{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,3]],"date-time":"2026-04-03T16:01:01Z","timestamp":1775232061947,"version":"3.50.1"},"reference-count":53,"publisher":"American Chemical Society (ACS)","issue":"8","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Inorg. Chem."],"published-print":{"date-parts":[[2009,4,20]]},"DOI":"10.1021\/ic8023887","type":"journal-article","created":{"date-parts":[[2009,3,12]],"date-time":"2009-03-12T18:02:09Z","timestamp":1236880929000},"page":"3720-3730","source":"Crossref","is-referenced-by-count":40,"title":["Cationic Clathrate I Si<sub>46-<i>x<\/i><\/sub>P<sub><i>x<\/i><\/sub>Te<sub><i>y<\/i><\/sub> (6.6(1) \u2264 <i>y<\/i> \u2264 7.5(1), <i>x<\/i> \u2264 2<i>y<\/i>): Crystal Structure, Homogeneity Range, and Physical Properties"],"prefix":"10.1021","volume":"48","author":[{"given":"J. V.","family":"Zaikina","sequence":"first","affiliation":[{"name":"Chemistry Department, Lomonosov Moscow State University, 119991 Moscow, Russia, and Max-Planck-Institut f\u00fcr Chemische Physik fester Stoffe, 01187 Dresden, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"K. A.","family":"Kovnir","sequence":"additional","affiliation":[{"name":"Chemistry Department, Lomonosov Moscow State University, 119991 Moscow, Russia, and Max-Planck-Institut f\u00fcr Chemische Physik fester Stoffe, 01187 Dresden, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"U.","family":"Burkhardt","sequence":"additional","affiliation":[{"name":"Chemistry Department, Lomonosov Moscow State University, 119991 Moscow, Russia, and Max-Planck-Institut f\u00fcr Chemische Physik fester Stoffe, 01187 Dresden, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"W.","family":"Schnelle","sequence":"additional","affiliation":[{"name":"Chemistry Department, Lomonosov Moscow State University, 119991 Moscow, Russia, and Max-Planck-Institut f\u00fcr Chemische Physik fester Stoffe, 01187 Dresden, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"F.","family":"Haarmann","sequence":"additional","affiliation":[{"name":"Chemistry Department, Lomonosov Moscow State University, 119991 Moscow, Russia, and Max-Planck-Institut f\u00fcr Chemische Physik fester Stoffe, 01187 Dresden, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"U.","family":"Schwarz","sequence":"additional","affiliation":[{"name":"Chemistry Department, Lomonosov Moscow State University, 119991 Moscow, Russia, and Max-Planck-Institut f\u00fcr Chemische Physik fester Stoffe, 01187 Dresden, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yu.","family":"Grin","sequence":"additional","affiliation":[{"name":"Chemistry Department, Lomonosov Moscow State University, 119991 Moscow, Russia, and Max-Planck-Institut f\u00fcr Chemische Physik fester Stoffe, 01187 Dresden, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"A. V.","family":"Shevelkov","sequence":"additional","affiliation":[{"name":"Chemistry Department, Lomonosov Moscow State University, 119991 Moscow, Russia, and Max-Planck-Institut f\u00fcr Chemische Physik fester Stoffe, 01187 Dresden, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"316","published-online":{"date-parts":[[2009,3,12]]},"reference":[{"key":"ref1\/cit1","volume-title":"Inclusion Compounds","author":"Jeffrey G. A.","year":"1984"},{"key":"ref2\/cit2","doi-asserted-by":"crossref","first-page":"1713","DOI":"10.1126\/science.150.3704.1713","volume":"150","author":"Kasper J. S.","year":"1965","journal-title":"Science"},{"key":"ref3\/cit3a","doi-asserted-by":"crossref","first-page":"923","DOI":"10.1070\/RC2004v073n09ABEH000916","volume":"73","author":"Kovnir K. A.","year":"2004","journal-title":"Russ. Chem. Rev."