{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,21]],"date-time":"2026-10-21T10:27:29Z","timestamp":1792578449186,"version":"4.5.0"},"reference-count":80,"publisher":"American Chemical Society (ACS)","issue":"39","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2012,10,3]]},"DOI":"10.1021\/ja307783w","type":"journal-article","created":{"date-parts":[[2012,9,21]],"date-time":"2012-09-21T15:56:36Z","timestamp":1348242996000},"page":"16167-16170","source":"Crossref","is-referenced-by-count":203,"title":["Trifluoromethylation of \u03b1-Haloketones"],"prefix":"10.1021","volume":"134","author":[{"given":"Petr","family":"Nov\u00e1k","sequence":"first","affiliation":[{"name":"Institute of Chemical Research of Catalonia (ICIQ), Tarragona 43007, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anton","family":"Lishchynskyi","sequence":"additional","affiliation":[{"name":"Institute of Chemical Research of Catalonia (ICIQ), Tarragona 43007, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vladimir V.","family":"Grushin","sequence":"additional","affiliation":[{"name":"Institute of Chemical Research of Catalonia (ICIQ), Tarragona 43007, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2012,9,21]]},"reference":[{"key":"ref1\/cit1a","volume-title":"Chemistry of Organic Fluorine Compounds","author":"Hudlicky M.","year":"1976"},{"key":"ref1\/cit1b","volume-title":"Organofluorine Chemicals and Their Industrial Applications","author":"Banks R. E.","year":"1979"},{"key":"ref1\/cit1c","volume-title":"Biomedicinal Aspects of Fluorine Chemistry","author":"Filler R.","year":"1982"},{"key":"ref1\/cit1d","doi-asserted-by":"crossref","DOI":"10.1002\/352760393X","volume-title":"Modern Fluoroorganic Chemistry","author":"Kirsch P.","year":"2004"},{"key":"ref1\/cit1e","doi-asserted-by":"crossref","DOI":"10.1002\/9780470988589","volume-title":"Organofluorine Chemistry","author":"Uneyama K.","year":"2006"},{"key":"ref1\/cit1f","doi-asserted-by":"crossref","DOI":"10.1002\/9781444312096","volume-title":"Fluorine in Medicinal Chemistry and Chemical Biology","author":"Ojima I.","year":"2009"},{"key":"ref1\/cit1g","doi-asserted-by":"crossref","DOI":"10.1002\/9780470528952","volume-title":"Fluorinated Heterocyclic Compounds. Synthesis, Chemistry and Applications","author":"Petrov V. A.","year":"2009"},{"key":"ref2\/cit2a","doi-asserted-by":"crossref","first-page":"6119","DOI":"10.1021\/cr030143e","volume":"104","author":"Cahard D.","year":"2004","journal-title":"Chem. Rev."},{"key":"ref2\/cit2b","doi-asserted-by":"crossref","first-page":"5432","DOI":"10.1002\/anie.200600449","volume":"45","author":"Schlosser M.","year":"2006","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref2\/cit2c","doi-asserted-by":"crossref","first-page":"921","DOI":"10.1021\/ar700149s","volume":"40","author":"Prakash G. K. S.","year":"2007","journal-title":"Acc. Chem. Res."},{"key":"ref2\/cit2d","doi-asserted-by":"crossref","first-page":"975","DOI":"10.1016\/j.jfluchem.2007.04.026","volume":"128","author":"Cahard D.","year":"2007","journal-title":"J. Fluorine. Chem."},{"key":"ref2\/cit2e","doi-asserted-by":"crossref","first-page":"260","DOI":"10.2533\/chimia.2008.260","volume":"62","author":"Kieltsch I.","year":"2008","journal-title":"Chimia"},{"key":"ref2\/cit2f","doi-asserted-by":"crossref","first-page":"817","DOI":"10.1021\/ar7002573","volume":"41","author":"Uneyama K.","year":"2008","journal-title":"Acc. Chem. Res."},{"key":"ref2\/cit2g","doi-asserted-by":"crossref","first-page":"PR1","DOI":"10.1021\/cr800221v","volume":"108","author":"Ma J.-A.","year":"2008","journal-title":"Chem. Rev."},{"key":"ref2\/cit2h","doi-asserted-by":"crossref","first-page":"65","DOI":"10.3762\/bjoc.6.65","volume":"6","author":"Shibata N.","year":"2010","journal-title":"Beilstein J. Org. Chem"},{"key":"ref2\/cit2i","first-page":"1865","author":"Sato K.","year":"2010","journal-title":"Synthesis"},{"key":"ref2\/cit2j","doi-asserted-by":"crossref","first-page":"1022","DOI":"10.1016\/j.progpolymsci.2010.04.003","volume":"35","author":"Dhara M. G.","year":"2010","journal-title":"Prog. Polym. Sci."