{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T05:17:35Z","timestamp":1791263855467,"version":"4.1.0"},"reference-count":89,"publisher":"American Chemical Society (ACS)","issue":"15","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2010,4,21]]},"DOI":"10.1021\/ja100261z","type":"journal-article","created":{"date-parts":[[2010,3,26]],"date-time":"2010-03-26T17:15:20Z","timestamp":1269623720000},"page":"5456-5468","source":"Crossref","is-referenced-by-count":65,"title":["Polymetallic Oxalate-Based 2D Magnets: Soluble Molecular Precursors for the Nanostructuration of Magnetic Oxides"],"prefix":"10.1021","volume":"132","author":[{"given":"Eugenio","family":"Coronado","sequence":"first","affiliation":[{"name":"Instituto de Ciencia Molecular (ICMol), Universidad de Valencia, Pol\u00edgono de la Coma s\/n, 46980 Paterna, Spain, Institute of Chemical Research of Catalonia (ICIQ), Av. Pa\u00efsos Catalans 16, 43007 Tarragona, Spain, and CNR-Institute of Nanostructured Materials (ISMN), Via P. Gobetti 101, 40129 Bologna, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Carlos","family":"Mart\u00ed-Gastaldo","sequence":"additional","affiliation":[{"name":"Instituto de Ciencia Molecular (ICMol), Universidad de Valencia, Pol\u00edgono de la Coma s\/n, 46980 Paterna, Spain, Institute of Chemical Research of Catalonia (ICIQ), Av. Pa\u00efsos Catalans 16, 43007 Tarragona, Spain, and CNR-Institute of Nanostructured Materials (ISMN), Via P. Gobetti 101, 40129 Bologna, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jos\u00e9 R.","family":"Gal\u00e1n-Mascar\u00f3s","sequence":"additional","affiliation":[{"name":"Instituto de Ciencia Molecular (ICMol), Universidad de Valencia, Pol\u00edgono de la Coma s\/n, 46980 Paterna, Spain, Institute of Chemical Research of Catalonia (ICIQ), Av. Pa\u00efsos Catalans 16, 43007 Tarragona, Spain, and CNR-Institute of Nanostructured Materials (ISMN), Via P. Gobetti 101, 40129 Bologna, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Massimiliano","family":"Cavallini","sequence":"additional","affiliation":[{"name":"Instituto de Ciencia Molecular (ICMol), Universidad de Valencia, Pol\u00edgono de la Coma s\/n, 46980 Paterna, Spain, Institute of Chemical Research of Catalonia (ICIQ), Av. Pa\u00efsos Catalans 16, 43007 Tarragona, Spain, and CNR-Institute of Nanostructured Materials (ISMN), Via P. Gobetti 101, 40129 Bologna, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2010,3,26]]},"reference":[{"key":"ref1\/cit1a","doi-asserted-by":"crossref","first-page":"21","DOI":"10.1557\/mrs2000.221","volume":"25","author":"Miller J. S.","year":"2000","journal-title":"MRS Bull.: Molecule-Based Magnets"},{"key":"ref1\/cit1b","doi-asserted-by":"crossref","first-page":"98","DOI":"10.1002\/adma.19900020207","volume":"2","author":"Miller J. S.","year":"1990","journal-title":"Adv. Mater."},{"key":"ref2\/cit2a","unstructured":"aDay, P. and Underhill, A. E.Metal-Organic and Organic Molecular Magnets;Royal Society of Chemistry:Cambridge, U.K., 2000; Spec. Publ. R. Soc. Chem. Vol.252."},{"key":"ref2\/cit2b","doi-asserted-by":"crossref","first-page":"1353","DOI":"10.1039\/b804757j","volume":"38","author":"Kurmoo M.","year":"2009","journal-title":"Chem. Soc. Rev."