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T.","year":"2006","journal-title":"CrystEngComm"},{"key":"ref6\/cit6a","doi-asserted-by":"crossref","first-page":"471","DOI":"10.1055\/s-1976-24088","volume":"6","author":"Degani J.","year":"1976","journal-title":"Synthesis"},{"key":"ref6\/cit6b","doi-asserted-by":"crossref","first-page":"1111","DOI":"10.1039\/B612726F","author":"Kreickmann T.","year":"2007","journal-title":"Chem. Commun."},{"key":"ref7\/cit7","doi-asserted-by":"crossref","first-page":"8","DOI":"10.1002\/9780470132418.ch3","volume":"10","author":"Davison A.","year":"1967","journal-title":"Inorg. Synth."},{"key":"ref8\/cit8","doi-asserted-by":"crossref","first-page":"211","DOI":"10.1016\/S0010-8545(99)00031-4","volume":"188","author":"Pullen A. E.","year":"1999","journal-title":"Coord. Chem. Rev."},{"key":"ref9\/cit9a","doi-asserted-by":"crossref","first-page":"5765","DOI":"10.1021\/jo00350a066","volume":"50","author":"Sorrell T. N.","year":"1985","journal-title":"J. Org. Chem."},{"key":"ref9\/cit9b","doi-asserted-by":"crossref","first-page":"2528","DOI":"10.1021\/om061134+","volume":"26","author":"Singh R.","year":"2007","journal-title":"Organometallics"},{"key":"ref9\/cit9c","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1002\/1615-4169(200201)344:1<3::AID-ADSC3>3.0.CO;2-2","volume":"344","author":"Matsunaga S.","year":"2002","journal-title":"Adv. Synth. Catal."},{"key":"ref10\/cit10","doi-asserted-by":"crossref","first-page":"909","DOI":"10.1080\/00397918108065746","volume":"11","author":"Sorrell T. N.","year":"1981","journal-title":"Synth. Commun."},{"key":"ref11\/cit11a","doi-asserted-by":"crossref","first-page":"1183","DOI":"10.1002\/1099-0682(200105)2001:5<1183::AID-EJIC1183>3.0.CO;2-I","author":"Tesmer M.","year":"2001","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref11\/cit11b","doi-asserted-by":"crossref","first-page":"247","DOI":"10.1002\/ejic.200600788","author":"Robertson S. D.","year":"2007","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref12\/cit12","first-page":"55","volume":"52","author":"Beswick C. L.","year":"2003","journal-title":"Prog. Inorg. Chem."},{"key":"ref13\/cit13","first-page":"267","volume":"52","author":"Wang K.","year":"2003","journal-title":"Prog. Inorg. Chem."},{"key":"ref14\/cit14","first-page":"315","volume":"52","author":"Cummings S. D.","year":"2003","journal-title":"Prog. Inorg. Chem."},{"key":"ref14\/cit14a","first-page":"399","volume":"52","author":"Faulmann C.","year":"2003","journal-title":"Prog. Inorg. Chem."},{"key":"ref15\/cit15","doi-asserted-by":"crossref","first-page":"6073","DOI":"10.1016\/S0040-4020(97)00268-8","volume":"53","author":"Cossu S.","year":"1997","journal-title":"Tetrahedron"},{"key":"ref16\/cit16","doi-asserted-by":"crossref","first-page":"131","DOI":"10.1007\/128_065","volume":"275","author":"Zonta C.","year":"2007","journal-title":"Top. Curr. Chem."},{"key":"ref17\/cit17","doi-asserted-by":"crossref","first-page":"5660","DOI":"10.1021\/jo049359m","volume":"69","author":"Alexakis A.","year":"2004","journal-title":"J. Org. Chem."},{"key":"ref18\/cit18","doi-asserted-by":"crossref","first-page":"1435","DOI":"10.1002\/cber.19931260625","volume":"126","author":"Yamato T.","year":"1993","journal-title":"Chem. Ber."},{"key":"ref19\/cit19","doi-asserted-by":"crossref","first-page":"413","DOI":"10.1021\/jo01340a016","volume":"31","author":"Kwart H.","year":"1966","journal-title":"J. Org. 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Chem."},{"key":"ref25\/cit25","doi-asserted-by":"crossref","first-page":"2409","DOI":"10.1002\/(SICI)1099-0690(199811)1998:11<2409::AID-EJOC2409>3.0.CO;2-2","volume":"11","author":"Zhu-Ohlbach Q.","year":"1998","journal-title":"Eur. J. Org. Chem."