{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T22:01:26Z","timestamp":1792101686862,"version":"4.4.0"},"reference-count":63,"publisher":"American Chemical Society (ACS)","issue":"14","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Inorg. Chem."],"published-print":{"date-parts":[[2013,7,15]]},"DOI":"10.1021\/ic401096p","type":"journal-article","created":{"date-parts":[[2013,6,21]],"date-time":"2013-06-21T14:05:37Z","timestamp":1371823537000},"page":"8218-8227","source":"Crossref","is-referenced-by-count":49,"title":["Reactivity and M\u00f6ssbauer Spectroscopic Characterization of an Fe(IV) Ketimide Complex and Reinvestigation of an Fe(IV) Norbornyl Complex"],"prefix":"10.1021","volume":"52","author":[{"given":"Richard A.","family":"Lewis","sequence":"first","affiliation":[{"name":"Department of Chemistry and\rBiochemistry, University of California,\rSanta Barbara, California 93106, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Danil E.","family":"Smiles","sequence":"additional","affiliation":[{"name":"Department of Chemistry and\rBiochemistry, University of California,\rSanta Barbara, California 93106, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jonathan M.","family":"Darmon","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Princeton University, Princeton, New Jersey 08544,\rUnited States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"S. Chantal E.","family":"Stieber","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Princeton University, Princeton, New Jersey 08544,\rUnited States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guang","family":"Wu","sequence":"additional","affiliation":[{"name":"Department of Chemistry and\rBiochemistry, University of California,\rSanta Barbara, California 93106, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Trevor W.","family":"Hayton","sequence":"additional","affiliation":[{"name":"Department of Chemistry and\rBiochemistry, University of California,\rSanta Barbara, California 93106, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2013,6,21]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"crossref","first-page":"333","DOI":"10.1038\/nature07371","volume":"455","author":"Que L.","year":"2008","journal-title":"Nature"},{"key":"ref2\/cit2","doi-asserted-by":"crossref","first-page":"414","DOI":"10.1016\/j.ccr.2012.08.002","volume":"257","author":"McDonald A. R.","year":"2013","journal-title":"Coord. Chem. Rev."},{"key":"ref3\/cit3","doi-asserted-by":"crossref","first-page":"939","DOI":"10.1021\/cr020628n","volume":"104","author":"Costas M.","year":"2004","journal-title":"Chem. Rev."},{"key":"ref4\/cit4","doi-asserted-by":"crossref","first-page":"2227","DOI":"10.1021\/cr040653o","volume":"105","author":"Abu-Omar M. M.","year":"2005","journal-title":"Chem. Rev."},{"key":"ref5\/cit5","doi-asserted-by":"crossref","first-page":"484","DOI":"10.1021\/ar700066p","volume":"40","author":"Krebs C.","year":"2007","journal-title":"Acc. Chem. Res."},{"key":"ref6\/cit6","doi-asserted-by":"crossref","first-page":"15964","DOI":"10.1021\/ja075115i","volume":"129","author":"Mas-Ballest\u00e9 R.","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"ref7\/cit7","doi-asserted-by":"crossref","first-page":"472","DOI":"10.1021\/ja037288n","volume":"126","author":"Kaizer J.","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"ref8\/cit8","doi-asserted-by":"crossref","first-page":"522","DOI":"10.1021\/ar700027f","volume":"40","author":"Nam W.","year":"2007","journal-title":"Acc. Chem. Res."