},{"key":"ref3\/cit3","doi-asserted-by":"crossref","first-page":"447","DOI":"10.1038\/35044035","volume":"408","author":"Coronado E.","year":"2000","journal-title":"Nature"},{"key":"ref4\/cit4a","doi-asserted-by":"crossref","first-page":"9444","DOI":"10.1021\/ja0002619","volume":"122","author":"B\u00e9nard S.","year":"2000","journal-title":"J. Am. Chem. Soc."},{"key":"ref4\/cit4b","doi-asserted-by":"crossref","first-page":"704","DOI":"10.1126\/science.272.5262.704","volume":"272","author":"Sato O.","year":"1996","journal-title":"Science"},{"key":"ref4\/cit4c","doi-asserted-by":"crossref","first-page":"6648","DOI":"10.1021\/ja000348u","volume":"122","author":"Bleuzen A.","year":"2000","journal-title":"J. Am. Chem. Soc."},{"key":"ref4\/cit4d","doi-asserted-by":"crossref","first-page":"15519","DOI":"10.1021\/ja8047046","volume":"130","author":"Coronado E.","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"ref5\/cit5a","doi-asserted-by":"crossref","first-page":"586","DOI":"10.1002\/1521-3773(20020215)41:4<586::AID-ANIE586>3.0.CO;2-6","volume":"41","author":"Minguet M.","year":"2002","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref5\/cit5b","doi-asserted-by":"crossref","first-page":"4810","DOI":"10.1002\/anie.200351888","volume":"42","author":"Inoue K.","year":"2003","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref5\/cit5c","doi-asserted-by":"crossref","first-page":"3484","DOI":"10.1002\/chem.200501351","volume":"12","author":"Coronado E.","year":"2006","journal-title":"Chem. Eur. J."},{"key":"ref5\/cit5d","doi-asserted-by":"crossref","first-page":"729","DOI":"10.1038\/nmat2256","volume":"7","author":"Train C.","year":"2008","journal-title":"Nat. Mater."},{"key":"ref5\/cit5e","doi-asserted-by":"crossref","first-page":"16838","DOI":"10.1021\/ja9061568","volume":"131","author":"Train C.","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"ref6\/cit6","doi-asserted-by":"crossref","first-page":"3238","DOI":"10.1002\/anie.200604452","volume":"46","author":"Ohkoshi S.","year":"2007","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref7\/cit7a","doi-asserted-by":"crossref","first-page":"4164","DOI":"10.1021\/cm0211406","volume":"14","author":"Floquet S.","year":"2002","journal-title":"Chem. Mater."},{"key":"ref7\/cit7b","doi-asserted-by":"crossref","first-page":"535","DOI":"10.1039\/B311371J","volume":"28","author":"Floquet S.","year":"2004","journal-title":"New J. Chem."},{"key":"ref7\/cit7c","doi-asserted-by":"crossref","first-page":"9111","DOI":"10.1021\/ic801165b","volume":"47","author":"Clemente-Le\u00f3n M.","year":"2008","journal-title":"Inorg. Chem."},{"key":"ref8\/cit8a","doi-asserted-by":"crossref","first-page":"6974","DOI":"10.1021\/ja00044a004","volume":"114","author":"Tamaki H.","year":"1992","journal-title":"J. Am. Chem. Soc."},{"key":"ref8\/cit8b","first-page":"617","volume":"232","author":"Okawa H.","year":"1993","journal-title":"Mol. Cryst. Liq. Cryst."},{"key":"ref8\/cit8c","doi-asserted-by":"crossref","first-page":"1975","DOI":"10.1246\/cl.1992.1975","author":"Tamaki H.","year":"1992","journal-title":"Chem. Lett."