{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,2]],"date-time":"2026-10-02T12:03:07Z","timestamp":1790942587547,"version":"4.1.0"},"reference-count":49,"publisher":"American Chemical Society (ACS)","issue":"2","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2012,1,18]]},"DOI":"10.1021\/ja209339j","type":"journal-article","created":{"date-parts":[[2011,12,8]],"date-time":"2011-12-08T18:27:51Z","timestamp":1323368871000},"page":"1212-1220","source":"Crossref","is-referenced-by-count":60,"title":["A Stepwise Solvent-Promoted S<sub>N<\/sub>i Reaction of \u03b1-<scp>d<\/scp>-Glucopyranosyl Fluoride: Mechanistic Implications for Retaining Glycosyltransferases"],"prefix":"10.1021","volume":"134","author":[{"given":"Jefferson","family":"Chan","sequence":"first","affiliation":[{"name":"Department\rof Chemistry, Simon Fraser University, 8888 University Drive, Burnaby, BC V5A 1S6,\rCanada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ariel","family":"Tang","sequence":"additional","affiliation":[{"name":"Department\rof Chemistry, Simon Fraser University, 8888 University Drive, Burnaby, BC V5A 1S6,\rCanada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andrew J.","family":"Bennet","sequence":"additional","affiliation":[{"name":"Department\rof Chemistry, Simon Fraser University, 8888 University Drive, Burnaby, BC V5A 1S6,\rCanada"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2011,12,30]]},"reference":[{"key":"ref1\/cit1","volume-title":"Introduction to Glycobiology","author":"Taylor M. E.","year":"2003"},{"key":"ref2\/cit2","volume-title":"Comprehensive biological catalysis: A mechanistic reference","author":"Sinnott M.","year":"1998"},{"key":"ref3\/cit3","volume-title":"Carbohydrate chemistry and biochemistry: Structure and mechanism","author":"Sinnott M.","year":"2007"},{"key":"ref4\/cit4","doi-asserted-by":"crossref","first-page":"1207","DOI":"10.1039\/b108446c","author":"Bennet A. J.","year":"2002","journal-title":"J. Chem. Soc., Perkin Trans. 2"},{"key":"ref5\/cit5","first-page":"109","volume":"19","author":"Winstein S.","year":"1965","journal-title":"Spec. Publ.\u2014R. Soc. Chem."},{"key":"ref6\/cit6","volume-title":"Mechanism and theory in organic chemistry","author":"Lowry T. H.","year":"1987","edition":"3"},{"key":"ref7\/cit7","doi-asserted-by":"crossref","first-page":"1252","DOI":"10.1039\/jr9370001252","author":"Cowdrey W. A.","year":"1937","journal-title":"J. Chem. Soc."},{"key":"ref8\/cit8","doi-asserted-by":"crossref","first-page":"343","DOI":"10.1021\/ar00166a001","volume":"22","author":"Guthrie R.","year":"1989","journal-title":"Acc. Chem. Res."},{"key":"ref9\/cit9","doi-asserted-by":"crossref","first-page":"2026","DOI":"10.1021\/ja00526a043","volume":"102","author":"Sinnott M. L.","year":"1980","journal-title":"J. Am. Chem. Soc."},{"key":"ref10\/cit10","doi-asserted-by":"crossref","first-page":"631","DOI":"10.1038\/nchembio.628","volume":"7","author":"Lee S. S.","year":"2011","journal-title":"Nat. Chem. Biol."},{"key":"ref11\/cit11","doi-asserted-by":"crossref","first-page":"16030","DOI":"10.1021\/ja0659931","volume":"128","author":"Monegal A.","year":"2006","journal-title":"J. Am. Chem. Soc."},{"key":"ref12\/cit12","doi-asserted-by":"crossref","first-page":"547","DOI":"10.1093\/glycob\/cwq190","volume":"21","author":"Soya N.","year":"2011","journal-title":"Glycobiology"},{"key":"ref13\/cit13","doi-asserted-by":"crossref","first-page":"15307","DOI":"10.1073\/pnas.0405657101","volume":"101","author":"Fritz T. A.","year":"2004","journal-title":"Proc. Natl. Acad. Sci. U.S.A."