},{"key":"ref2\/cit2k","first-page":"33","volume":"28","author":"Koller R.","year":"2010","journal-title":"Chim. Oggi"},{"key":"ref2\/cit2l","doi-asserted-by":"crossref","first-page":"2161","DOI":"10.1016\/j.tet.2011.01.002","volume":"67","author":"Roy S.","year":"2011","journal-title":"Tetrahedron"},{"key":"ref2\/cit2m","doi-asserted-by":"crossref","first-page":"4475","DOI":"10.1021\/cr1004293","volume":"111","author":"Tomashenko O. A.","year":"2011","journal-title":"Chem. Rev."},{"key":"ref2\/cit2n","doi-asserted-by":"crossref","first-page":"1052","DOI":"10.1055\/s-0030-1259947","author":"Qing F.-L.","year":"2011","journal-title":"Synlett"},{"key":"ref2\/cit2o","doi-asserted-by":"crossref","first-page":"831","DOI":"10.1002\/ejoc.201001558","author":"Dilman A. D.","year":"2011","journal-title":"Eur. J. Org. Chem."},{"key":"ref2\/cit2p","doi-asserted-by":"crossref","first-page":"455","DOI":"10.1021\/cr100166a","volume":"111","author":"Nie J.","year":"2011","journal-title":"Chem. Rev."},{"key":"ref2\/cit2q","doi-asserted-by":"crossref","first-page":"803","DOI":"10.1016\/j.tet.2010.11.068","volume":"67","author":"Grygorenko O. O.","year":"2011","journal-title":"Tetrahedron"},{"key":"ref2\/cit2r","doi-asserted-by":"crossref","first-page":"1591","DOI":"10.1055\/s-0031-1289756","volume":"44","author":"Acena J. L.","year":"2012","journal-title":"Synthesis"},{"key":"ref2\/cit2s","doi-asserted-by":"crossref","first-page":"2479","DOI":"10.1002\/ejoc.201101535","author":"Mac\u00e9 Y.","year":"2012","journal-title":"Eur. J. Org. Chem."},{"key":"ref3\/cit3","doi-asserted-by":"crossref","first-page":"7","DOI":"10.1016\/j.jfluchem.2012.04.012","volume":"140","author":"Han W.","year":"2012","journal-title":"J. Fluorine Chem."},{"key":"ref4\/cit4","doi-asserted-by":"crossref","first-page":"57","DOI":"10.1021\/bk-2005-0911.ch003","volume":"911","author":"Langlois B. R.","year":"2005","journal-title":"ACS Symp. Ser."},{"key":"ref5\/cit5a","unstructured":"aA high-temperature (550 \u00b0C) gas-phase catalytic process has been recently developed(5b)to produce CF\n                      3\n                      I from CHF\n                      3\n                      and I\n                      2\n                      at up to ca. 80% conversion and ca. 60% selectivity. The high cost of iodine puts limitations on many applications of CF\n                      3\n                      I.(3)"},{"key":"ref5\/cit5b","doi-asserted-by":"crossref","first-page":"121","DOI":"10.1016\/j.cattod.2003.11.007","volume":"88","author":"Nagasaki N.","year":"2004","journal-title":"Catal. Today"},{"key":"ref6\/cit6a","doi-asserted-by":"crossref","first-page":"20901","DOI":"10.1021\/ja2081026","volume":"133","author":"Zanardi A.","year":"2011","journal-title":"J. Am. Chem. Soc."},{"key":"ref6\/cit6b","unstructured":"bPatent pending."},{"key":"ref7\/cit7","doi-asserted-by":"crossref","first-page":"7767","DOI":"10.1002\/anie.201201613","volume":"51","author":"Nov\u00e1k P.","year":"2012","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref8\/cit8","doi-asserted-by":"crossref","first-page":"3815","DOI":"10.1021\/jo9004348","volume":"74","author":"Sato K.","year":"2009","journal-title":"J. Org. Chem."},{"key":"ref9\/cit9","doi-asserted-by":"crossref","first-page":"6119","DOI":"10.1002\/anie.201101861","volume":"50","author":"Pham P. V.","year":"2011","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref10\/cit10a","doi-asserted-by":"crossref","first-page":"6391","DOI":"10.1016\/S0040-4039(00)97073-4","volume":"31","author":"Miura K.","year":"1990","journal-title":"Tetrahedron Lett."},{"key":"ref10\/cit10b","doi-asserted-by":"crossref","first-page":"1291","DOI":"10.1016\/S0040-4039(00)91604-6","volume":"33","author":"Langlois B. R.","year":"1992","journal-title":"Tetrahedron Lett."