{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T18:34:12Z","timestamp":1790015652351,"version":"4.0.1"},"reference-count":45,"publisher":"American Chemical Society (ACS)","issue":"16","license":[{"start":{"date-parts":[[2007,7,7]],"date-time":"2007-07-07T00:00:00Z","timestamp":1183766400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2007,7,7]],"date-time":"2007-07-07T00:00:00Z","timestamp":1183766400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2007,7,7]],"date-time":"2007-07-07T00:00:00Z","timestamp":1183766400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2007,8,6]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>The tricoordinated cationic CuI complex [Cu(\u03ba2-P,P\u2018-DPEphos)(\u03ba1-P-DPEphos)][BF4] (1) (DPEphos = bis(2-(diphenylphosphino)phenyl) ether) containing a dangling phosphorus center was synthesized from the reaction of [Cu(CH3CN)4][BF4] with DPEphos in a 1:2 molar ratio in dichloromethane. When complex 1 is treated with MnO2, elemental sulfur, or selenium, the uncoordinated phosphorus atom undergoes oxidation to form a P\ue5fbE bond resulting in the formation of complexes of the type [Cu(\u03ba2-P,P\u2018-DPEphos)(\u03ba2-P,E-DPEphos-E)][BF4] (2, E = O; 3, E = S; 4, E = Se) containing a Cu\u2212E bond. The zigzag polymeric CuI complex [Cu(\u03ba2-P,P\u2018-DPEphos)(\u03bc-4,4\u2018-bpy)]n[BF4]n (5) was prepared by the reaction of [Cu(CH3CN)4][BF4] with DPEphos and 4,4\u2018-bipyridine in an equimolar ratio. The stereochemical influences of DPEphos on its coordination behavior are examined by density functional theory calculations.<\/jats:p>","DOI":"10.1021\/ic7005474","type":"journal-article","created":{"date-parts":[[2007,7,7]],"date-time":"2007-07-07T07:02:09Z","timestamp":1183791729000},"page":"6535-6541","source":"Crossref","is-referenced-by-count":41,"title":["Copper(I) Complexes of Bis(2-(diphenylphosphino)phenyl) Ether:\u2009\nSynthesis, Reactivity, and Theoretical Calculations"],"prefix":"10.1021","volume":"46","author":[{"given":"Ramalingam","family":"Venkateswaran","sequence":"first","affiliation":[{"name":"Phosphorus Laboratory, Department of Chemistry and National Single Crystal X-ray Diffraction Facility, Indian Institute of Technology, Bombay, Mumbai 400 076, India, and Department of Chemistry, University of Jyv\u00e4skyl\u00e4, P.O. Box 35, Jyv\u00e4skyl\u00e4 FI-40014, Finland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maravanji S.","family":"Balakrishna","sequence":"additional","affiliation":[{"name":"Phosphorus Laboratory, Department of Chemistry and National Single Crystal X-ray Diffraction Facility, Indian Institute of Technology, Bombay, Mumbai 400 076, India, and Department of Chemistry, University of Jyv\u00e4skyl\u00e4, P.O. Box 35, Jyv\u00e4skyl\u00e4 FI-40014, Finland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shaikh M.","family":"Mobin","sequence":"additional","affiliation":[{"name":"Phosphorus Laboratory, Department of Chemistry and National Single Crystal X-ray Diffraction Facility, Indian Institute of Technology, Bombay, Mumbai 400 076, India, and Department of Chemistry, University of Jyv\u00e4skyl\u00e4, P.O. Box 35, Jyv\u00e4skyl\u00e4 FI-40014, Finland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Heikki M.","family":"Tuononen","sequence":"additional","affiliation":[{"name":"Phosphorus Laboratory, Department of Chemistry and National Single Crystal X-ray Diffraction Facility, Indian Institute of Technology, Bombay, Mumbai 400 076, India, and Department of Chemistry, University of Jyv\u00e4skyl\u00e4, P.O. Box 35, Jyv\u00e4skyl\u00e4 FI-40014, Finland"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2007,7,7]]},"reference":[{"key":"2026091506553609800_elcit1","doi-asserted-by":"publisher","first-page":"213508","DOI":"10.1063\/1.2207489","volume":"88","author":"Su","year":"2006","journal-title":"Appl. Phys. Lett."},{"key":"2026091506553609800_elcit2","doi-asserted-by":"publisher","first-page":"1313","DOI":"10.1002\/adma.200502365","volume":"18","author":"Armaroli","year":"2006","journal-title":"Adv. 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