{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,2]],"date-time":"2026-08-02T23:08:21Z","timestamp":1785712101079,"version":"3.56.0"},"reference-count":54,"publisher":"American Chemical Society (ACS)","issue":"29","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2012,7,25]]},"DOI":"10.1021\/ja300002k","type":"journal-article","created":{"date-parts":[[2012,7,12]],"date-time":"2012-07-12T14:43:56Z","timestamp":1342104236000},"page":"12010-12015","source":"Crossref","is-referenced-by-count":20,"title":["Causation in a Cascade: The Origins of Selectivities in Intramolecular Nitrone Cycloadditions"],"prefix":"10.1021","volume":"134","author":[{"given":"Elizabeth H.","family":"Krenske","sequence":"first","affiliation":[{"name":"School of\rChemistry, University of Melbourne, VIC\r3010, Australia"},{"name":"Australian\rResearch Council\rCentre of Excellence for Free Radical Chemistry and Biotechnology"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sesil","family":"Agopcan","sequence":"additional","affiliation":[{"name":"Chemistry Department, Bogazici University, 34342 Bebek, Istanbul, Turkey"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Viktorya","family":"Aviyente","sequence":"additional","affiliation":[{"name":"Chemistry Department, Bogazici University, 34342 Bebek, Istanbul, Turkey"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"K. N.","family":"Houk","sequence":"additional","affiliation":[{"name":"Department of Chemistry and\rBiochemistry, University of California, Los Angeles, California 90095, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Brian A.","family":"Johnson","sequence":"additional","affiliation":[{"name":"School of\rChemistry, University of Melbourne, VIC\r3010, Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andrew B.","family":"Holmes","sequence":"additional","affiliation":[{"name":"School of\rChemistry, University of Melbourne, VIC\r3010, Australia"},{"name":"CSIRO Materials Science and Engineering, Bag 10, Clayton South, VIC\r3169, Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2012,7,12]]},"reference":[{"key":"ref1\/cit1a","doi-asserted-by":"crossref","first-page":"3497","DOI":"10.1016\/S0040-4020(01)96703-1","volume":"41","author":"Oppolzer W.","year":"1985","journal-title":"Tetrahedron"},{"key":"ref1\/cit1b","doi-asserted-by":"crossref","first-page":"3363","DOI":"10.1021\/ja00191a038","volume":"111","author":"LeBel N. A.","year":"1989","journal-title":"J. Am. Chem. Soc."},{"key":"ref1\/cit1c","doi-asserted-by":"crossref","first-page":"3379","DOI":"10.1039\/P19940003379","author":"Fox M. E.","year":"1994","journal-title":"J. Chem. Soc., Perkin Trans. 1"},{"key":"ref1\/cit1d","doi-asserted-by":"crossref","first-page":"9047","DOI":"10.1016\/0040-4039(95)01908-Z","volume":"36","author":"Davison E. C.","year":"1995","journal-title":"Tetrahedron Lett."},{"key":"ref1\/cit1e","doi-asserted-by":"crossref","first-page":"11601","DOI":"10.1016\/0040-4020(96)00643-6","volume":"52","author":"Davison E. C.","year":"1996","journal-title":"Tetrahedron"},{"key":"ref1\/cit1f","doi-asserted-by":"crossref","first-page":"531","DOI":"10.1351\/pac199769030531","volume":"69","author":"Holmes A. B.","year":"1997","journal-title":"Pure Appl. Chem."},{"key":"ref1\/cit1g","unstructured":"gMartin, J. N.; Jones, R. C. F.InSynthetic Applications of 1,3-Dipolar Cycloaddition Chemistry Toward Heterocycles and Natural Products;Padwa, A.; Pearson, W. H., Eds.Wiley:Hoboken, NJ, 2003; pp1\u201381."},{"key":"ref2\/cit2a","doi-asserted-by":"crossref","first-page":"4900","DOI":"10.1021\/ja990138l","volume":"121","author":"Williams G. M.","year":"1999","journal-title":"J. Am. Chem. Soc."},{"key":"ref2\/cit2b","doi-asserted-by":"crossref","first-page":"1214","DOI":"10.1039\/b111514f","author":"Smith C. J.","year":"2002","journal-title":"Chem. Commun."},{"key":"ref2\/cit2c","doi-asserted-by":"crossref","first-page":"1494","DOI":"10.1039\/b200328g","author":"Davison E. C.","year":"2002","journal-title":"J. Chem. Soc., Perkin Trans. 1"},{"key":"ref2\/cit2d","doi-asserted-by":"crossref","first-page":"1258","DOI":"10.1039\/b402307b","volume":"2","author":"Horsley H. T.","year":"2004","journal-title":"Org. Biomol. Chem."