},{"key":"ref8\/cit8d","doi-asserted-by":"crossref","first-page":"1551","DOI":"10.1039\/C39940001551","author":"Mathoniere C.","year":"1994","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"ref8\/cit8e","doi-asserted-by":"crossref","first-page":"1201","DOI":"10.1021\/ic950703v","volume":"35","author":"Mathoniere C.","year":"1996","journal-title":"Inorg. Chem."},{"key":"ref8\/cit8f","doi-asserted-by":"crossref","first-page":"391","DOI":"10.1006\/jssc.2001.9169","volume":"159","author":"Coronado E.","year":"2001","journal-title":"J. Solid State Chem."},{"key":"ref8\/cit8g","doi-asserted-by":"crossref","first-page":"2463","DOI":"10.1039\/b516198c","author":"Min K. S.","year":"2006","journal-title":"Dalton Trans."},{"key":"ref8\/cit8h","doi-asserted-by":"crossref","first-page":"2685","DOI":"10.1039\/B602250B","volume":"16","author":"Coronado E.","year":"2006","journal-title":"J. Mater. Chem."},{"key":"ref9\/cit9a","doi-asserted-by":"crossref","first-page":"2301","DOI":"10.1021\/ic960838g","volume":"36","author":"Pellaux R.","year":"1997","journal-title":"Inorg. Chem."},{"key":"ref9\/cit9b","doi-asserted-by":"crossref","first-page":"1888","DOI":"10.1021\/ic00062a004","volume":"32","author":"Decurtins S.","year":"1993","journal-title":"Inorg. Chem."},{"key":"ref9\/cit9c","doi-asserted-by":"crossref","first-page":"9521","DOI":"10.1021\/ja00100a016","volume":"116","author":"Decurtins S.","year":"1994","journal-title":"J. Am. Chem. Soc."},{"key":"ref9\/cit9d","doi-asserted-by":"crossref","first-page":"4131","DOI":"10.1021\/ic980306v","volume":"37","author":"Hernandez-Molina M.","year":"1998","journal-title":"Inorg. Chem."},{"key":"ref9\/cit9e","doi-asserted-by":"crossref","first-page":"113","DOI":"10.1021\/ic0008870","volume":"40","author":"Coronado E.","year":"2001","journal-title":"Inorg. Chem."},{"key":"ref9\/cit9f","doi-asserted-by":"crossref","first-page":"832","DOI":"10.1021\/cm020330d","volume":"16","author":"Pointillart F.","year":"2004","journal-title":"Chem. Mater."},{"key":"ref9\/cit9g","doi-asserted-by":"crossref","first-page":"5653","DOI":"10.1021\/ic060442x","volume":"45","author":"Clemente-Le\u00f3n M.","year":"2006","journal-title":"Inorg. Chem."},{"key":"ref10\/cit10a","doi-asserted-by":"crossref","first-page":"792","DOI":"10.1002\/1521-3773(20010216)40:4<792::AID-ANIE7920>3.0.CO;2-L","volume":"40","author":"Ballester G.","year":"2001","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref11\/cit11","doi-asserted-by":"crossref","first-page":"14987","DOI":"10.1021\/ja806298t","volume":"130","author":"Coronado E.","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"ref12\/cit12a","doi-asserted-by":"crossref","first-page":"6197","DOI":"10.1021\/ic050258w","volume":"44","author":"Coronado E.","year":"2005","journal-title":"Inorg. Chem."},{"key":"ref12\/cit12b","doi-asserted-by":"crossref","first-page":"2101","DOI":"10.1016\/j.poly.2006.10.024","volume":"26","author":"Coronado E.","year":"2007","journal-title":"Polyhedron"},{"key":"ref12\/cit12c","doi-asserted-by":"crossref","first-page":"6829","DOI":"10.1021\/ic800418k","volume":"47","author":"Coronado E.","year":"2008","journal-title":"Inorg. Chem."},{"key":"ref13\/cit13","doi-asserted-by":"crossref","first-page":"8108","DOI":"10.1021\/ic700808h","volume":"46","author":"Coronado E.","year":"2007","journal-title":"Inorg. Chem."