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S.","year":"1993","journal-title":"Science"},{"key":"ja002114gb00053\/ja002114gb00053_1","doi-asserted-by":"crossref","first-page":"2352","DOI":"10.1021\/ja982280c","volume":"121","author":"Andersson M. E.","year":"1999","journal-title":"J. Am. Chem. Soc."},{"key":"ja002114gb00055\/ja002114gb00055_1","unstructured":"Although the paramagnetic features that develop can be analyzed as originating from a single site, they must be associated with two Fe ions, as they are the only features to develop upon decay of diamagnetic diiron(III) precursors. On the basis of this conclusion, which is consistent with the crystal structure, we have analyzed the paramagnetic M\u00f6ssbauer component by assuming that it arises from two adjacent Fe(III) ions. Preliminary analysis indicates that coupling between the Fe(III) ions must be extremely weak. A coupling interaction (exchange or dipolar) between the two Fe(III) ions would be expected to affect the paramagnetic M\u00f6ssbauer component in the following way. Electronic states that would in a completely uncoupled system exhibit isotropic spin expectation values (e.g., the first excited Kramers' doublet) would be perturbed by the coupling such that their expectation values would no longer be isotropic. As a consequence, M\u00f6ssbauer peaks from these states would be broadened and their field-orientation dependencies diminished with increasing magnitude of |J|. To the contrary, the peaks at \u22123.25 and +4.45 mm\/s (marked by arrows in Figure 10), which originate from the first excited Kramers' doublet, are quite sharp and show a dependence on the orientation of the applied field relative to the \u03b3-beam, as expected for an isotropic doublet (ref 56). From simulations of the spectra according to our present understanding we conclude that |J| must be less than \u223c10-4cm-1to account for the data. This weak interaction seems incompatible with the expected \u223c3.4 \u00c5 separation of the Fe(III) ions, for which dipolar couplings on the order of 10-2cm-1would be expected (ref 57). Thus, the paramagnetic features associated with the purple Fe(III)\u2212phenolate complex are not yet satisfactorily explained. Nevertheless, we tentatively conclude that the features reflect two M\u00f6ssbauer-indistinguishable and essentially uncoupled Fe(III) sites."},{"key":"ja002114gb00057\/ja002114gb00057_1","volume-title":"EPR of exchange coupled systems","author":"Bencini A.","year":"1990"},{"key":"ja002114gb00058\/ja002114gb00058_1","doi-asserted-by":"crossref","first-page":"6291","DOI":"10.1021\/ja00016a066","volume":"113","author":"Bollinger J. M.","year":"1991","journal-title":"J. Am. Chem. 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