{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,8]],"date-time":"2026-09-08T11:20:14Z","timestamp":1788866414028,"version":"build-2803163510"},"reference-count":78,"publisher":"American Chemical Society (ACS)","issue":"35","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2005,9,1]]},"DOI":"10.1021\/ja052150l","type":"journal-article","created":{"date-parts":[[2005,8,31]],"date-time":"2005-08-31T04:39:31Z","timestamp":1125463171000},"page":"12378-12386","source":"Crossref","is-referenced-by-count":29,"title":["Initial Members of the Family of Molecular Mid-Valent High-Nuclearity Iron Nitrides:\u2009 [Fe<sub>4<\/sub>N<sub>2<\/sub>X<sub>10<\/sub>]<sup>4-<\/sup> and [Fe<sub>10<\/sub>N<sub>8<\/sub>X<sub>12<\/sub>]<sup>5-<\/sup> (X = Cl<sup>-<\/sup>, Br<sup>-<\/sup>)"],"prefix":"10.1021","volume":"127","author":[{"given":"Miriam V.","family":"Bennett","sequence":"first","affiliation":[{"name":"Contribution from the Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, and Department of Chemistry, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sebastian","family":"Stoian","sequence":"additional","affiliation":[{"name":"Contribution from the Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, and Department of Chemistry, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Emile L.","family":"Bominaar","sequence":"additional","affiliation":[{"name":"Contribution from the Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, and Department of Chemistry, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eckard","family":"M\u00fcnck","sequence":"additional","affiliation":[{"name":"Contribution from the Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, and Department of Chemistry, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Richard H.","family":"Holm","sequence":"additional","affiliation":[{"name":"Contribution from the Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, and Department of Chemistry, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2005,8,13]]},"reference":[{"key":"ja052150lb00001\/ja052150lb00001_1","doi-asserted-by":"crossref","first-page":"1700","DOI":"10.1126\/science.1073877","volume":"297","author":"Einsle O.","year":"2002","journal-title":"Science"},{"key":"ja052150lb00002\/ja052150lb00002_1","doi-asserted-by":"crossref","first-page":"1173","DOI":"10.1021\/cr020608l","volume":"104","author":"Dos Santos P. C.","year":"2004","journal-title":"Chem. Rev."},{"key":"ja052150lb00003\/ja052150lb00003_1","first-page":"414","volume":"187","author":"Rubio L. M.","year":"2005","journal-title":"J. Bacteriol."},{"key":"ja052150lb00004\/ja052150lb00004_1","first-page":"3600","volume":"100","author":"Lee S. C.","year":"2003","journal-title":"Proc. Natl. Acad. Sci. U.S.A."},{"key":"ja052150lb00005\/ja052150lb00005_1","first-page":"1157","volume":"104","author":"Lee S. C.","year":"2004","journal-title":"Chem. Rev."},{"key":"ja052150lb00006\/ja052150lb00006_1","doi-asserted-by":"crossref","first-page":"5988","DOI":"10.1021\/ic0301371","volume":"42","author":"Vrajmasu V.","year":"2003","journal-title":"Inorg. Chem."},{"key":"ja052150lb00007\/ja052150lb00007_1","doi-asserted-by":"crossref","first-page":"8383","DOI":"10.1021\/ja0301572","volume":"125","author":"Lovell T.","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"ja052150lb00008\/ja052150lb00008_1","first-page":"325","volume":"324","author":"Dance I.","year":"2003","journal-title":"Chem. Commun."