},{"key":"ref14\/cit14","doi-asserted-by":"crossref","first-page":"521","DOI":"10.1146\/annurev.biochem.76.061005.092322","volume":"77","author":"Lairson L. L.","year":"2008","journal-title":"Annu. Rev. Biochem."},{"key":"ref15\/cit15","doi-asserted-by":"crossref","first-page":"2335","DOI":"10.1016\/S0040-4039(01)92248-8","author":"Schadt F. L.","year":"1974","journal-title":"Tetrahedron Lett."},{"key":"ref16\/cit16","volume-title":"Purification of laboratory chemicals","author":"Perrin D. D.","year":"1988","edition":"3"},{"key":"ref17\/cit17","doi-asserted-by":"crossref","first-page":"409","DOI":"10.1016\/0960-894X(94)80006-5","volume":"4","author":"Hardick D. J.","year":"1994","journal-title":"Bioorg. Med. Chem. Lett."},{"key":"ref18\/cit18","doi-asserted-by":"crossref","first-page":"7287","DOI":"10.1021\/ja00283a025","volume":"108","author":"Bennet A. J.","year":"1986","journal-title":"J. Am. Chem. Soc."},{"key":"ref19\/cit19","doi-asserted-by":"crossref","first-page":"1747","DOI":"10.1246\/cl.1984.1747","author":"Hayashi M.","year":"1984","journal-title":"Chem. Lett."},{"key":"ref20\/cit20","doi-asserted-by":"crossref","first-page":"405","DOI":"10.1038\/nchembio.352","volume":"6","author":"Chan J.","year":"2010","journal-title":"Nat. Chem. Biol."},{"key":"ref21\/cit21","doi-asserted-by":"crossref","first-page":"3230","DOI":"10.1021\/jo01046a518","volume":"28","author":"Gramera R. E.","year":"1963","journal-title":"J. Org. Chem."},{"key":"ref22\/cit22","doi-asserted-by":"crossref","first-page":"194","DOI":"10.1021\/jo01179a005","volume":"10","author":"Montgomery E. M.","year":"1945","journal-title":"J. Org. Chem."},{"key":"ref23\/cit23","volume-title":"An introduction to error analysis: The study of uncertainties in physical measurements","author":"Taylor J. R.","year":"1982"},{"key":"ref24\/cit24","volume-title":"Gaussian 09","author":"Frisch M. J.","year":"2009"},{"key":"ref25\/cit25","doi-asserted-by":"crossref","first-page":"75","DOI":"10.1023\/A:1019173509273","volume":"26","author":"Anisimov V.","year":"1999","journal-title":"J. Math. Chem."},{"key":"ref26\/cit26","doi-asserted-by":"crossref","first-page":"16502","DOI":"10.1021\/jp960976r","volume":"100","author":"Scott A. P.","year":"1996","journal-title":"J. Phys. Chem."},{"key":"ref27\/cit27","doi-asserted-by":"crossref","first-page":"7557","DOI":"10.1021\/ja00096a012","volume":"116","author":"Zhang Y.","year":"1994","journal-title":"J. Am. Chem. Soc."},{"key":"ref28\/cit28","volume-title":"Reaction rates of isotopic molecules","author":"Melander L. C. S.","year":"1980"},{"key":"ref29\/cit29","doi-asserted-by":"crossref","first-page":"3769","DOI":"10.1021\/ja0394028","volume":"126","author":"Lee J. K.","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"ref30\/cit30","doi-asserted-by":"crossref","first-page":"10889","DOI":"10.1021\/ja011232g","volume":"123","author":"Indurugalla D.","year":"2001","journal-title":"J. Am. Chem. Soc."},{"key":"ref31\/cit31","doi-asserted-by":"crossref","first-page":"10547","DOI":"10.1021\/bi049188f","volume":"43","author":"Cassano A. G.","year":"2004","journal-title":"Biochemistry"},{"key":"ref32\/cit32","doi-asserted-by":"crossref","first-page":"5953","DOI":"10.1021\/ja00067a008","volume":"115","author":"Marlier J. F.","year":"1993","journal-title":"J. Am. Chem. Soc."},{"key":"ref33\/cit33","doi-asserted-by":"crossref","first-page":"7951","DOI":"10.1021\/ja00021a021","volume":"113","author":"Banait N. S.","year":"1991","journal-title":"J. Am. Chem. Soc."