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Chem."},{"key":"ic700846xb00018\/ic700846xb00018_1","unstructured":"The broad band in the vicinity of 1060 cm\n                      -1\n                      overlapped with porphyrin bands (Figure 3) belongs to the intense \u03bd\n                      2\n                      (A\n                      1\n                      ) vibration of solid NH\n                      3\n                      .\n                      16\n                      This band together with other ammonia bands at 3200\u22123300 and 1630 cm\n                      -1\n                      (not shown) disappear after NH\n                      3\n                      evaporation upon layer warming (Figure 5)."},{"key":"ic700846xb00019\/ic700846xb00019_1","doi-asserted-by":"crossref","first-page":"2856","DOI":"10.1021\/ic0510866","volume":"45","author":"Paulat F.","year":"2006","journal-title":"Inorg. 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