},{"key":"ja052150lb00009\/ja052150lb00009_1","doi-asserted-by":"crossref","first-page":"1467","DOI":"10.1021\/ja029041g","volume":"125","author":"Hinnemann B.","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"ja052150lb00010\/ja052150lb00010_1","doi-asserted-by":"crossref","first-page":"3927","DOI":"10.1021\/ja037792s","volume":"126","author":"Hinnemann B.","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"ja052150lb00011\/ja052150lb00011_1","doi-asserted-by":"crossref","first-page":"11863","DOI":"10.1021\/ja0481070","volume":"126","author":"Dance I.","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"ja052150lb00012\/ja052150lb00012_1","first-page":"4045","volume":"110","author":"Wagner W.-D.","year":"1988","journal-title":"J. Am. Chem. Soc."},{"key":"ja052150lb00013\/ja052150lb00013_1","first-page":"4876","volume":"121","author":"Meyer K.","year":"1999","journal-title":"J. Am. Chem. Soc."},{"key":"ja052150lb00014\/ja052150lb00014_1","doi-asserted-by":"crossref","first-page":"5317","DOI":"10.1021\/ic0005238","volume":"39","author":"Grapperhaus C. A.","year":"2000","journal-title":"Inorg. Chem."},{"key":"ja052150lb00015\/ja052150lb00015_1","doi-asserted-by":"crossref","first-page":"2912","DOI":"10.1002\/anie.200462368","volume":"44","author":"Aliaga-Alcalde N.","year":"2005","journal-title":"Angew. Chem., Int. Ed."},{"key":"ja052150lb00016\/ja052150lb00016_1","doi-asserted-by":"crossref","first-page":"1752","DOI":"10.1021\/ja00423a020","volume":"98","author":"Summerville D. A.","year":"1976","journal-title":"J. Am. Chem. Soc."},{"key":"ja052150lb00017\/ja052150lb00017_1","doi-asserted-by":"crossref","first-page":"230","DOI":"10.1515\/znb-1984-0218","volume":"39","author":"Buchler J. W.","year":"1984","journal-title":"Z. Naturforsch."},{"key":"ja052150lb00018\/ja052150lb00018_1","first-page":"21","volume":"134","author":"Kennedy B. J.","year":"1987","journal-title":"Inorg. Chim. Acta"},{"key":"ja052150lb00019\/ja052150lb00019_1","doi-asserted-by":"crossref","first-page":"424","DOI":"10.1021\/ic00275a036","volume":"27","author":"Ercolani C.","year":"1988","journal-title":"Inorg. Chem."},{"key":"ja052150lb00020\/ja052150lb00020_1","doi-asserted-by":"crossref","first-page":"2541","DOI":"10.1021\/ic00114a010","volume":"34","author":"Ercolani C.","year":"1995","journal-title":"Inorg. Chem."},{"key":"ja052150lb00021\/ja052150lb00021_1","doi-asserted-by":"crossref","first-page":"672","DOI":"10.1002\/anie.199506691","volume":"34","author":"J\u00fcstel T.","year":"1995","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"ja052150lb00022\/ja052150lb00022_1","first-page":"238","volume":"624","author":"Kienast A.","year":"1998","journal-title":"Z. Anorg. Allg. Chem."},{"key":"ja052150lb00023\/ja052150lb00023_1","doi-asserted-by":"crossref","first-page":"810","DOI":"10.1002\/(SICI)1521-3765(19990201)5:2<793::AID-CHEM793>3.0.CO;2-2","volume":"5","author":"J\u00fcstel T.","year":"1999","journal-title":"Chem. Eur. J."},{"key":"ja052150lb00024\/ja052150lb00024_1","doi-asserted-by":"crossref","first-page":"6628","DOI":"10.1021\/ja00437a035","volume":"98","author":"Scheidt W. R.","year":"1976","journal-title":"J. Am. Chem. Soc."},{"key":"ja052150lb00025\/ja052150lb00025_1","first-page":"394","volume":"45","author":"Moubaraki P. B.","year":"1989","journal-title":"Acta Crystallogr."},{"key":"ja052150lb00026\/ja052150lb00026_1","first-page":"583","volume":"39","author":"Li M.","year":"2000","journal-title":"Inorg. Chem."