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Commun."},{"key":"ref2\/cit2c","doi-asserted-by":"crossref","first-page":"4350","DOI":"10.1002\/1521-3757(20021115)114:22<4350::AID-ANGE4350>3.0.CO;2-0","volume":"114","author":"Littke A. F.","year":"2002","journal-title":"Angew. Chem."},{"key":"ref2\/cit2d","doi-asserted-by":"crossref","unstructured":"dAngew. Chem., Int. Ed.2002,41, 4176\u22124211;and references therein.","DOI":"10.1002\/1521-3773(20021115)41:22<4176::AID-ANIE4176>3.0.CO;2-U"},{"key":"ref3\/cit3a","doi-asserted-by":"crossref","first-page":"627","DOI":"10.1016\/j.ccr.2005.04.032","volume":"250","author":"Le Floch P.","year":"2006","journal-title":"Coord. Chem. Rev."},{"key":"ref3\/cit3b","unstructured":"bMathey, F. and Le Floch, P.InScience of Synthesis; Vol.15,Thieme:Stuttgart, 2004; pp1097\u22121156"},{"key":"ref4\/cit4a","volume-title":"Phosphorus-Carbon Heterocyclic Chemistry: The Rise of a New Domain","author":"Mathey F.","year":"2001"},{"key":"ref4\/cit4b","volume-title":"Phosphorus: The Carbon Copy","author":"Dillon K. B.","year":"1998"},{"key":"ref5\/cit5","doi-asserted-by":"crossref","first-page":"3549","DOI":"10.1021\/cr000434c","volume":"101","author":"Bansal R. K.","year":"2001","journal-title":"Chem. Rev."},{"key":"ref6\/cit6a","doi-asserted-by":"crossref","first-page":"3106","DOI":"10.1002\/1521-3765(20010716)7:14<3106::AID-CHEM3106>3.0.CO;2-Y","volume":"7","author":"Breit B.","year":"2001","journal-title":"Chem. Eur. J."},{"key":"ref6\/cit6b","doi-asserted-by":"crossref","first-page":"143","DOI":"10.1016\/S1381-1169(98)00377-X","volume":"143","author":"Breit B.","year":"1999","journal-title":"J. Mol. Catal. A: Chemical"},{"key":"ref6\/cit6c","doi-asserted-by":"crossref","first-page":"2071","DOI":"10.1039\/CC9960002071","author":"Breit B.","year":"1996","journal-title":"Chem. Commun."},{"key":"ref7\/cit7a","doi-asserted-by":"crossref","first-page":"4686","DOI":"10.1002\/1521-3757(20001215)112:24<4686::AID-ANGE4686>3.0.CO;2-L","volume":"112","author":"Ikeda S.","year":"2000","journal-title":"Angew. Chem."},{"key":"ref7\/cit7b","unstructured":"bAngew. Chem., Int. Ed.2002,39, 4512\u22124513;and references therein."},{"key":"ref8\/cit8a","doi-asserted-by":"crossref","first-page":"1424","DOI":"10.1021\/om050972l","volume":"25","author":"Ito S.","year":"2006","journal-title":"Organometallics"},{"key":"ref8\/cit8b","doi-asserted-by":"crossref","first-page":"693","DOI":"10.1002\/asia.200600155","volume":"1","author":"Freytag M.","year":"2006","journal-title":"Chem. Asian J."},{"key":"ref9\/cit9","doi-asserted-by":"crossref","first-page":"912","DOI":"10.1021\/om010884a","volume":"21","author":"Heinicke J.","year":"2002","journal-title":"Organometallics"},{"key":"ref10\/cit10a","doi-asserted-by":"crossref","first-page":"9963","DOI":"10.1016\/S0040-4020(01)01019-5","volume":"57","author":"Heinicke J.","year":"2001","journal-title":"Tetrahedron"},{"key":"ref10\/cit10b","doi-asserted-by":"crossref","first-page":"2563","DOI":"10.1002\/1099-0682(200109)2001:10<2563::AID-EJIC2563>3.0.CO;2-2","author":"Heinicke J.","year":"2001","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref11\/cit11","doi-asserted-by":"crossref","first-page":"2869","DOI":"10.1002\/1521-3749(200213)628:13<2869::AID-ZAAC2869>3.0.CO;2-3","volume":"628","author":"Heinicke J.","year":"2002","journal-title":"Z. Anorg. Allg. Chem."},{"key":"ref12\/cit12a","doi-asserted-by":"crossref","first-page":"1742","DOI":"10.1002\/adsc.200404213","volume":"346","author":"Harkal S.","year":"2004","journal-title":"Adv. Synth. Catal."},{"key":"ref12\/cit12b","first-page":"3722","author":"Schwarz N.","year":"2007","journal-title":"Synthesis"},{"key":"ref13\/cit13","doi-asserted-by":"crossref","first-page":"4328","DOI":"10.1002\/chem.200702016","volume":"14","author":"Aluri B. R.","year":"2008","journal-title":"Chem.