{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T21:00:09Z","timestamp":1791406809299,"version":"4.3.3"},"reference-count":20,"publisher":"American Chemical Society (ACS)","issue":"14","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2010,4,14]]},"DOI":"10.1021\/ja100748y","type":"journal-article","created":{"date-parts":[[2010,3,18]],"date-time":"2010-03-18T17:32:08Z","timestamp":1268933528000},"page":"4986-4987","source":"Crossref","is-referenced-by-count":366,"title":["The Productive Merger of Iodonium Salts and Organocatalysis: A Non-photolytic Approach to the Enantioselective \u03b1-Trifluoromethylation of Aldehydes"],"prefix":"10.1021","volume":"132","author":[{"given":"Anna E.","family":"Allen","sequence":"first","affiliation":[{"name":"Merck Center for Catalysis, Princeton University, Princeton, New Jersey 08544"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"David W. C.","family":"MacMillan","sequence":"additional","affiliation":[{"name":"Merck Center for Catalysis, Princeton University, Princeton, New Jersey 08544"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2010,3,18]]},"reference":[{"key":"ref1\/cit1a","volume-title":"Fluorine in Organic Chemistry","author":"Chambers R. D.","year":"1973"},{"key":"ref1\/cit1b","doi-asserted-by":"crossref","DOI":"10.1007\/978-1-4899-1202-2","volume-title":"Organofluorine Chemistry: Principles and Commercial Applications","author":"Banks R. E.","year":"1994"},{"key":"ref1\/cit1c","volume-title":"Organofluorine Compounds in Medicinal Chemistry and Biomedical Applications","author":"Filler R.","year":"1993"},{"key":"ref1\/cit1d","doi-asserted-by":"crossref","first-page":"1881","DOI":"10.1126\/science.1131943","volume":"317","author":"M\u00fcller K.","year":"2007","journal-title":"Science"},{"key":"ref1\/cit1e","doi-asserted-by":"crossref","first-page":"320","DOI":"10.1039\/B610213C","volume":"37","author":"Pursor S.","year":"2008","journal-title":"Chem. Soc. Rev."},{"key":"ref2\/cit2a","doi-asserted-by":"crossref","first-page":"10875","DOI":"10.1021\/ja9053338","volume":"131","author":"Nagib D. A.","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"ref2\/cit2b","doi-asserted-by":"crossref","first-page":"3599","DOI":"10.1039\/b909641h","volume":"7","author":"Noritake S.","year":"2009","journal-title":"Org. Biomol. Chem."},{"key":"ref3\/cit3a","doi-asserted-by":"crossref","first-page":"2579","DOI":"10.1002\/chem.200501052","volume":"12","author":"Eisenberger P.","year":"2006","journal-title":"Chem.\u2014Eur. J."},{"key":"ref3\/cit3b","doi-asserted-by":"crossref","first-page":"754","DOI":"10.1002\/anie.200603497","volume":"46","author":"Kieltsch I.","year":"2007","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref3\/cit3c","doi-asserted-by":"crossref","first-page":"1575","DOI":"10.1039\/b801424h","author":"Eisenberger P.","year":"2008","journal-title":"Chem. Commun."},{"key":"ref3\/cit3d","doi-asserted-by":"crossref","first-page":"260","DOI":"10.2533\/chimia.2008.260","volume":"62","author":"Kieltsch I.","year":"2008","journal-title":"Chimia"},{"key":"ref3\/cit3e","doi-asserted-by":"crossref","first-page":"4332","DOI":"10.1002\/anie.200900974","volume":"48","author":"Koller R.","year":"2009","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref4\/cit4a","first-page":"103","volume":"20","author":"Yagupolskii L. M.","year":"1984","journal-title":"J. Org. Chem. USSR (Engl. Transl.)"},{"key":"ref4\/cit4b","doi-asserted-by":"crossref","first-page":"3579","DOI":"10.1016\/S0040-4039(00)94447-2","volume":"31","author":"Umemoto T.","year":"1990","journal-title":"Tetrahedron Lett."},{"key":"ref4\/cit4c","doi-asserted-by":"crossref","first-page":"2156","DOI":"10.1021\/ja00059a009","volume":"115","author":"Umemoto T.","year":"1993","journal-title":"J. Am. Chem. Soc."},{"key":"ref4\/cit4d","doi-asserted-by":"crossref","first-page":"1757","DOI":"10.1021\/cr941149u","volume":"96","author":"Umemoto T.","year":"1996","journal-title":"Chem. Rev."},{"key":"ref6\/cit6","unstructured":"3,3-Dimethyl-1-trifluoromethyl-1,2-benziodoxole can be handled in moist air without any special precautions. However, it should be stored at\u2009\u221220 \u00b0C to prevent slow degradation over time (see ref3a)."},{"key":"ref8\/cit8","doi-asserted-by":"crossref","first-page":"3149","DOI":"10.1016\/j.tet.2008.09.028","volume":"65","author":"Eastman K.","year":"2009","journal-title":"Tetrahedron"},{"key":"ref9\/cit9a","doi-asserted-by":"crossref","first-page":"8826","DOI":"10.1021\/ja051805f","volume":"127","author":"Beeson T. D.","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"ref9\/cit9b","doi-asserted-by":"crossref","first-page":"4108","DOI":"10.1021\/ja049562z","volume":"126","author":"Brochu M. P.","year":"2004","journal-title":"J. Am. Chem. Soc."}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/ja100748y","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,3,15]],"date-time":"2023-03-15T20:15:54Z","timestamp":1678911354000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/ja100748y"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2010,3,18]]},"references-count":20,"journal-issue":{"issue":"14","published-print":{"date-parts":[[2010,4,14]]}},"alternative-id":["10.1021\/ja100748y"],"URL":"https:\/\/doi.org\/10.1021\/ja100748y","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2010,3,18]]}}}