},{"key":"ja052150lb00027\/ja052150lb00027_1","first-page":"1923","volume":"127","author":"Brown S. D.","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"ja052150lb00028\/ja052150lb00028_1","doi-asserted-by":"crossref","first-page":"6254","DOI":"10.1021\/ja048713v","volume":"126","author":"Betley T. A.","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"ja052150lb00029\/ja052150lb00029_1","doi-asserted-by":"crossref","first-page":"1574","DOI":"10.1021\/ja00396a053","volume":"103","author":"Fjare D. E.","year":"1981","journal-title":"J. Am. Chem. Soc."},{"key":"ja052150lb00030\/ja052150lb00030_1","doi-asserted-by":"crossref","first-page":"211","DOI":"10.1016\/0022-328X(85)87432-5","volume":"290","author":"Gourdon A.","year":"1985","journal-title":"J. Organomet. Chem."},{"key":"ja052150lb00031\/ja052150lb00031_1","first-page":"46","volume":"43","author":"Hourihane R.","year":"1993","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ja052150lb00032\/ja052150lb00032_1","first-page":"754","volume":"747","author":"Della Pergola R.","year":"1996","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ja052150lb00033\/ja052150lb00033_1","first-page":"1136","volume":"43","author":"Roesky H. W.","year":"1988","journal-title":"Z. Naturforsch."},{"key":"ja052150lb00034\/ja052150lb00034_1","first-page":"1494","volume":"43","author":"Roesky H. W.","year":"1988","journal-title":"Z. Naturforsch."},{"key":"ja052150lb00035\/ja052150lb00035_1","first-page":"712","volume":"621","author":"Mai H.-J.","year":"1995","journal-title":"Z. Anorg. Allg. Chem."},{"key":"ja052150lb00036\/ja052150lb00036_1","first-page":"754","volume":"625","author":"Riese U.","year":"1999","journal-title":"Z. Anorg. Allg. Chem."},{"key":"ja052150lb00037\/ja052150lb00037_1","doi-asserted-by":"crossref","first-page":"1366","DOI":"10.1021\/om011041m","volume":"21","author":"LePichon L.","year":"2002","journal-title":"Organometallics"},{"key":"ja052150lb00038\/ja052150lb00038_1","doi-asserted-by":"crossref","first-page":"11014","DOI":"10.1021\/ja001147t","volume":"122","author":"Verma A. K.","year":"2000","journal-title":"J. Am. Chem. Soc."},{"key":"ja052150lb00039\/ja052150lb00039_1","doi-asserted-by":"crossref","first-page":"1574","DOI":"10.1002\/1521-3749(200007)626:7<1567::AID-ZAAC1567>3.0.CO;2-K","volume":"626","author":"Link H.","year":"2000","journal-title":"Z. Anorg. Allg. Chem."},{"key":"ja052150lb00040\/ja052150lb00040_1","doi-asserted-by":"crossref","first-page":"1224","DOI":"10.1021\/ic025825j","volume":"42","author":"Duncan J. S.","year":"2003","journal-title":"Inorg. Chem."},{"key":"ja052150lb00041\/ja052150lb00041_1","doi-asserted-by":"crossref","first-page":"909","DOI":"10.1021\/jo01027a038","volume":"29","author":"Sisido K.","year":"1964","journal-title":"J. Org. Chem."},{"key":"ja052150lb00042\/ja052150lb00042_1","first-page":"3515","volume":"3512","author":"Gill N. S.","year":"1961","journal-title":"J. Chem. Soc."},{"key":"ja052150lb00043\/ja052150lb00043_1","volume-title":"Inc.","author":"Frisch M. J.","year":"2004"},{"key":"ja052150lb00044\/ja052150lb00044_1","doi-asserted-by":"crossref","first-page":"2327","DOI":"10.1021\/ja00320a017","volume":"106","author":"Noodleman L.","year":"1984","journal-title":"J. Am. Chem. Soc."},{"key":"ja052150lb00046\/ja052150lb00046_1","doi-asserted-by":"crossref","first-page":"426","DOI":"10.1002\/anie.198104133","volume":"20","author":"Dehnicke K.","year":"1981","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"ja052150lb00047\/ja052150lb00047_1","doi-asserted-by":"crossref","first-page":"978","DOI":"10.1002\/ange.19921040805","volume":"31","author":"Dehnicke K.","year":"1992","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"ja052150lb00048\/ja052150lb00048_1","first-page":"1004","volume":"40","author":"Godemeyer T.","year":"1985","journal-title":"Z. Naturforsch."