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Chem."},{"key":"ref9\/cit9","unstructured":"Crystallographic data.1: C40H56N4P2Pt\u00b7C7H8,M= 942.05,T= 173(2) K, monoclinic, space groupP21\/c(No. 14),a= 13.3845(2) \u00c5,b= 22.7704(3) \u00c5,c= 15.5458(2) \u00c5, \u03b2 = 104.780(1)\u00b0,U= 4581.13(11) \u00c53,Z= 4,Dc= 1.37 Mg m\u22123, \u03bc(Mo K\u03b1) = 3.17 mm\u22121, independent reflections = 7728 [Rint= 0.058], R1 [for 6438 reflections withI> 2\u03c3(I)] = 0.030, wR2 (all data) = 0.063.2: C40H80N4P2Pt,M= 874.11,T= 173(2) K, monoclinic, space groupP21\/c(No. 14),a= 11.8881(2) \u00c5,b= 17.9465(3) \u00c5,c= 21.0820(3) \u00c5, \u03b2 = 94.286(1)\u00b0,U= 4485.26(12) \u00c53,Z= 4,Dc= 1.29 Mg m\u22123, \u03bc(Mo K\u03b1) = 3.23 mm\u22121, independent reflections = 8767 [Rint= 0.052], R1 [for 7609 reflections withI> 2\u03c3(I)] = 0.023, wR2 (all data) = 0.053.4: C38H50BrCuN4P2,M= 768.21,T= 173(2) K, monoclinic, space groupP21\/n(No. 14),a= 10.4275(1) \u00c5,b= 17.1857(2) \u00c5,c= 22.3749(3) \u00c5, \u03b2 = 97.210(1)\u00b0,U= 3977.96(8) \u00c53,Z= 4,Dc= 1.28 Mg m\u22123, \u03bc(Mo K\u03b1) = 1.66 mm\u22121, independent reflections = 9060 [Rint= 0.054], R1 [for 7135 reflections withI> 2\u03c3(I)] = 0.038, wR2 (all data) = 0.081.5: C42H60Al2BrCuN4P2,M= 880.29,T= 173(2) K, monoclinic, space groupP21\/n(No. 14),a= 14.0207(2) \u00c5,b= 22.0117(3) \u00c5,c= 16.2740(2) \u00c5, \u03b2 = 110.996(1)\u00b0,U= 4689.01(11) \u00c53,Z= 4,Dc= 1.25 Mg m\u22123, \u03bc(Mo K\u03b1) = 1.46 mm\u22121, independent reflections = 8218 [Rint= 0.087], R1 [for 5932 reflections withI> 2\u03c3(I)] = 0.049, wR2 (all data) = 0.103."},{"key":"ref10\/cit10","doi-asserted-by":"crossref","first-page":"474","DOI":"10.1021\/om9807001","volume":"18","author":"Haar C. M.","year":"1999","journal-title":"Organometallics"},{"key":"ref11\/cit11a","doi-asserted-by":"crossref","first-page":"521","DOI":"10.1080\/00958970500037540","volume":"58","author":"Palcic J. D.","year":"2005","journal-title":"J. Coord. Chem."},{"key":"ref11\/cit11b","doi-asserted-by":"crossref","first-page":"2044","DOI":"10.1021\/om00141a018","volume":"5","author":"Wisner J. M.","year":"1986","journal-title":"Organometallics"},{"key":"ref11\/cit11c","doi-asserted-by":"crossref","first-page":"780","DOI":"10.1139\/v01-037","volume":"79","author":"Durran S. E.","year":"2001","journal-title":"Can. J. Chem."},{"key":"ref12\/cit12","volume-title":"The Chemistry of Amidines and Imidates","volume":"2","author":"H\u00e4felinger G.","year":"1991"},{"key":"ref13\/cit13a","doi-asserted-by":"crossref","first-page":"3154","DOI":"10.1021\/ic034213b","volume":"42","author":"Oakley S. H.","year":"2003","journal-title":"Inorg. Chem."},{"key":"ref13\/cit13b","doi-asserted-by":"crossref","first-page":"537","DOI":"10.1039\/b314707j","author":"Oakley S. H.","year":"2004","journal-title":"Dalton Trans."},{"key":"ref14\/cit14","doi-asserted-by":"crossref","first-page":"2722","DOI":"10.1039\/b111121n","author":"Bowmaker G. A.","year":"2002","journal-title":"Dalton Trans."},{"key":"ref15\/cit15","doi-asserted-by":"crossref","first-page":"213","DOI":"10.1021\/ic50119a047","volume":"12","author":"Davis P. H.","year":"1973","journal-title":"Inorg. Chem."},{"key":"ref16\/cit16","doi-asserted-by":"crossref","first-page":"3533","DOI":"10.1021\/ic00268a023","volume":"22","author":"Bowmaker G. A.","year":"1987","journal-title":"Inorg. Chem."},{"key":"ref17\/cit17","unstructured":"TheP-dicyclohexylphosphaguanidinate anion was shown to bridge between Li atoms via the Nimineatom in the cyclic hexamer [Li(Cy2PC{NiPr}2)]6. See ref5."},{"key":"ref18\/cit18","doi-asserted-by":"crossref","first-page":"5183","DOI":"10.1021\/om9706323","volume":"16","author":"Coles M. P.","year":"1997","journal-title":"Organometallics"}],"container-title":["Inorganic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/ic7024457","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,3,16]],"date-time":"2023-03-16T11:46:12Z","timestamp":1678967172000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/ic7024457"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2008,2,23]]},"references-count":24,"journal-issue":{"issue":"7","published-print":{"date-parts":[[2008,4,1]]}},"alternative-id":["10.1021\/ic7024457"],"URL":"https:\/\/doi.org\/10.1021\/ic7024457","relation":{},"ISSN":["0020-1669","1520-510X"],"issn-type":[{"value":"0020-1669","type":"print"},{"value":"1520-510X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2008,2,23]]}}}