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Chem."},{"key":"ref49\/cit49e","doi-asserted-by":"crossref","first-page":"4632","DOI":"10.1021\/ja0602389","volume":"128","author":"Grushin V. V.","year":"2006","journal-title":"J. Am. Chem. Soc."},{"key":"ref49\/cit49f","doi-asserted-by":"crossref","first-page":"2496","DOI":"10.1021\/ic00338a021","volume":"29","author":"Yang D. S.","year":"1990","journal-title":"Inorg. Chem."},{"key":"ref50\/cit50","volume-title":"Orbital Interactions in Chemistry","author":"Albright T. A.","year":"1985"},{"key":"ref51\/cit51a","doi-asserted-by":"crossref","first-page":"165","DOI":"10.1021\/cr00002a004","volume":"91","author":"Hansch H.","year":"1991","journal-title":"Chem. Rev."},{"key":"ref51\/cit51b","doi-asserted-by":"crossref","DOI":"10.1002\/9780470988589","volume-title":"Organofluorine Chemistry","author":"Uneyama K.","year":"2006"},{"key":"ref52\/cit52","doi-asserted-by":"crossref","first-page":"1842","DOI":"10.1021\/ja9710114","volume":"120","author":"Landis C. 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Soc."},{"key":"ref55\/cit55a","doi-asserted-by":"crossref","first-page":"3132","DOI":"10.1021\/ic990572o","volume":"38","author":"Christe K. O.","year":"1999","journal-title":"Inorg. Chem."},{"key":"ref55\/cit55b","doi-asserted-by":"crossref","first-page":"481","DOI":"10.1021\/ja9933137","volume":"122","author":"Christe K. O.","year":"2000","journal-title":"J. Am. Chem. Soc."},{"key":"ref56\/cit56a","unstructured":"aIn general, this shortening is rationalized in terms of significant carbon 2s character in the M\u2212CF3bonds.(48, 49, 53b)Note that in some cases, such as (CX3)nE (E = P, As;n= 3 and E = Hg,n= 2) the C\u2212E bond is shorter for X = H than for X = F.(56b-56d)"},{"key":"ref56\/cit56b","doi-asserted-by":"crossref","first-page":"71","DOI":"10.1007\/BFb0045411","volume":"53","author":"Yokozeki A.","year":"1975","journal-title":"Top. Curr. 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Soc."},{"key":"ref60\/cit60c","doi-asserted-by":"crossref","first-page":"1449","DOI":"10.1039\/b718430a","volume":"32","author":"Exner O.","year":"2008","journal-title":"New J. Chem."},{"key":"ref61\/cit61","doi-asserted-by":"crossref","first-page":"1143","DOI":"10.1021\/om0610703","volume":"26","author":"Macgregor S. A.","year":"2007","journal-title":"Organometallics"},{"key":"ref62\/cit62","doi-asserted-by":"crossref","first-page":"2871","DOI":"10.1021\/ic702276k","volume":"47","author":"Cirera J.","year":"2008","journal-title":"Inorg. Chem."},{"key":"ref63\/cit63b","doi-asserted-by":"crossref","first-page":"65","DOI":"10.1007\/b95422","volume":"235","author":"Bousseksou A.","year":"2004","journal-title":"Top. Curr. 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