},{"key":"ja052150lb00049\/ja052150lb00049_1","doi-asserted-by":"crossref","first-page":"39","DOI":"10.1016\/0166-1280(94)80200-9","volume":"306","author":"Leroy G.","year":"1994","journal-title":"J. Mol. Struct. (THEOCHEM)"},{"key":"ja052150lb00050\/ja052150lb00050_1","doi-asserted-by":"crossref","first-page":"279","DOI":"10.1016\/S0020-1693(96)05326-1","volume":"252","author":"Basch H.","year":"1996","journal-title":"Inorg. Chim. Acta"},{"key":"ja052150lb00051\/ja052150lb00051_1","doi-asserted-by":"crossref","unstructured":"Luo, Y.R.Handbook of Bond Dissociation Energies in OrganicCompounds; CRC Press:\u2009 New York, 2003; pp 287\u2212299.","DOI":"10.1201\/9781420039863"},{"key":"ja052150lb00052\/ja052150lb00052_1","doi-asserted-by":"crossref","first-page":"C12","DOI":"10.1016\/0022-328X(86)80421-1","volume":"315","author":"Dilworth J. R.","year":"1986","journal-title":"J. Organomet. Chem."},{"key":"ja052150lb00053\/ja052150lb00053_1","doi-asserted-by":"crossref","first-page":"1331","DOI":"10.1002\/anie.198813301","volume":"27","author":"Plenio H.","year":"1988","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"ja052150lb00054\/ja052150lb00054_1","doi-asserted-by":"crossref","first-page":"608","DOI":"10.1515\/znc-1992-7-819","volume":"47","author":"Bai Y.","year":"1992","journal-title":"Z. Naturforsch."},{"key":"ja052150lb00055\/ja052150lb00055_1","doi-asserted-by":"crossref","first-page":"2866","DOI":"10.1002\/anie.199628631","volume":"35","author":"Decker A.","year":"1996","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"ja052150lb00056\/ja052150lb00056_1","first-page":"1331","volume":"626","author":"Reiss P.","year":"2000","journal-title":"Z. Anorg. Allg. Chem."},{"key":"ja052150lb00057\/ja052150lb00057_1","first-page":"3578","volume":"40","author":"Cotton F. A.","year":"2001","journal-title":"Inorg. Chem."},{"key":"ja052150lb00058\/ja052150lb00058_1","first-page":"2469","volume":"14","author":"Cotton F. A.","year":"1975","journal-title":"Inorg. Chem."},{"key":"ja052150lb00059\/ja052150lb00059_1","first-page":"251","volume":"560","author":"Shollhammer P.","year":"1998","journal-title":"J. Organomet. Chem."},{"key":"ja052150lb00060\/ja052150lb00060_1","doi-asserted-by":"crossref","first-page":"876","DOI":"10.1039\/c29710000876","author":"Ciechanowicz M.","year":"1971","journal-title":"Chem. Commun."},{"key":"ja052150lb00061\/ja052150lb00061_1","doi-asserted-by":"crossref","first-page":"970","DOI":"10.1002\/anie.199409691","volume":"33","author":"Schulz S.","year":"1994","journal-title":"Angew. Chem., Int. Ed."},{"key":"ja052150lb00062\/ja052150lb00062_1","doi-asserted-by":"crossref","first-page":"6326","DOI":"10.1021\/ja00255a016","volume":"109","author":"Armstrong W. H.","year":"1987","journal-title":"J. Am. Chem. Soc."},{"key":"ja052150lb00063\/ja052150lb00063_1","doi-asserted-by":"crossref","first-page":"156","DOI":"10.1021\/ic00274a030","volume":"27","author":"Gorun S. M.","year":"1988","journal-title":"J. Inorg. Chem."},{"key":"ja052150lb00064\/ja052150lb00064_1","doi-asserted-by":"crossref","first-page":"5846","DOI":"10.1021\/ic000261+","volume":"39","author":"\u00c7elenligil-\u00c7etin R.","year":"2000","journal-title":"Inorg. Chem."},{"key":"ja052150lb00065\/ja052150lb00065_1","doi-asserted-by":"crossref","first-page":"366","DOI":"10.1016\/0022-328X(92)80214-I","volume":"440","author":"Gourdon A.","year":"1992","journal-title":"J. Organomet. Chem."