},{"key":"ref2\/cit2e","doi-asserted-by":"crossref","first-page":"11471","DOI":"10.1002\/chem.201001435","volume":"16","author":"Brasholz M.","year":"2010","journal-title":"Chem.\u2014Eur. J."},{"key":"ref2\/cit2f","doi-asserted-by":"crossref","first-page":"6445","DOI":"10.1016\/j.tet.2010.04.092","volume":"66","author":"Brasholz M.","year":"2010","journal-title":"Tetrahedron"},{"key":"ref3\/cit3a","doi-asserted-by":"crossref","first-page":"9163","DOI":"10.1016\/S0040-4039(00)01640-3","volume":"41","author":"Stockman R. A.","year":"2000","journal-title":"Tetrahedron Lett."},{"key":"ref3\/cit3b","doi-asserted-by":"crossref","first-page":"1598","DOI":"10.1021\/jo035639a","volume":"69","author":"Stockman R. A.","year":"2004","journal-title":"J. Org. Chem."},{"key":"ref4\/cit4a","doi-asserted-by":"crossref","first-page":"6929","DOI":"10.1016\/S0040-4020(01)89883-5","volume":"48","author":"Grigg R.","year":"1992","journal-title":"Tetrahedron"},{"key":"ref4\/cit4b","doi-asserted-by":"crossref","first-page":"10399","DOI":"10.1016\/S0040-4020(01)88344-7","volume":"48","author":"Grigg R.","year":"1992","journal-title":"Tetrahedron"},{"key":"ref4\/cit4c","doi-asserted-by":"crossref","first-page":"372","DOI":"10.1039\/C39930000372","author":"Grigg R.","year":"1993","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"ref4\/cit4d","doi-asserted-by":"crossref","first-page":"10087","DOI":"10.1016\/S0040-4020(00)01012-7","volume":"56","author":"Dondas H. A.","year":"2000","journal-title":"Tetrahedron"},{"key":"ref4\/cit4e","doi-asserted-by":"crossref","first-page":"1119","DOI":"10.1016\/S0040-4020(00)01084-X","volume":"57","author":"Dondas H. A.","year":"2001","journal-title":"Tetrahedron"},{"key":"ref4\/cit4f","doi-asserted-by":"crossref","first-page":"9997","DOI":"10.1016\/j.tet.2003.10.027","volume":"59","author":"Dondas H. A.","year":"2003","journal-title":"Tetrahedron"},{"key":"ref6\/cit6a","doi-asserted-by":"crossref","first-page":"785","DOI":"10.1103\/PhysRevB.37.785","volume":"37","author":"Lee C.","year":"1988","journal-title":"Phys. Rev. B"},{"key":"ref6\/cit6b","doi-asserted-by":"crossref","first-page":"1372","DOI":"10.1063\/1.464304","volume":"98","author":"Becke A. D.","year":"1993","journal-title":"J. Chem. Phys."},{"key":"ref6\/cit6c","doi-asserted-by":"crossref","first-page":"5648","DOI":"10.1063\/1.464913","volume":"98","author":"Becke A. D.","year":"1993","journal-title":"J. Chem. Phys."},{"key":"ref7\/cit7","volume-title":"Gaussian 03","author":"Frisch M. J.","year":"2004"},{"key":"ref8\/cit8a","volume-title":"Spartan\u201908"},{"key":"ref9\/cit9a","doi-asserted-by":"crossref","first-page":"2154","DOI":"10.1063\/1.456010","volume":"90","author":"Gonzalez C.","year":"1989","journal-title":"J. Chem. Phys."},{"key":"ref9\/cit9b","doi-asserted-by":"crossref","first-page":"5523","DOI":"10.1021\/j100377a021","volume":"94","author":"Gonzalez C.","year":"1990","journal-title":"J. Phys. Chem."},{"key":"ref10\/cit10a","doi-asserted-by":"crossref","first-page":"215","DOI":"10.1007\/s00214-007-0310-x","volume":"120","author":"Zhao Y.","year":"2008","journal-title":"Theor. Chem. Acc."},{"key":"ref10\/cit10b","doi-asserted-by":"crossref","first-page":"157","DOI":"10.1021\/ar700111a","volume":"41","author":"Zhao Y.","year":"2008","journal-title":"Acc. Chem. Res."},{"key":"ref11\/cit11","volume-title":"Gaussian 09","author":"Frisch M. J.","year":"2009"},{"key":"ref12\/cit12a","doi-asserted-by":"crossref","first-page":"1995","DOI":"10.1021\/jp9716997","volume":"102","author":"Barone V.","year":"1998","journal-title":"J. Phys. Chem. A"},{"key":"ref12\/cit12b","doi-asserted-by":"crossref","first-page":"669","DOI":"10.1002\/jcc.10189","volume":"24","author":"Cossi M.","year":"2003","journal-title":"J. Comput. Chem."