{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T05:28:07Z","timestamp":1790832487774,"version":"4.1.0"},"reference-count":42,"publisher":"American Chemical Society (ACS)","issue":"7","license":[{"start":{"date-parts":[[2015,3,12]],"date-time":"2015-03-12T00:00:00Z","timestamp":1426118400000},"content-version":"vor","delay-in-days":365,"URL":"https:\/\/pubs.acs.org\/page\/policy\/authorchoice_termsofuse.html"}],"funder":[{"DOI":"10.13039\/100000002","name":"National Institutes of Health","doi-asserted-by":"publisher","award":["GM-38401"],"award-info":[{"award-number":["GM-38401"]}],"id":[{"id":"10.13039\/100000002","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2014,4,7]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>The synthesis and spectroscopic characterization of three five-coordinate nitrosyliron(II) complexes, [Fe(Porph)(NO)], are reported. These three nitrosyl derivatives, where Porph represents protoporphyrin IX dimethyl ester, mesoporphyrin IX dimethyl ester, or deuteroporphyrin IX dimethyl ester, display notable differences in their properties relative to the symmetrical synthetic porphyrins such as OEP and TPP. The N\u2013O stretching frequencies are in the range of 1651\u20131660 cm\u20131, frequencies that are lower than those of synthetic porphyrin derivatives. Mo\u0308ssbauer spectra obtained in both zero and applied magnetic field show that the quadrupole splitting values are slightly larger than those of known synthetic porphyrins. The electronic structures of these naturally occurring porphyrin derivatives are thus seen to be consistently different from those of the synthetic derivatives, the presumed consequence of the asymmetric peripheral substituent pattern. The molecular structure of [Fe(PPIX-DME)(NO)] has been determined by X-ray crystallography. Although disorder of the axial nitrosyl ligand limits the structural quality, this derivative appears to show the same subtle structural features as previously characterized five-coordinate nitrosyls.<\/jats:p>","DOI":"10.1021\/ic500086k","type":"journal-article","created":{"date-parts":[[2014,3,12]],"date-time":"2014-03-12T08:43:41Z","timestamp":1394613821000},"page":"3763-3768","source":"Crossref","is-referenced-by-count":15,"title":["Iron Nitrosyl \u201cNatural\u201d Porphyrinates:\nDoes the Porphyrin Matter?"],"prefix":"10.1021","volume":"53","author":[{"given":"Graeme R. A.","family":"Wyllie","sequence":"first","affiliation":[{"name":"University of Notre Dame , , , ,","place":["Notre Dame, Indiana, United States, 46556"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nathan J.","family":"Silvernail","sequence":"additional","affiliation":[{"name":"University of Notre Dame , , , ,","place":["Notre Dame, Indiana, United States, 46556"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Allen G.","family":"Oliver","sequence":"additional","affiliation":[{"name":"University of Notre Dame , , , ,","place":["Notre Dame, Indiana, United States, 46556"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Charles E.","family":"Schulz","sequence":"additional","affiliation":[{"name":"Knox College , , , ,","place":["Galesburg, Illinois, United States, 61401"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"W. Robert","family":"Scheidt","sequence":"additional","affiliation":[{"name":"University of Notre Dame , , , ,","place":["Notre Dame, Indiana, United States, 46556"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2014,3,12]]},"reference":[{"key":"2026090303452782000_cit1","doi-asserted-by":"crossref","first-page":"1862","DOI":"10.1126\/science.1361684","volume":"258","author":"Culotta","year":"1992","journal-title":"Science"},{"key":"2026090303452782000_cit2","first-page":"1","volume-title":"Handbook of Experimental\nPharmacology","author":"Kots","year":"2009"},{"key":"2026090303452782000_cit3","doi-asserted-by":"crossref","first-page":"4443","DOI":"10.1038\/sj.emboj.7600422","volume":"23","author":"Russwurm","year":"2004","journal-title":"EMBO J."},{"key":"2026090303452782000_cit4","doi-asserted-by":"crossref","first-page":"109","DOI":"10.1016\/S0031-6997(25)06663-3","volume":"43","author":"Moncada","year":"1991","journal-title":"Pharmacol. 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