},{"key":"ja052150lb00066\/ja052150lb00066_1","doi-asserted-by":"crossref","first-page":"8","DOI":"10.1016\/0020-1693(94)04061-3","volume":"226","author":"Zanello P.","year":"1994","journal-title":"Inorg. Chim. Acta"},{"key":"ja052150lb00067\/ja052150lb00067_1","first-page":"2183","volume":"2179","author":"Della Pergola R.","year":"2001","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ja052150lb00068\/ja052150lb00068_1","doi-asserted-by":"crossref","first-page":"17","DOI":"10.1016\/0925-8388(95)01610-4","volume":"227","author":"Jacobs H.","year":"1995","journal-title":"J. Alloys Cmpds."},{"key":"ja052150lb00069\/ja052150lb00069_1","doi-asserted-by":"crossref","first-page":"5743","DOI":"10.1063\/1.440939","volume":"74","author":"Noodleman L.","year":"1981","journal-title":"J. Chem. Phys."},{"key":"ja052150lb00070\/ja052150lb00070_1","doi-asserted-by":"crossref","first-page":"6270","DOI":"10.1063\/1.1461363","volume":"116","author":"Rodriguez J. H.","year":"2002","journal-title":"J. Chem. Phys."},{"key":"ja052150lb00071\/ja052150lb00071_1","doi-asserted-by":"crossref","first-page":"767","DOI":"10.1107\/S0567739476001551","volume":"32","author":"Shannon R. D.","year":"1976","journal-title":"Acta Crystallogr."},{"key":"ja052150lb00072\/ja052150lb00072_1","doi-asserted-by":"crossref","first-page":"1904","DOI":"10.1021\/ic00231a037","volume":"25","author":"Maelia L. E.","year":"1986","journal-title":"Inorg. Chem."},{"key":"ja052150lb00075\/ja052150lb00075_1","doi-asserted-by":"crossref","unstructured":"Kauffmann, K.; M\u00fcnck, E. InSpectroscopic Methods in BioinorganicChemistry; Solomon, E. I., Hodgson, K. O., Eds.; ACS Symposium Series 692; American Chemical Society:\u2009 Washington, DC, 1998; pp 16\u221229.","DOI":"10.1021\/bk-1998-0692.ch002"},{"key":"ja052150lb00076\/ja052150lb00076_1","doi-asserted-by":"crossref","first-page":"869","DOI":"10.1007\/s00775-002-0371-1","volume":"7","author":"Krebs C.","year":"2002","journal-title":"J. Biol. Inorg. Chem."},{"key":"ja052150lb00078\/ja052150lb00078_1","doi-asserted-by":"crossref","first-page":"192","DOI":"10.1016\/S0020-1693(02)01031-9","volume":"337","author":"Neese F.","year":"2002","journal-title":"Inorg. Chim. Acta"},{"key":"ja052150lb00079\/ja052150lb00079_1","first-page":"7839","volume":"124","author":"Zhang Y.","year":"2002","journal-title":"J. Am. Chem. Soc."},{"key":"ja052150lb00080\/ja052150lb00080_1","doi-asserted-by":"crossref","first-page":"7247","DOI":"10.1021\/ja00200a053","volume":"111","author":"Sage J. T.","year":"1989","journal-title":"J. Am. Chem. Soc."},{"key":"ja052150lb00081\/ja052150lb00081_1","doi-asserted-by":"crossref","unstructured":"Dibar-Ure, M. C.; Flinn, P. A. InM\u00f6ssbauer Effect Methodology; Gruverman, I. J., Ed.; Plenum Press:\u2009 New York, 1971; pp 245\u2212262.","DOI":"10.1007\/978-1-4615-9002-6_13"},{"key":"ja052150lb00082\/ja052150lb00082_1","doi-asserted-by":"crossref","first-page":"368","DOI":"10.1021\/ic00144a038","volume":"22","author":"English D. R.","year":"1983","journal-title":"Inorg. Chem."}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/ja052150l","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2021,9,20]],"date-time":"2021-09-20T03:41:35Z","timestamp":1632109295000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/ja052150l"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2005,8,13]]},"references-count":78,"journal-issue":{"issue":"35","published-print":{"date-parts":[[2005,9,1]]}},"alternative-id":["10.1021\/ja052150l"],"URL":"https:\/\/doi.org\/10.1021\/ja052150l","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2005,8,13]]}}}