},{"key":"ref9\/cit9","doi-asserted-by":"crossref","first-page":"11880","DOI":"10.1021\/ja2040909","volume":"133","author":"England J.","year":"2011","journal-title":"J. Am. Chem. Soc."},{"key":"ref10\/cit10","doi-asserted-by":"crossref","first-page":"807","DOI":"10.1126\/science.1207661","volume":"335","author":"White M. C.","year":"2012","journal-title":"Science"},{"key":"ref11\/cit11","doi-asserted-by":"crossref","first-page":"566","DOI":"10.1126\/science.1183602","volume":"327","author":"Chen M. S.","year":"2010","journal-title":"Science"},{"key":"ref12\/cit12","doi-asserted-by":"crossref","first-page":"783","DOI":"10.1126\/science.1148597","volume":"318","author":"Chen M. S.","year":"2007","journal-title":"Science"},{"key":"ref13\/cit13","doi-asserted-by":"crossref","first-page":"19342","DOI":"10.1021\/ja2090965","volume":"133","author":"Cramer S. A.","year":"2011","journal-title":"J. Am. Chem. Soc."},{"key":"ref14\/cit14","doi-asserted-by":"crossref","first-page":"901","DOI":"10.1002\/anie.201208044","volume":"52","author":"Meyer S.","year":"2013","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref15\/cit15","doi-asserted-by":"crossref","first-page":"1037","DOI":"10.1126\/science.299.5609.1037","volume":"299","author":"Rohde J.-U.","year":"2003","journal-title":"Science"},{"key":"ref16\/cit16","doi-asserted-by":"crossref","first-page":"8635","DOI":"10.1021\/ja100366c","volume":"132","author":"England J.","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"ref17\/cit17","doi-asserted-by":"crossref","first-page":"5306","DOI":"10.1021\/ic0005238","volume":"39","author":"Grapperhaus C. A.","year":"2000","journal-title":"Inorg. Chem."},{"key":"ref18\/cit18","doi-asserted-by":"crossref","first-page":"16657","DOI":"10.1021\/ja207131g","volume":"133","author":"Xue G.","year":"2011","journal-title":"J. Am. Chem. Soc."},{"key":"ref19\/cit19","doi-asserted-by":"crossref","first-page":"7256","DOI":"10.1021\/ja111742z","volume":"133","author":"Li F.","year":"2011","journal-title":"J. Am. Chem. Soc."},{"key":"ref20\/cit20","doi-asserted-by":"crossref","first-page":"7194","DOI":"10.1021\/ja015884g","volume":"123","author":"White M. C.","year":"2001","journal-title":"J. Am. Chem. Soc."},{"key":"ref21\/cit21","doi-asserted-by":"crossref","first-page":"12814","DOI":"10.1021\/ja104934n","volume":"132","author":"Lewis R. A.","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"ref22\/cit22","volume-title":"Advanced Inorganic Chemistry","author":"Cotton F. A.","year":"1999","edition":"6"},{"key":"ref23\/cit23","doi-asserted-by":"crossref","first-page":"12063","DOI":"10.1002\/anie.201206464","volume":"51","author":"Schl\u00f6der T.","year":"2012","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref24\/cit24","doi-asserted-by":"crossref","first-page":"2512","DOI":"10.1021\/ja00762a056","volume":"94","author":"Bower B. K.","year":"1972","journal-title":"J. Am. Chem. Soc."},{"key":"ref25\/cit25","doi-asserted-by":"crossref","first-page":"643","DOI":"10.1016\/S1387-7003(03)00070-4","volume":"6","author":"Rau J. V.","year":"2003","journal-title":"Inorg. Chem. Commun."},{"key":"ref26\/cit26","first-page":"197","volume":"28","author":"Thiele K.-H.","year":"1986","journal-title":"Wiss. Z. Tech. Hochsch. \u2033Carl Schorlemmer\u2033 Leuna-Merseburg"},{"key":"ref27\/cit27","doi-asserted-by":"crossref","first-page":"3887","DOI":"10.1021\/ja00193a021","volume":"111","author":"Byrne E. K.","year":"1989","journal-title":"J. Am. Chem. Soc."