},{"key":"ref26\/cit26","doi-asserted-by":"crossref","first-page":"281","DOI":"10.1016\/S0065-3233(08)60538-0","volume":"42","author":"Christianson D. W.","year":"1991","journal-title":"Adv. Protein Chem."},{"key":"ref27\/cit27","doi-asserted-by":"crossref","first-page":"267","DOI":"10.1002\/zfch.19800200718","volume":"20","author":"Andr\u00e4 K.","year":"1980","journal-title":"Z. Chem."},{"key":"ref28\/cit28","doi-asserted-by":"crossref","first-page":"193","DOI":"10.1016\/S0020-1693(98)00215-1","volume":"282","author":"Burth R.","year":"1998","journal-title":"Inorg. Chim. Acta"},{"key":"ref29\/cit29","unstructured":"The \u03c44value has been proposed as a simple geometry index to quantify the distortion from tetrahedral geometry (\u03c44= 1) for four-coordinate species and is calculated by \u03c44= 1\/141\u00b0 \u00d7 (360\u00b0 \u2212 \u03b1 \u2212 \u03b2), with \u03b1 and \u03b2 defined as the two largest angles (Ligand)\u2212(Metal)\u2212(Ligand) in the four-coordinate complex:"},{"key":"ref29\/cit29a","doi-asserted-by":"crossref","first-page":"955","DOI":"10.1039\/B617136B","author":"Yang L.","year":"2007","journal-title":"Dalton Trans."},{"key":"ref30\/cit30","unstructured":"The \u03c45value has been proposed as a simple geometry index to quantify the distortion from trigonal bipyramidal geometry (\u03c45= 1) for five-coordinate species and is calculated by \u03c45= 1\/60\u00b0 \u00d7 (\u03b2 \u2212 \u03b1), with \u03b1 and \u03b2 defined as the two largest angles (Ligand)\u2212(Metal)\u2212(Ligand) in the five-coordinate complex. Thus, \u03c45values for ideally square pyramidal five-coordinate complexes are equal to zero:"},{"key":"ref30\/cit30a","doi-asserted-by":"crossref","first-page":"1349","DOI":"10.1039\/DT9840001349","author":"Addison A. W.","year":"1984","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ref31\/cit31","doi-asserted-by":"crossref","first-page":"1586","DOI":"10.1021\/ic702095a","volume":"47","author":"Ballmann J.","year":"2008","journal-title":"Inorg. Chem."},{"key":"ref32\/cit32","doi-asserted-by":"crossref","first-page":"9","DOI":"10.1016\/S0020-1693(99)00267-4","volume":"295","author":"Anjali K. S.","year":"1999","journal-title":"Inorg. Chim. Acta"},{"key":"ref33\/cit33","first-page":"m452\u2212m453","volume":"59","author":"Hatch D. M.","year":"2003","journal-title":"Acta Crystallogr."},{"key":"ref34\/cit34","doi-asserted-by":"crossref","first-page":"1591","DOI":"10.1002\/1099-0682(200207)2002:7<1591::AID-EJIC1591>3.0.CO;2-T","author":"Liu C.-M.","year":"2002","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref35\/cit35","doi-asserted-by":"crossref","first-page":"81","DOI":"10.1016\/0020-1693(94)04177-W","volume":"228","author":"Halvorsen K.","year":"1995","journal-title":"Inorg. Chim. Acta"},{"key":"ref36\/cit36","doi-asserted-by":"crossref","first-page":"201","DOI":"10.1080\/00958970008022572","volume":"49","author":"Wang Q.-H.","year":"2000","journal-title":"J. Coord. Chem."},{"key":"ref36\/cit36a","unstructured":"As steric effects most likely do not play a role in this case, the electronic structure of this particular dithiolene ligand seems to control the nuclearity of the complex (Note: both thiolate-sulfurs are comparatively electron-poor because of the nitrile substituents in close proximity which might disfavor a \u03bc-S-coordination mode)."},{"key":"ref37\/cit37","doi-asserted-by":"crossref","first-page":"993","DOI":"10.1107\/S0909049500014527","volume":"8","author":"Kawai T.","year":"2001","journal-title":"J. Synchrotron Rad."},{"key":"ref38\/cit38","doi-asserted-by":"crossref","first-page":"1297","DOI":"10.1039\/b001083i","author":"Thu\u00e9ry T.","year":"2000","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ref39\/cit39","doi-asserted-by":"crossref","first-page":"1364","DOI":"10.1021\/om020941f","volume":"22","author":"Redford R. 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