics"},{"key":"ref41\/cit41a","doi-asserted-by":"crossref","first-page":"3488","DOI":"10.1002\/anie.200600987","volume":"45","author":"Lavallo V.","year":"2006","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref41\/cit41b","doi-asserted-by":"crossref","first-page":"645","DOI":"10.1016\/0040-4039(94)02341-8","volume":"36","author":"Dixon D. A.","year":"1995","journal-title":"Tetrahedron Lett."},{"key":"ref42\/cit42","doi-asserted-by":"crossref","first-page":"156","DOI":"10.1016\/S0022-328X(01)01363-8","volume":"641","author":"Bornemann H.","year":"2002","journal-title":"J. Organomet. Chem."},{"key":"ref43\/cit43","doi-asserted-by":"crossref","first-page":"6912","DOI":"10.1021\/ja9017286","volume":"131","author":"Wang X.","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"ref44\/cit44","doi-asserted-by":"crossref","first-page":"16272","DOI":"10.1021\/ja9068408","volume":"131","author":"Peng Y.","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"ref45\/cit45","doi-asserted-by":"crossref","first-page":"3768","DOI":"10.1021\/om300271c","volume":"31","author":"Brown Z. D.","year":"2012","journal-title":"Organometallics"},{"key":"ref46\/cit46","doi-asserted-by":"crossref","first-page":"617","DOI":"10.1021\/om301121x","volume":"32","author":"Brown Z. D.","year":"2013","journal-title":"Organometallics"},{"key":"ref47\/cit47","doi-asserted-by":"crossref","first-page":"1989","DOI":"10.1002\/chem.200400859","volume":"11","author":"Bourke S. C.","year":"2005","journal-title":"Chem.\u2014Eur. J."},{"key":"ref48\/cit48","doi-asserted-by":"crossref","first-page":"325","DOI":"10.1021\/ar960132q","volume":"31","author":"Reed C. A.","year":"1998","journal-title":"Acc. Chem. Res."},{"key":"ref49\/cit49","unstructured":"Lesbre, M.; Mazerolles, P.; Satg\u00e9, J.Organic Compounds of Germanium;Wiley:London, 1971; p20."},{"key":"ref50\/cit50","doi-asserted-by":"crossref","first-page":"417","DOI":"10.1021\/om060928l","volume":"26","author":"Tamm M.","year":"2007","journal-title":"Organometallics"},{"key":"ref51\/cit51","doi-asserted-by":"crossref","first-page":"751","DOI":"10.1021\/om00049a040","volume":"10","author":"Lee K. E.","year":"1991","journal-title":"Organometallics"},{"key":"ref52\/cit52","doi-asserted-by":"crossref","first-page":"3530","DOI":"10.1002\/chem.200204643","volume":"9","author":"Takeda N.","year":"2003","journal-title":"Chem.\u2014Eur. J."},{"key":"ref53\/cit53","doi-asserted-by":"crossref","first-page":"757","DOI":"10.1002\/cber.19801130233","volume":"113","author":"Jutzi P.","year":"1980","journal-title":"Chem. Ber."},{"key":"ref54\/cit54","doi-asserted-by":"crossref","first-page":"31","DOI":"10.1016\/0022-328X(87)80276-0","volume":"330","author":"Lappert M. F.","year":"1987","journal-title":"J. Organomet. Chem."},{"key":"ref55\/cit55","doi-asserted-by":"crossref","first-page":"353","DOI":"10.1039\/B813353K","author":"Hitchcock P. B.","year":"2009","journal-title":"Dalton Trans."},{"key":"ref56\/cit56","doi-asserted-by":"crossref","first-page":"C4","DOI":"10.1016\/S0022-328X(00)85535-7","volume":"212","author":"Lappert M. F.","year":"1981","journal-title":"J. Organomet. Chem."},{"key":"ref57\/cit57","doi-asserted-by":"crossref","first-page":"1546","DOI":"10.1021\/om970997n","volume":"17","author":"Schager F.","year":"1998","journal-title":"Organometallics"}],"container-title":["Inorganic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/ic4007058","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,4,30]],"date-time":"2025-04-30T10:32:27Z","timestamp":1746009147000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/ic4007058"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2013,5,17]]},"references-count":91,"journal-issue":{"issue":"11","published-print":{"date-parts":[[2013,6,3]]}},"alternative-id":["10.1021\/ic4007058"],"URL":"https:\/\/doi.org\/10.1021\/ic4007058","relation":{},"ISSN":["0020-1669","1520-510X"],"issn-type":[{"value":"0020-1669","type":"print"},{"value":"1520-510X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2013,5,17]]}}}