},{"key":"ref28\/cit28","doi-asserted-by":"crossref","first-page":"1282","DOI":"10.1021\/ja00238a066","volume":"109","author":"Byrne E. K.","year":"1987","journal-title":"J. Am. Chem. Soc."},{"key":"ref29\/cit29","doi-asserted-by":"crossref","first-page":"1491","DOI":"10.1039\/c39860001491","author":"Byrne E. K.","year":"1986","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"ref30\/cit30","doi-asserted-by":"crossref","first-page":"2735","DOI":"10.1002\/ange.200219383","volume":"115","author":"Dimitrov V.","year":"2003","journal-title":"Angew. Chem."},{"key":"ref31\/cit31","doi-asserted-by":"crossref","first-page":"2888","DOI":"10.1039\/c3cc40461g","volume":"49","author":"Lewis R. A.","year":"2013","journal-title":"Chem. Commun."},{"key":"ref32\/cit32","doi-asserted-by":"crossref","first-page":"12772","DOI":"10.1002\/anie.201206790","volume":"51","author":"Lewis R. A.","year":"2012","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref33\/cit33","doi-asserted-by":"crossref","first-page":"18014","DOI":"10.1021\/ja108265y","volume":"132","author":"Soriaga R. A. D.","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"ref34\/cit34","doi-asserted-by":"crossref","first-page":"6252","DOI":"10.1021\/ja048713v","volume":"126","author":"Betley T. A.","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"ref35\/cit35","doi-asserted-by":"crossref","first-page":"4660","DOI":"10.1021\/ic200490v","volume":"50","author":"Lewis R. A.","year":"2011","journal-title":"Inorg. Chem."},{"key":"ref36\/cit36","doi-asserted-by":"crossref","first-page":"4218","DOI":"10.1039\/jr9600004218","author":"Birrell R. N.","year":"1960","journal-title":"J. Chem. Soc."},{"key":"ref37\/cit37","doi-asserted-by":"crossref","first-page":"3560","DOI":"10.1039\/jr9630003560","author":"Metcalfe E. L.","year":"1963","journal-title":"J. Chem. Soc."},{"key":"ref38\/cit38","doi-asserted-by":"crossref","first-page":"3497","DOI":"10.1039\/ft9969203497","volume":"92","author":"Costello A. R.","year":"1996","journal-title":"J. Chem. Soc., Faraday Trans."},{"key":"ref39\/cit39","doi-asserted-by":"crossref","first-page":"1533","DOI":"10.1039\/c0nj00124d","volume":"34","author":"Cossairt B. M.","year":"2010","journal-title":"New J. Chem."},{"key":"ref40\/cit40","doi-asserted-by":"crossref","first-page":"4240","DOI":"10.1021\/ja058783h","volume":"128","author":"Sato A.","year":"2006","journal-title":"J. Am. Chem. Soc."},{"key":"ref41\/cit41","doi-asserted-by":"crossref","first-page":"654","DOI":"10.1021\/om00064a015","volume":"1","author":"Goel R. G.","year":"1982","journal-title":"Organometallics"},{"key":"ref42\/cit42","doi-asserted-by":"crossref","first-page":"239","DOI":"10.1107\/S0365110X67002531","volume":"23","author":"Iball J.","year":"1967","journal-title":"Acta Crystallogr."},{"key":"ref43\/cit43","doi-asserted-by":"crossref","first-page":"50","DOI":"10.1021\/ic00143a013","volume":"22","author":"Lauffer R. B.","year":"1983","journal-title":"Inorg. Chem."},{"key":"ref44\/cit44","doi-asserted-by":"crossref","first-page":"1379","DOI":"10.1021\/om00087a010","volume":"3","author":"Abrahamson H. B.","year":"1984","journal-title":"Organometallics"},{"key":"ref45\/cit45","doi-asserted-by":"crossref","first-page":"955","DOI":"10.1039\/B617136B","author":"Yang L.","year":"2007","journal-title":"Dalton Trans."},{"key":"ref46\/cit46","doi-asserted-by":"crossref","first-page":"720","DOI":"10.1038\/ncomms1718","volume":"3","author":"Hohenberger J.","year":"2012","journal-title":"Nat. Commun."