},{"key":"ref13\/cit13","volume-title":"CYLview","author":"Legault C. Y.","year":"2009"},{"key":"ref14\/cit14a","doi-asserted-by":"crossref","first-page":"9542","DOI":"10.1021\/jp052504v","volume":"109","author":"Ess D. H.","year":"2005","journal-title":"J. Phys. Chem. A"},{"key":"ref14\/cit14b","doi-asserted-by":"crossref","first-page":"13906","DOI":"10.1021\/jp207563h","volume":"115","author":"Lan Y.","year":"2011","journal-title":"J. Phys. Chem. A"},{"key":"ref15\/cit15","doi-asserted-by":"crossref","first-page":"1216","DOI":"10.1021\/jp052055z","volume":"110","author":"Jones G. O.","year":"2006","journal-title":"J. Phys. Chem. A"},{"key":"ref16\/cit16a","doi-asserted-by":"crossref","first-page":"2181","DOI":"10.1016\/j.tetlet.2010.11.121","volume":"52","author":"Krenske E. H.","year":"2011","journal-title":"Tetrahedron Lett."},{"key":"ref16\/cit16b","doi-asserted-by":"crossref","first-page":"2434","DOI":"10.1021\/ja211568k","volume":"134","author":"Krenske E. H.","year":"2012","journal-title":"J. Am. Chem. Soc."},{"key":"ref18\/cit18a","doi-asserted-by":"crossref","first-page":"5740","DOI":"10.1021\/ja01651a035","volume":"76","author":"Cram D. J.","year":"1954","journal-title":"J. Am. Chem. Soc."},{"key":"ref18\/cit18b","doi-asserted-by":"crossref","first-page":"1742","DOI":"10.1021\/jo00949a029","volume":"38","author":"Bach R. D.","year":"1973","journal-title":"J. Org. Chem."},{"key":"ref18\/cit18c","doi-asserted-by":"crossref","first-page":"2802","DOI":"10.1021\/ja00477a037","volume":"100","author":"Chiao W.-B.","year":"1978","journal-title":"J. Am. Chem. Soc."},{"key":"ref18\/cit18d","doi-asserted-by":"crossref","first-page":"3927","DOI":"10.1021\/ja00480a045","volume":"100","author":"Kwart H.","year":"1978","journal-title":"J. Am. Chem. Soc."},{"key":"ref19\/cit19a","doi-asserted-by":"crossref","first-page":"3554","DOI":"10.1021\/jp970617b","volume":"101","author":"Komaromi I.","year":"1997","journal-title":"J. Phys. Chem. A"},{"key":"ref19\/cit19b","doi-asserted-by":"crossref","first-page":"6141","DOI":"10.1021\/ja057523x","volume":"128","author":"Acevedo O.","year":"2006","journal-title":"J. Am. Chem. Soc."},{"key":"ref19\/cit19c","doi-asserted-by":"crossref","first-page":"1410","DOI":"10.1002\/anie.200703495","volume":"47","author":"Beauchemin A. M.","year":"2008","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref19\/cit19d","doi-asserted-by":"crossref","first-page":"17893","DOI":"10.1021\/ja806300r","volume":"130","author":"Moran J.","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"ref19\/cit19e","doi-asserted-by":"crossref","first-page":"874","DOI":"10.1021\/ja8077895","volume":"131","author":"Bourgeois J.","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"ref20\/cit20a","doi-asserted-by":"crossref","first-page":"3007","DOI":"10.1021\/jo00297a011","volume":"55","author":"Ciganek E.","year":"1990","journal-title":"J. Org. Chem."},{"key":"ref20\/cit20b","doi-asserted-by":"crossref","first-page":"3139","DOI":"10.1021\/ja00086a060","volume":"116","author":"Oppolzer W.","year":"1994","journal-title":"J. Am. Chem. Soc."},{"key":"ref20\/cit20c","doi-asserted-by":"crossref","first-page":"5795","DOI":"10.1021\/jo00123a013","volume":"60","author":"Ciganek E.","year":"1995","journal-title":"J. Org. Chem."},{"key":"ref21\/cit21a","doi-asserted-by":"crossref","first-page":"2456","DOI":"10.1021\/ja982762o","volume":"121","author":"Niu D.","year":"1999","journal-title":"J. Am. Chem. Soc."},{"key":"ref21\/cit21b","doi-asserted-by":"crossref","first-page":"8251","DOI":"10.1016\/S0040-4039(01)01746-4","volume":"42","author":"O\u2019Neil I. A.","year":"2001","journal-title":"Tetrahedron Lett."},{"key":"ref21\/cit21c","doi-asserted-by":"crossref","first-page":"2402","DOI":"10.1021\/jo0159082","volume":"67","author":"Moglioni A. G.","year":"2002","journal-title":"J. Org. Chem."}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/ja300002k","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,4,14]],"date-time":"2023-04-14T01:01:53Z","timestamp":1681434113000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/ja300002k"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2012,7,12]]},"references-count":54,"journal-issue":{"issue":"29","published-print":{"date-parts":[[2012,7,25]]}},"alternative-id":["10.1021\/ja300002k"],"URL":"https:\/\/doi.org\/10.1021\/ja300002k","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2012,7,12]]}}}