},{"key":"ref3\/cit3b","doi-asserted-by":"crossref","first-page":"6725","DOI":"10.1002\/anie.200701028","volume":"46","author":"Jung W.","year":"2007","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref3\/cit3c","doi-asserted-by":"crossref","first-page":"2556","DOI":"10.1021\/ic062115v","volume":"46","author":"Condron C. L.","year":"2007","journal-title":"Inorg. Chem."},{"key":"ref3\/cit3d","doi-asserted-by":"crossref","first-page":"5348","DOI":"10.1021\/ja0705691","volume":"129","author":"B\u00f6hme B.","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"ref3\/cit3e","doi-asserted-by":"crossref","first-page":"195124","DOI":"10.1103\/PhysRevB.76.195124","volume":"76","author":"Melnychenko-Koblyuk N.","year":"2007","journal-title":"Phys. Rev. B"},{"key":"ref3\/cit3f","doi-asserted-by":"crossref","first-page":"538","DOI":"10.1002\/ejic.200700854","author":"Kaltzoglou A.","year":"2008","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref4\/cit4a","doi-asserted-by":"crossref","first-page":"43","DOI":"10.1002\/anie.197200431","volume":"11","author":"von Schnering H. G.","year":"1972","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref4\/cit4b","doi-asserted-by":"crossref","first-page":"223","DOI":"10.1002\/zaac.19733950211","volume":"395","author":"Menke H.","year":"1973","journal-title":"Z. Anorg. Allg. Chem."},{"key":"ref5\/cit5a","doi-asserted-by":"crossref","first-page":"3455","DOI":"10.1021\/ic990153r","volume":"38","author":"Shatruk M. M.","year":"1999","journal-title":"Inorg. Chem."},{"key":"ref5\/cit5b","doi-asserted-by":"crossref","first-page":"233","DOI":"10.1006\/jssc.2001.9304","volume":"161","author":"Shatruk M. M.","year":"2001","journal-title":"J. Solid State Chem."},{"key":"ref5\/cit5c","doi-asserted-by":"crossref","first-page":"957","DOI":"10.1016\/j.solidstatesciences.2005.04.002","volume":"7","author":"Kovnir K. A.","year":"2005","journal-title":"Solid State Sci."},{"key":"ref5\/cit5d","doi-asserted-by":"crossref","first-page":"5090","DOI":"10.1002\/chem.200601772","volume":"13","author":"Zaikina J. V.","year":"2007","journal-title":"Chem. Eur. J."},{"key":"ref5\/cit5e","doi-asserted-by":"crossref","first-page":"8786","DOI":"10.1021\/ic051160k","volume":"44","author":"Kovnir K. A.","year":"2005","journal-title":"Inorg. Chem."},{"issue":"1","key":"ref5\/cit5f","doi-asserted-by":"crossref","first-page":"222115","DOI":"10.1063\/1.2209207","volume":"88","author":"Kishimoto K.","year":"2006","journal-title":"Appl. Phys. Lett."},{"key":"ref6\/cit6a","doi-asserted-by":"crossref","first-page":"350","DOI":"10.1002\/anie.198603501","volume":"25","author":"Nesper R.","year":"1986","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"ref6\/cit6b","doi-asserted-by":"crossref","first-page":"527","DOI":"10.1524\/zkri.2006.221.5-7.527","volume":"221","author":"Kovnir K. A.","year":"2006","journal-title":"Z. Kristallogr.\u2212New Cryst. Struct."},{"issue":"1","key":"ref6\/cit6c","doi-asserted-by":"crossref","first-page":"172106","DOI":"10.1063\/1.2364473","volume":"89","author":"Kishimoto K.","year":"2006","journal-title":"Appl. Phys. Lett."