},{"key":"ref14\/cit14a","doi-asserted-by":"crossref","first-page":"1002","DOI":"10.1039\/B609630A","volume":"17","author":"Neo K. E.","year":"2007","journal-title":"J. Mater. Chem."},{"key":"ref14\/cit14b","doi-asserted-by":"crossref","first-page":"2324","DOI":"10.1021\/cm001063j","volume":"12","author":"Boudaren C.","year":"2000","journal-title":"Chem. Mater."},{"key":"ref15\/cit15a","doi-asserted-by":"crossref","first-page":"1043","DOI":"10.1002\/adma.200801979","volume":"21","author":"Cavallini M.","year":"2009","journal-title":"Adv. Mater."},{"key":"ref15\/cit15b","doi-asserted-by":"crossref","first-page":"6085","DOI":"10.1039\/b903569a","volume":"19","author":"Cavallini M.","year":"2009","journal-title":"J. Mater. Chem."},{"key":"ref15\/cit15c","doi-asserted-by":"crossref","first-page":"249","DOI":"10.1016\/S0039-6028(03)00167-5","volume":"532","author":"Corradini V.","year":"2003","journal-title":"Surf. Sci."},{"key":"ref15\/cit15d","doi-asserted-by":"crossref","first-page":"1959","DOI":"10.1039\/B316399G","volume":"14","author":"Leclere P.","year":"2004","journal-title":"J. Mater. Chem."},{"key":"ref16\/cit16a","doi-asserted-by":"crossref","first-page":"1527","DOI":"10.1021\/nl034630l","volume":"3","author":"Cavallini M.","year":"2003","journal-title":"Nano Lett."},{"key":"ref16\/cit16b","doi-asserted-by":"crossref","first-page":"3949","DOI":"10.1016\/j.jssc.2004.08.015","volume":"177","author":"Leyva A. G.","year":"2004","journal-title":"J. Solid State Chem."},{"key":"ref16\/cit16c","doi-asserted-by":"crossref","first-page":"784","DOI":"10.1039\/B711677B","volume":"10","author":"Cavallini M.","year":"2008","journal-title":"Phys. Chem. Chem. Phys."},{"key":"ref16\/cit16d","doi-asserted-by":"crossref","first-page":"8596","DOI":"10.1002\/anie.200802085","volume":"47","author":"Cavallini M.","year":"2008","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref17\/cit17","volume-title":"Inorganic Synthesis","author":"Baylar J. M.","year":"1939"},{"key":"ref18\/cit18","first-page":"120","volume":"23","author":"Wyrouboff G.","year":"1900","journal-title":"Bl. Soc. Min."},{"key":"ref19\/cit19","doi-asserted-by":"crossref","unstructured":"Otwinowski, Z. and Minor, W.Methods in Enzymology;Carter, C. W., Jr. and Sweet, R. M., Eds.Academic Press:New York, 1997; Vol. 276, pp307\u2212326.","DOI":"10.1016\/S0076-6879(97)76066-X"},{"key":"ref20\/cit20","doi-asserted-by":"crossref","first-page":"115","DOI":"10.1107\/S0021889898007717","volume":"32","author":"Altomare A.","year":"1999","journal-title":"J. Appl. Crystallogr."},{"key":"ref21\/cit21","unstructured":"Sheldrick, G. M.SHELXL-97;University of G\u00f6ttingen,G\u00f6ttingen, Germany, 1997."},{"key":"ref22\/cit22","unstructured":"CrystalMaker;CrystalMaker Software,Oxford, U.K., 2006."},{"key":"ref23\/cit23","doi-asserted-by":"crossref","first-page":"65","DOI":"10.1180\/minmag.1997.061.404.07","volume":"61","author":"Holland T. J. B.","year":"1997","journal-title":"Mineral. Magn."},{"key":"ref24\/cit24a","doi-asserted-by":"crossref","first-page":"11607","DOI":"10.1021\/jp061231g","volume":"110","author":"Cavallini M.","year":"2006","journal-title":"J. Phys. Chem. B"},{"key":"ref24\/cit24b","doi-asserted-by":"crossref","first-page":"219","DOI":"10.1016\/S0022-0728(02)00846-X","volume":"532","author":"Innocenti M.","year":"2002","journal-title":"J. Electroanal. Chem."