},{"key":"ref34\/cit34","doi-asserted-by":"crossref","first-page":"7171","DOI":"10.1021\/ja01027a075","volume":"90","author":"Shiner V. J.","year":"1968","journal-title":"J. Am. Chem. Soc."},{"key":"ref35\/cit35","doi-asserted-by":"crossref","first-page":"2551","DOI":"10.1021\/ja00739a042","volume":"93","author":"Harris J. M.","year":"1971","journal-title":"J. Am. Chem. Soc."},{"key":"ref36\/cit36","doi-asserted-by":"crossref","first-page":"1029","DOI":"10.1021\/ja00733a043","volume":"93","author":"Shiner V. J.","year":"1971","journal-title":"J. Am. Chem. Soc."},{"key":"ref37\/cit37","doi-asserted-by":"crossref","first-page":"15008","DOI":"10.1021\/ja038343v","volume":"125","author":"Perrin C. L.","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"ref38\/cit38","doi-asserted-by":"crossref","first-page":"9641","DOI":"10.1021\/ja0511927","volume":"127","author":"Perrin C. L.","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"ref39\/cit39","doi-asserted-by":"crossref","first-page":"7958","DOI":"10.1021\/ja00021a022","volume":"113","author":"Banait N. S.","year":"1991","journal-title":"J. Am. Chem. Soc."},{"key":"ref40\/cit40","first-page":"19","volume":"44","author":"O\u2019Ferrall R. M.","year":"2010","journal-title":"Adv. Phys. Org. Chem."},{"key":"ref41\/cit41","doi-asserted-by":"crossref","first-page":"1437","DOI":"10.1039\/c39910001437","author":"Chateauneuf J. E.","year":"1991","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"ref42\/cit42","doi-asserted-by":"crossref","first-page":"6913","DOI":"10.1021\/ja00228a066","volume":"110","author":"McClelland R. A.","year":"1988","journal-title":"J. Am. Chem. Soc."},{"key":"ref43\/cit43","doi-asserted-by":"crossref","first-page":"1531","DOI":"10.1039\/P29960001531","author":"McClelland R. A.","year":"1996","journal-title":"J. Chem. Soc., Perkin Trans. 2"},{"key":"ref44\/cit44","doi-asserted-by":"crossref","first-page":"7888","DOI":"10.1021\/ja00202a033","volume":"111","author":"Amyes T. L.","year":"1989","journal-title":"J. Am. Chem. Soc."},{"key":"ref45\/cit45","doi-asserted-by":"crossref","first-page":"10614","DOI":"10.1021\/ja00148a002","volume":"117","author":"Huang X.","year":"1995","journal-title":"J. Am. Chem. Soc."},{"key":"ref46\/cit46","doi-asserted-by":"crossref","first-page":"4685","DOI":"10.1021\/ja808346y","volume":"131","author":"Zhang Y.","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"ref47\/cit47","doi-asserted-by":"crossref","first-page":"1234","DOI":"10.1002\/anie.200905096","volume":"49","author":"Errey J. C.","year":"2010","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref48\/cit48","doi-asserted-by":"crossref","first-page":"10897","DOI":"10.1002\/anie.201104623","volume":"49","author":"Ard\u00e8vol A.","year":"2011","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref49\/cit49","doi-asserted-by":"crossref","first-page":"2333","DOI":"10.1002\/cbic.200900429","volume":"10","author":"Goedl C.","year":"2009","journal-title":"ChemBioChem"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/ja209339j","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,4,18]],"date-time":"2023-04-18T06:39:40Z","timestamp":1681799980000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/ja209339j"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2011,12,30]]},"references-count":49,"journal-issue":{"issue":"2","published-print":{"date-parts":[[2012,1,18]]}},"alternative-id":["10.1021\/ja209339j"],"URL":"https:\/\/doi.org\/10.1021\/ja209339j","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2011,12,30]]}}}