},{"key":"ref7\/cit7","doi-asserted-by":"crossref","first-page":"135","DOI":"10.1070\/MC2004v014n04ABEH001945","author":"Kovnir K. A.","year":"2004","journal-title":"Mendeleev Commun."},{"key":"ref8\/cit8","doi-asserted-by":"crossref","first-page":"401","DOI":"10.1016\/j.solidstatesciences.2004.02.010","volume":"6","author":"Jaussaud N.","year":"2004","journal-title":"Solid State Sci."},{"key":"ref9\/cit9","doi-asserted-by":"crossref","first-page":"2505","DOI":"10.1039\/b007632p","author":"Reny E.","year":"2000","journal-title":"Chem. Commun."},{"key":"ref10\/cit10","volume-title":"Chemistry, Structure, and Bonding of Zintl Phases and Ions","author":"Kauzlarich M. S.","year":"1996"},{"key":"ref11\/cit11","volume-title":"CRC Handbook of Thermoelectrics;","author":"Slack G. A.","year":"1995"},{"key":"ref12\/cit12a","first-page":"162","volume":"096","author":"Zaikina J. V.","year":"2005","journal-title":"Book of Abstracts, The 10th European Conference on Solid State Chemistry"},{"key":"ref12\/cit12b","first-page":"L746\u2212L748","volume":"46","author":"Kishimoto K.","year":"2007","journal-title":"Jpn. J. Appl. Phys. Part 2"},{"key":"ref13\/cit13","doi-asserted-by":"crossref","first-page":"335","DOI":"10.4028\/www.scientific.net\/MSF.133-136.335","volume":"133","author":"Akselrud L. G.","year":"1993","journal-title":"Mater. Sci. Forum"},{"key":"ref14\/cit14","volume-title":"Jana2000. The Crystallographic Computing System.","author":"Petricek V.","year":"2000"},{"key":"ref15\/cit15","first-page":"38","author":"Schnelle W.","year":"2003","journal-title":"Scientific Report MPI CPfS"},{"key":"ref16\/cit16a","doi-asserted-by":"crossref","first-page":"6996","DOI":"10.1002\/anie.200462170","volume":"44","author":"Kanatzidis M. G.","year":"2005","journal-title":"Angew. Chem., Int. Ed"},{"key":"ref16\/cit16b","unstructured":"bCompound GeTe with the accurately defined composition was donated by Dr. V. I. Shtanov (Chemistry Department, Lomonosov Moscow State University)."},{"key":"ref19\/cit19a","first-page":"1","volume":"86","author":"Larson A. C.","year":"2000","journal-title":"General Structure Analysis System (GSAS). Los Alamos National Laboratory Report (LAUR)"},{"key":"ref19\/cit19b","doi-asserted-by":"crossref","first-page":"210","DOI":"10.1107\/S0021889801002242","volume":"34","author":"Toby B. H.","year":"2001","journal-title":"J. Appl. Crystallogr."},{"key":"ref20\/cit20","doi-asserted-by":"crossref","first-page":"26","DOI":"10.1080\/10448639208218770","volume":"3","author":"Sears V.","year":"1992","journal-title":"Neutron News"},{"key":"ref21\/cit21","doi-asserted-by":"crossref","first-page":"177","DOI":"10.1524\/ncrs.2007.0074","volume":"222","author":"Zaikina J. V.","year":"2007","journal-title":"Z. Kristallogr. \u2013 New Cryst. Struct."},{"key":"ref22\/cit22a","doi-asserted-by":"crossref","first-page":"2267","DOI":"10.1002\/zaac.200400268","volume":"630","author":"Carrillo-Cabrera W.","year":"2004","journal-title":"Z. Anorg. Allg. Chem."},{"key":"ref22\/cit22b","doi-asserted-by":"crossref","first-page":"3264","DOI":"10.1021\/ja043500r","volume":"127","author":"Dubois F.","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"ref22\/cit22c","doi-asserted-by":"crossref","first-page":"191","DOI":"10.1002\/zaac.19956210205","volume":"621","author":"D\u00fcnner J.","year":"1995","journal-title":"Z. Anorg. Allg. Chem."