},{"key":"ref24\/cit24c","doi-asserted-by":"crossref","first-page":"25","DOI":"10.1016\/S0167-9317(02)00505-1","volume":"61","author":"Cedeno C. C.","year":"2002","journal-title":"J. Microelectron. Eng."},{"key":"ref24\/cit24d","doi-asserted-by":"crossref","first-page":"18987","DOI":"10.1021\/jp903494e","volume":"113","author":"Simeone F. C.","year":"2009","journal-title":"J. Phys. Chem. C"},{"key":"ref25\/cit25","doi-asserted-by":"crossref","first-page":"5037","DOI":"10.1039\/b805776a","author":"Zhang B.","year":"2008","journal-title":"Dalton Trans."},{"key":"ref26\/cit26a","doi-asserted-by":"crossref","first-page":"870","DOI":"10.1039\/c39760000870","author":"Bellito C.","year":"1976","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"ref26\/cit26b","doi-asserted-by":"crossref","first-page":"1081","DOI":"10.1039\/dt9820001081","author":"Stead M. J.","year":"1982","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ref26\/cit26c","doi-asserted-by":"crossref","first-page":"4756","DOI":"10.1021\/ic025704j","volume":"41","author":"Kou H.-Z.","year":"2002","journal-title":"Inorg. Chem."},{"key":"ref27\/cit27a","doi-asserted-by":"crossref","first-page":"13","DOI":"10.1039\/DT9880000013","volume":"1","author":"Rogers R. D.","year":"1988","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ref27\/cit27b","doi-asserted-by":"crossref","first-page":"2141","DOI":"10.1039\/a902358e","volume":"13","author":"Steed J. W.","year":"1999","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ref28\/cit28a","doi-asserted-by":"crossref","first-page":"2241","DOI":"10.1016\/S0025-5408(01)00703-6","volume":"36","author":"Kim C. K.","year":"2001","journal-title":"Mater. Res. Bull."},{"key":"ref28\/cit28b","doi-asserted-by":"crossref","first-page":"111","DOI":"10.1016\/j.mseb.2003.10.111","volume":"110","author":"Gao J.","year":"2004","journal-title":"Mater. Sci. Eng., B"},{"key":"ref29\/cit29","doi-asserted-by":"crossref","first-page":"563","DOI":"10.1016\/0038-1098(92)90412-3","volume":"81","author":"Kamiyama T.","year":"1992","journal-title":"Solid State Commun."},{"key":"ref30\/cit30","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1021\/ja00183a001","volume":"111","author":"Grimes R. W.","year":"1989","journal-title":"J. Am. Chem. Soc."},{"key":"ref31\/cit31","doi-asserted-by":"crossref","first-page":"4017","DOI":"10.1016\/j.ica.2008.03.041","volume":"361","author":"Coronado E.","year":"2008","journal-title":"Inorg. Chim. Acta"},{"key":"ref32\/cit32","doi-asserted-by":"crossref","first-page":"1078","DOI":"10.1039\/b201312f","author":"Th\u00e9tiot F.","year":"2002","journal-title":"Chem. Commun."},{"key":"ref33\/cit33","volume-title":"Oxide Spinels in Ferromagnetic Materials","author":"Krupicka S.","year":"1982"},{"key":"ref34\/cit34","volume-title":"Spin Glasses: An Experimental Introduction","author":"Mydosh J. A.","year":"1993"},{"key":"ref35\/cit35","first-page":"551","volume":"37","author":"Xia Y.","year":"1998","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref36\/cit36","doi-asserted-by":"crossref","first-page":"1269","DOI":"10.1021\/nl0342388","volume":"3","author":"Cavallini M.","year":"2003","journal-title":"Nano Lett."