},{"key":"ref47\/cit47","doi-asserted-by":"crossref","first-page":"2681","DOI":"10.1002\/anie.200800600","volume":"47","author":"Vogel C.","year":"2008","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref48\/cit48","doi-asserted-by":"crossref","first-page":"1049","DOI":"10.1126\/science.1198315","volume":"331","author":"Scepaniak J. J.","year":"2011","journal-title":"Science"},{"key":"ref49\/cit49","doi-asserted-by":"crossref","DOI":"10.1007\/978-3-540-88428-6","volume-title":"M\u00f6ssbauer Spectroscopy and Transition Metal Chemistry","author":"G\u00fctlich P.","year":"2011"},{"key":"ref50\/cit50","doi-asserted-by":"crossref","first-page":"20352","DOI":"10.1021\/ja305679m","volume":"134","author":"Dugan T. R.","year":"2012","journal-title":"J. Am. Chem. Soc."},{"key":"ref51\/cit51","doi-asserted-by":"crossref","first-page":"4828","DOI":"10.1021\/ic900001y","volume":"48","author":"Cowley R. E.","year":"2009","journal-title":"Inorg. Chem."},{"key":"ref52\/cit52","doi-asserted-by":"crossref","first-page":"13515","DOI":"10.1021\/ja063590v","volume":"128","author":"Berry J. F.","year":"2006","journal-title":"J. Am. Chem. Soc."},{"key":"ref53\/cit53","doi-asserted-by":"crossref","first-page":"1937","DOI":"10.1126\/science.1128506","volume":"312","author":"Berry J. F.","year":"2006","journal-title":"Science"},{"key":"ref54\/cit54","doi-asserted-by":"crossref","first-page":"606","DOI":"10.1016\/j.jinorgbio.2005.12.016","volume":"100","author":"Chanda A.","year":"2006","journal-title":"J. Inorg. Biochem."},{"key":"ref55\/cit55","doi-asserted-by":"crossref","first-page":"17107","DOI":"10.1073\/pnas.0604402103","volume":"103","author":"Hendrich M. P.","year":"2006","journal-title":"Proc. Natl. Acad. Sci. U.S.A."},{"key":"ref56\/cit56","doi-asserted-by":"crossref","first-page":"3609","DOI":"10.1039\/c004166a","volume":"8","author":"Hioe J.","year":"2010","journal-title":"Org. Biomol. Chem."},{"key":"ref57\/cit57","doi-asserted-by":"crossref","first-page":"1309","DOI":"10.1039\/DT9830001309","author":"Clegg W.","year":"1983","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ref58\/cit58","doi-asserted-by":"crossref","first-page":"c1","DOI":"10.1016\/S0022-328X(00)98819-3","volume":"249","author":"Jennings J. R.","year":"1983","journal-title":"J. Organomet. Chem."},{"key":"ref59\/cit59","doi-asserted-by":"crossref","first-page":"532","DOI":"10.1021\/ed085p532","volume":"85","author":"Bain G. A.","year":"2008","journal-title":"J. Chem. Educ."},{"key":"ref60\/cit60","volume-title":"SMART","year":"2005"},{"key":"ref61\/cit61","volume-title":"SAINT","year":"2005"},{"key":"ref62\/cit62","volume-title":"SADABS","author":"Sheldrick G. M.","year":"2005"},{"key":"ref63\/cit63","volume-title":"SHELXTL","year":"2005"}],"container-title":["Inorganic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/ic401096p","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,4,2]],"date-time":"2023-04-02T21:13:05Z","timestamp":1680469985000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/ic401096p"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2013,6,21]]},"references-count":63,"journal-issue":{"issue":"14","published-print":{"date-parts":[[2013,7,15]]}},"alternative-id":["10.1021\/ic401096p"],"URL":"https:\/\/doi.org\/10.1021\/ic401096p","relation":{},"ISSN":["0020-1669","1520-510X"],"issn-type":[{"value":"0020-1669","type":"print"},{"value":"1520-510X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2013,6,21]]}}}