},{"key":"ref23\/cit23","doi-asserted-by":"crossref","first-page":"626","DOI":"10.1006\/jssc.2000.8906","volume":"154","author":"Ramachandran G. K.","year":"2000","journal-title":"J. Solid State Chem."},{"key":"ref24\/cit24","doi-asserted-by":"crossref","first-page":"2933","DOI":"10.1021\/ic020676q","volume":"42","author":"Fukuoka H.","year":"2003","journal-title":"Inorg. Chem."},{"key":"ref25\/cit25","doi-asserted-by":"crossref","first-page":"393","DOI":"10.1016\/0038-1098(96)00430-9","volume":"100","author":"Kawaji H.","year":"1996","journal-title":"Solid State Commun."},{"key":"ref26\/cit26","doi-asserted-by":"crossref","first-page":"5414","DOI":"10.1002\/chem.200800453","volume":"14","author":"Zaikina J. V.","year":"2008","journal-title":"Chem. Eur. J."},{"key":"ref27\/cit27","volume-title":"The Elements","author":"Emsley J.","year":"1991"},{"key":"ref28\/cit28","doi-asserted-by":"crossref","first-page":"294","DOI":"10.1016\/S0022-3093(96)00601-1","volume":"204","author":"Zhang P.","year":"1996","journal-title":"J. Non-Cryst. Solids"},{"key":"ref29\/cit29","doi-asserted-by":"crossref","DOI":"10.1007\/978-1-4613-1783-8","volume-title":"Multinuclear NMR","author":"Mason I.","year":"1987"},{"key":"ref30\/cit30","doi-asserted-by":"crossref","first-page":"5402","DOI":"10.1016\/j.jcrysgro.2008.09.001","volume":"310","author":"Philipp F.","year":"2008","journal-title":"J. Cryst. Growth"},{"key":"ref31\/cit31","doi-asserted-by":"crossref","first-page":"2839","DOI":"10.1039\/a804565h","volume":"8","author":"Reny E.","year":"1998","journal-title":"J. Mater. Chem."},{"key":"ref32\/cit32","volume-title":"Magnetochemistry","author":"Selwood P. W.","year":"1956","edition":"2"},{"key":"ref33\/cit33a","doi-asserted-by":"crossref","first-page":"570","DOI":"10.1016\/0022-4596(70)90053-8","volume":"2","author":"Cros C.","year":"1970","journal-title":"J. Solid State Chem."},{"issue":"1","key":"ref33\/cit33b","doi-asserted-by":"crossref","first-page":"134435","DOI":"10.1103\/PhysRevB.65.134435","volume":"65","author":"Paschen S.","year":"2002","journal-title":"Phys. Rev. B"},{"key":"ref33\/cit33c","doi-asserted-by":"crossref","first-page":"664","DOI":"10.1016\/j.solidstatesciences.2007.05.008","volume":"9","author":"Zaikina J. V.","year":"2007","journal-title":"Solid State Sci."},{"key":"ref34\/cit34a","doi-asserted-by":"crossref","first-page":"554","DOI":"10.1107\/S002188987901325X","volume":"12","author":"Sakata M.","year":"1979","journal-title":"J. Appl. Crystallogr."},{"key":"ref34\/cit34b","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1107\/S0021889890008391","volume":"24","author":"Berar J.-F","year":"1991","journal-title":"J. Appl. Crystallogr."}],"container-title":["Inorganic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/ic8023887","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,3,5]],"date-time":"2023-03-05T16:33:59Z","timestamp":1678034039000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/ic8023887"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2009,3,12]]},"references-count":53,"journal-issue":{"issue":"8","published-print":{"date-parts":[[2009,4,20]]}},"alternative-id":["10.1021\/ic8023887"],"URL":"https:\/\/doi.org\/10.1021\/ic8023887","relation":{},"ISSN":["0020-1669","1520-510X"],"issn-type":[{"value":"0020-1669","type":"print"},{"value":"1520-510X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2009,3,12]]}}}