},{"key":"ref37\/cit37a","doi-asserted-by":"crossref","first-page":"531","DOI":"10.1126\/science.1078012","volume":"299","author":"Cavallini M.","year":"2003","journal-title":"Science"},{"key":"ref37\/cit37b","doi-asserted-by":"crossref","first-page":"3003","DOI":"10.1021\/la9815392","volume":"15","author":"Cavallini M.","year":"1999","journal-title":"Langmuir"},{"key":"ref37\/cit37c","doi-asserted-by":"crossref","first-page":"391","DOI":"10.1126\/science.285.5426.391","volume":"285","author":"Collier C. P.","year":"1999","journal-title":"Science"},{"key":"ref37\/cit37d","doi-asserted-by":"crossref","first-page":"75","DOI":"10.1016\/S0022-0728(97)00560-3","volume":"444","author":"M. Cavallini M.","year":"1998","journal-title":"Electroanal. Chem."},{"key":"ref38\/cit38a","doi-asserted-by":"crossref","first-page":"9143","DOI":"10.1103\/PhysRevB.53.9143","volume":"53","author":"Schiessl W.","year":"1996","journal-title":"Phys. Rev. B"},{"key":"ref38\/cit38b","doi-asserted-by":"crossref","first-page":"663","DOI":"10.3989\/cyv.2004.v43.i3.472","volume":"43","author":"Ma Y.","year":"2004","journal-title":"Bol. Soc. Esp. Ceram. Vidrio"},{"key":"ref38\/cit38c","doi-asserted-by":"crossref","first-page":"249","DOI":"10.1016\/S0025-5408(96)00180-8","volume":"32","author":"Laberty C.","year":"1997","journal-title":"Mater. Res. Bull."},{"key":"ref39\/cit39","doi-asserted-by":"crossref","first-page":"32","DOI":"10.1038\/scientificamerican0805-32","volume":"293","author":"Walter C.","year":"2005","journal-title":"Sci. Am."},{"key":"ref40\/cit40","unstructured":"Coronado, E., Mart\u00ed-Gastaldo, C., and Gal\u00e1n-Mascar\u00f3s, J. R.Pol\u00edmeros de coordinaci\u00f3n solubles homo y heteromet\u00e1licos basados en el ligando oxalato y m\u00e9todo de obtenci\u00f3n de espinelas a partir de ellos. Patent WO2009130359-A1."},{"key":"ref41\/cit41","doi-asserted-by":"crossref","first-page":"797","DOI":"10.1038\/nature01299","volume":"420","author":"Loudon J. C.","year":"2002","journal-title":"Nature"},{"key":"ref42\/cit42","first-page":"766","volume":"58","author":"Atovmyan L. O.","year":"1993","journal-title":"JETP Lett."},{"key":"ref43\/cit43","doi-asserted-by":"crossref","first-page":"552","DOI":"10.1002\/(SICI)1521-3765(20000204)6:3<552::AID-CHEM552>3.0.CO;2-U","volume":"6","author":"Coronado E.","year":"2000","journal-title":"Chem. Eur. J."},{"key":"ref44\/cit44","doi-asserted-by":"crossref","first-page":"65","DOI":"10.1016\/0020-1693(93)03711-I","volume":"216","author":"Decurtins S.","year":"1994","journal-title":"Inorg. Chim. Acta"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/ja100261z","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,3,7]],"date-time":"2023-03-07T20:06:30Z","timestamp":1678219590000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/ja100261z"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2010,3,26]]},"references-count":89,"journal-issue":{"issue":"15","published-print":{"date-parts":[[2010,4,21]]}},"alternative-id":["10.1021\/ja100261z"],"URL":"https:\/\/doi.org\/10.1021\/ja100261z","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2010,3,26]]}}}