{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,15]],"date-time":"2026-09-15T12:03:40Z","timestamp":1789473820155,"version":"build-2803163510"},"reference-count":38,"publisher":"American Chemical Society (ACS)","issue":"16","license":[{"start":{"date-parts":[[2007,6,30]],"date-time":"2007-06-30T00:00:00Z","timestamp":1183161600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2007,6,30]],"date-time":"2007-06-30T00:00:00Z","timestamp":1183161600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2007,6,30]],"date-time":"2007-06-30T00:00:00Z","timestamp":1183161600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2007,8,6]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Four structurally diverse complexes, {[Pb(Hssal)(2,2\u2018-bipy)](4,4\u2018-bipy)0.5}n (1), [Pb2(Hssal)2(2,2\u2018-bipy)2(4,4\u2018-bipy)(H2O)2] (2), [Pb(Hssal)(phen)(4,4\u2018-bipy)0.5]n (3), and [Pb(Hssal)(2,2\u2018-bipy)(bpe)0.5]n (4), have been synthesized and characterized by elemental analyses, IR, thermogravimetric analyses, fluorescent spectra, and single-crystal X-ray analyses, where Hssal2- is doubly deprotonated 5-sulfosalicylate, 2,2\u2018-bipy is 2,2\u2018-bipyridine, phen is 1,10-phenanthroline, 4,4\u2018-bipy is 4,4\u2018-bipyridine, and bpe is trans-1,2-bis(4-pyridyl)ethylene. The structure of complex 1 possesses a one-dimensional ladderlike chain with guest 4,4\u2018-bipy molecules, while the molecular structure of complex 2 is a dimeric species with a coordinating 4,4\u2018-bipy ligand. Complex 3 consists of a one-dimensional ladderlike chain with monodentate 4,4\u2018-bipyridine but somewhat different from that of complex 1. Complex 4 is a two-dimensional layer structure. In 1\u22124, all 5-sulfosalicylates are doubly deprotonated, and all carboxylate groups of Hssal2- chelate to PbII ions; however, the coordination modes of sulfonyl groups are different:\u2009 syn\u2212syn bridging in 1, noncoordinating in 2, syn-skew bridging in 3, and one-atom bridging in 4. The noncoordinating mode of sulfonate in PbII complexes containing 5-sulfosalicylate is first reported in this presentation. The 4,4\u2018-bipy ligands act as guest molecules in 1, dimeric linkers in 2, and monodentates in 3. The \u03c0\u2212\u03c0 stacking interactions can be observed in complexes 1\u22123, whereas there is no such interaction in complex 4. The coordination spheres of PbII ions in 1\u22124 are controlled by three factors:\u2009 the activity of a lone pair of electrons, weak Pb\u2212O interactions, and \u03c0\u2212\u03c0 stacking interactions. The PbII lone pair in 4 is inactive, whereas in 1\u22123, they are stereochemically active. The thermal stability and fluorescent property of complexes 1\u22124 are different from those of PbII complexes only containing chelating ligands, [Pb(Hssal)(2,2\u2018-bipy)(DMF)]n (5), and [Pb(Hssal)(2,2\u2018-bipy)(H2O)]n (6), and [Pb(Hssal)(phen)(DMF)]n (7).<\/jats:p>","DOI":"10.1021\/ic700611e","type":"journal-article","created":{"date-parts":[[2007,6,30]],"date-time":"2007-06-30T07:39:59Z","timestamp":1183189199000},"page":"6785-6793","source":"Crossref","is-referenced-by-count":103,"title":["Syntheses, Structures, and Characterizations of Four New Lead(II)\n5-Sulfosalicylate Complexes with Both Chelating and Bridging Neutral\nLigands"],"prefix":"10.1021","volume":"46","author":[{"given":"Sai-Rong","family":"Fan","sequence":"first","affiliation":[{"name":"Department of Chemistry, Zhejiang University, Hangzhou 310027, People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Long-Guan","family":"Zhu","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Zhejiang University, Hangzhou 310027, People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2007,6,30]]},"reference":[{"key":"2026091506553680600_elcit1","doi-asserted-by":"publisher","first-page":"6850","DOI":"10.1021\/ja990899o","volume":"121","author":"Payne","year":"1999","journal-title":"J. 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