\u2014Eur. J."},{"key":"ref14\/cit14","doi-asserted-by":"crossref","first-page":"264","DOI":"10.1055\/s-1999-3394","author":"Bansal R. K.","year":"1999","journal-title":"Synthesis"},{"key":"ref15\/cit15a","doi-asserted-by":"crossref","first-page":"8050","DOI":"10.1021\/ja043273t","volume":"127","author":"Lane B. S.","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"ref15\/cit15b","first-page":"208","author":"Zhang-Gao Le.","year":"2004","journal-title":"Synthesis"},{"key":"ref16\/cit16","doi-asserted-by":"crossref","first-page":"1505","DOI":"10.1039\/a901088b","author":"Iwaki T.","year":"1999","journal-title":"J. Chem. Soc., Perkin Trans. 1"},{"key":"ref17\/cit17","doi-asserted-by":"crossref","first-page":"5425","DOI":"10.1021\/jo01314a059","volume":"45","author":"Balthazor T. M.","year":"1980","journal-title":"J. Org. Chem."},{"key":"ref18\/cit18a","unstructured":"aFluck, E. and Heckmann, G.InPhosphorus-31 NMR Spectroscopy in Stereochemical Analysis, Methods in Stereochemical Analysis, Vol. 8;Verkade, J. G. and Quin, L. D., Eds.VCH:Weinheim, 1987; pp61\u2212113."},{"key":"ref18\/cit18b","unstructured":"bBerger, S., Braun, S., and Kalinowski, H.O.NMR-Spektroskopie von Nichtmetallen, Vol.3,Thieme:Stuttgart, NY, 1993."},{"key":"ref18\/cit18c","volume-title":"Concise Introduction to 31 P-NMR Spectroscopy - A Guide for the Synthetic Organic and Organometallic Chemist","author":"K\u00fchl O.","year":"2008"},{"key":"ref19\/cit19a","unstructured":"aSchlosser, M.InOrganometallics in Synthesis, 2nd Ed.Schlosser, M., Ed.Wiley:Chichester, 2002; 290, pp1\u2212352."},{"key":"ref19\/cit19b","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/S0040-4020(01)90438-7","volume":"50","author":"Schlosser M.","year":"1994","journal-title":"Tetrahedron"},{"key":"ref20\/cit20","doi-asserted-by":"crossref","first-page":"623","DOI":"10.1021\/j100181a021","volume":"96","author":"Veszpr\u00e9mi T.","year":"1992","journal-title":"J. Phys. Chem."},{"key":"ref21\/cit21","doi-asserted-by":"crossref","first-page":"7823","DOI":"10.1021\/ja00312a004","volume":"107","author":"Rithner C. D.","year":"1985","journal-title":"J. Am. Chem. Soc."},{"key":"ref22\/cit22","doi-asserted-by":"crossref","first-page":"308","DOI":"10.1002\/hlca.19830660128","volume":"66","author":"Seebach D.","year":"1983","journal-title":"Helv. Chim. Acta"},{"key":"ref23\/cit23","doi-asserted-by":"crossref","first-page":"336","DOI":"10.1002\/zaac.19865400936","volume":"540","author":"Becker G.","year":"1986","journal-title":"Z. Anorg. Allg. Chem."},{"key":"ref24\/cit24a","doi-asserted-by":"crossref","first-page":"79","DOI":"10.1039\/C39840000079","author":"Barr D.","year":"1984","journal-title":"J. Chem. Soc., Chem. Comm."},{"key":"ref24\/cit24b","unstructured":"bHeinicke, J., Ullah, F., and Mayer, P.Unpublished results."},{"key":"ref24\/cit24c","first-page":"m20\u2212m22","volume":"64","author":"Domanska-Babul W.","year":"2008","journal-title":"Acta Crystallogr."},{"key":"ref25\/cit25a","unstructured":"aMcFarlane, W.InPhosphorus-31 NMR Spectroscopy in Stereochemical Analysis, Methods in Stereochemical Analysis, Vol. 8;Verkade, J. G. and Quin, L. D., Eds.VCH:Weinheim, 1987; Vols.127\u2212130,pp115\u2212150."},{"key":"ref25\/cit25b","unstructured":"bBerger, S., Braun, S., and Kalinowski, H. O.NMR-Spektroskopie von Nichtmetallen, Band 3, 31 P-NMR-Spektroskopie;Thieme:Stuttgart, 1993; p173."},{"key":"ref26\/cit26","doi-asserted-by":"crossref","first-page":"511","DOI":"10.1002\/prac.19833250323","volume":"325","author":"Heinicke J.","year":"1983","journal-title":"J. Prakt. Chem."},{"key":"ref27\/cit27","volume-title":"SHELXL-97, A Program for Refining Crystal Structures","author":"Sheldrick G. 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