{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T04:44:15Z","timestamp":1790484255968,"version":"4.1.0"},"reference-count":13,"publisher":"American Chemical Society (ACS)","issue":"23","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2002,6,1]]},"DOI":"10.1021\/ja026136+","type":"journal-article","created":{"date-parts":[[2002,7,26]],"date-time":"2002-07-26T06:11:09Z","timestamp":1027663869000},"page":"6508-6509","source":"Crossref","is-referenced-by-count":259,"title":["<i>trans<\/i>-RuH(\u03b7-BH<sub>4<\/sub>)(binap)(1,2-diamine):\u2009 A Catalyst for Asymmetric Hydrogenation of Simple Ketones under Base-Free Conditions"],"prefix":"10.1021","volume":"124","author":[{"given":"Takeshi","family":"Ohkuma","sequence":"first","affiliation":[{"name":"Nagoya University, Department of Chemistry and Research Center for Materials Science, Chikusa, Nagoya 464-8602, Japan, and Tohoku University, Instrumental Analysis Center for Chemistry, Graduate School of Science, Aoba, Sendai 980-8578, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Masatoshi","family":"Koizumi","sequence":"additional","affiliation":[{"name":"Nagoya University, Department of Chemistry and Research Center for Materials Science, Chikusa, Nagoya 464-8602, Japan, and Tohoku University, Instrumental Analysis Center for Chemistry, Graduate School of Science, Aoba, Sendai 980-8578, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kilian","family":"Mu\u00f1iz","sequence":"additional","affiliation":[{"name":"Nagoya University, Department of Chemistry and Research Center for Materials Science, Chikusa, Nagoya 464-8602, Japan, and Tohoku University, Instrumental Analysis Center for Chemistry, Graduate School of Science, Aoba, Sendai 980-8578, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gerhard","family":"Hilt","sequence":"additional","affiliation":[{"name":"Nagoya University, Department of Chemistry and Research Center for Materials Science, Chikusa, Nagoya 464-8602, Japan, and Tohoku University, Instrumental Analysis Center for Chemistry, Graduate School of Science, Aoba, Sendai 980-8578, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chizuko","family":"Kabuto","sequence":"additional","affiliation":[{"name":"Nagoya University, Department of Chemistry and Research Center for Materials Science, Chikusa, Nagoya 464-8602, Japan, and Tohoku University, Instrumental Analysis Center for Chemistry, Graduate School of Science, Aoba, Sendai 980-8578, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ryoji","family":"Noyori","sequence":"additional","affiliation":[{"name":"Nagoya University, Department of Chemistry and Research Center for Materials Science, Chikusa, Nagoya 464-8602, Japan, and Tohoku University, Instrumental Analysis Center for Chemistry, Graduate School of Science, Aoba, Sendai 980-8578, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2002,5,15]]},"reference":[{"key":"ja0261361b00001\/ja0261361b00001_1","doi-asserted-by":"crossref","first-page":"1707","DOI":"10.1002\/(SICI)1521-3773(19980703)37:12<1703::AID-ANIE1703>3.0.CO;2-I","volume":"37","author":"Doucet H.","year":"1998","journal-title":"Angew. Chem., Int. Ed."},{"key":"ja0261361b00002\/ja0261361b00002_1","doi-asserted-by":"crossref","first-page":"73","DOI":"10.1002\/1521-3773(20010105)40:1<40::AID-ANIE40>3.0.CO;2-5","volume":"40","author":"Noyori R.","year":"2001","journal-title":"Angew. Chem., Int. Ed."},{"key":"ja0261361b00003\/ja0261361b00003_1","first-page":"2676","volume":"117","author":"Ohkuma T.","year":"1995","journal-title":"J. Am. Chem. Soc."},{"key":"ja0261361b00006\/ja0261361b00006_1","first-page":"328","volume":"54","author":"Holar D. G.","year":"1976","journal-title":"Can. J. Chem."},{"key":"ja0261361b00006\/ja0261361b00006_2","doi-asserted-by":"crossref","first-page":"101","DOI":"10.1016\/0020-1693(94)04336-T","volume":"231","author":"Yoshida T.","year":"1995","journal-title":"Inorg. Chim. Acta"},{"key":"ja0261361b00009\/ja0261361b00009_1","unstructured":"Hydrogenation of4awithtrans-RuCl2[(S)-xylbinap][(S)-daipen] and KO-t-C4H9in 2-propanol ([4a] = 2.0 M,4a:Ru:base = 2000:1:8, 8 atm, 25 \u00b0C, 12 h) gave a 36:64 mixture of the hydroxy ethyl ester and the isopropyl ester (bothRin 99% ee, 100% yield). DAIPEN = 1,1-di(4-anisyl)-2-isopropyl-1,2-ethylenediamine."},{"key":"ja0261361b00011\/ja0261361b00011_1","first-page":"1417","volume":"31","author":"Robertson D. W.","year":"1988","journal-title":"J. Med. Chem."},{"key":"ja0261361b00012\/ja0261361b00012_1","first-page":"6511","volume":"122","author":"Earlier","year":"2000","journal-title":"J. Am. Chem. Soc."},{"key":"ja0261361b00013\/ja0261361b00013_1","doi-asserted-by":"crossref","first-page":"4873","DOI":"10.1021\/jo960997h","volume":"61","author":"Ohkuma T.","year":"1996","journal-title":"J. Org. Chem."},{"key":"ja0261361b00014\/ja0261361b00014_1","first-page":"5046","volume":"40","author":"Matsumoto T.","year":"1999","journal-title":"Tetrahedron Lett."},{"key":"ja0261361b00015\/ja0261361b00015_1","doi-asserted-by":"crossref","first-page":"56","DOI":"10.1246\/bcsj.68.36","volume":"68","author":"Noyori R.","year":"1995","journal-title":"Bull. Chem. Soc. Jpn."},{"key":"ja0261361b00016\/ja0261361b00016_1","doi-asserted-by":"crossref","first-page":"1661","DOI":"10.1021\/jo962095m","volume":"62","author":"Rossi T.","year":"1997","journal-title":"J. Org. Chem."},{"key":"ja0261361b00017\/ja0261361b00017_1","first-page":"1049","volume":"20","author":"Ru","year":"2001","journal-title":"Organometallics"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/ja026136%2B","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2022,2,3]],"date-time":"2022-02-03T06:43:17Z","timestamp":1643870597000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/ja026136%2B"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2002,5,15]]},"references-count":13,"journal-issue":{"issue":"23","published-print":{"date-parts":[[2002,6,1]]}},"alternative-id":["10.1021\/ja026136+"],"URL":"https:\/\/doi.org\/10.1021\/ja026136+","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2002,5,15]]}}}