},{"key":"ref10\/cit10c","doi-asserted-by":"crossref","first-page":"2156","DOI":"10.1021\/ja00059a009","volume":"115","author":"Umemoto T.","year":"1993","journal-title":"J. Am. Chem. Soc."},{"key":"ref10\/cit10d","doi-asserted-by":"crossref","first-page":"5692","DOI":"10.1021\/jo00098a030","volume":"59","author":"Umemoto T.","year":"1994","journal-title":"J. Org. Chem."},{"key":"ref10\/cit10e","doi-asserted-by":"crossref","first-page":"155","DOI":"10.1080\/10426509708031590","volume":"129","author":"Kamigata N.","year":"1997","journal-title":"Phosphorus, Sulfur Silicon Relat. Elem."},{"key":"ref10\/cit10f","doi-asserted-by":"crossref","first-page":"8726","DOI":"10.1021\/jo034881e","volume":"68","author":"Ma J.-A.","year":"2003","journal-title":"J. Org. Chem."},{"key":"ref10\/cit10g","doi-asserted-by":"crossref","first-page":"335","DOI":"10.1016\/S0968-0896(02)00457-1","volume":"11","author":"Blazejewski J.-C.","year":"2003","journal-title":"Bioorg. Med. Chem."},{"key":"ref10\/cit10h","doi-asserted-by":"crossref","first-page":"649","DOI":"10.1021\/ol047565a","volume":"7","author":"Itoh Y.","year":"2005","journal-title":"Org. Lett."},{"key":"ref10\/cit10i","doi-asserted-by":"crossref","first-page":"4883","DOI":"10.1021\/ol0517574","volume":"7","author":"Itoh Y.","year":"2005","journal-title":"Org. Lett."},{"key":"ref10\/cit10j","doi-asserted-by":"crossref","first-page":"539","DOI":"10.1016\/j.jfluchem.2006.03.011","volume":"127","author":"Itoh Y.","year":"2006","journal-title":"J. Fluorine Chem."},{"key":"ref10\/cit10k","doi-asserted-by":"crossref","first-page":"4671","DOI":"10.1021\/ol0611301","volume":"8","author":"Mikami K.","year":"2006","journal-title":"Org. Lett."},{"key":"ref10\/cit10l","doi-asserted-by":"crossref","first-page":"7141","DOI":"10.1016\/S0040-4020(06)00915-X","volume":"62","author":"Itoh Y.","year":"2006","journal-title":"Tetrahedron"},{"key":"ref10\/cit10m","doi-asserted-by":"crossref","first-page":"8918","DOI":"10.1021\/jo0616153","volume":"71","author":"Itoh Y.","year":"2006","journal-title":"J. Org. Chem."},{"key":"ref10\/cit10n","doi-asserted-by":"crossref","first-page":"8922","DOI":"10.1016\/j.tetlet.2007.10.041","volume":"48","author":"Yomita Y.","year":"2007","journal-title":"Tetrahedron Lett."},{"key":"ref10\/cit10o","doi-asserted-by":"crossref","first-page":"3327","DOI":"10.1016\/j.tetlet.2007.03.097","volume":"48","author":"Petrik V.","year":"2007","journal-title":"Tetrahedron Lett."},{"key":"ref10\/cit10p","doi-asserted-by":"crossref","first-page":"754","DOI":"10.1002\/anie.200603497","volume":"46","author":"Kieltsch I.","year":"2007","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref10\/cit10q","doi-asserted-by":"crossref","first-page":"1080","DOI":"10.1246\/cl.2008.1080","volume":"37","author":"Tomita Y.","year":"2008","journal-title":"Chem. Lett."},{"key":"ref10\/cit10r","doi-asserted-by":"crossref","first-page":"3465","DOI":"10.1002\/ejoc.200800419","author":"Noritake S.","year":"2008","journal-title":"Eur. J. Org. Chem."},{"key":"ref10\/cit10s","doi-asserted-by":"crossref","first-page":"3558","DOI":"10.1016\/j.tetlet.2008.04.030","volume":"49","author":"Sato K.","year":"2008","journal-title":"Tetrahedron Lett."},{"key":"ref10\/cit10t","doi-asserted-by":"crossref","first-page":"51","DOI":"10.1016\/j.jfluchem.2007.08.013","volume":"129","author":"Sato K.","year":"2008","journal-title":"J. Fluorine Chem."},{"key":"ref10\/cit10u","doi-asserted-by":"crossref","first-page":"3599","DOI":"10.1039\/b909641h","volume":"7","author":"Noritake S.","year":"2009","journal-title":"Org. Biomol. Chem."},{"key":"ref10\/cit10v","doi-asserted-by":"crossref","first-page":"10875","DOI":"10.1021\/ja9053338","volume":"131","author":"Nagib D. A.","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"ref10\/cit10w","doi-asserted-by":"crossref","first-page":"4986","DOI":"10.1021\/ja100748y","volume":"132","author":"Allen A. E.","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"ref10\/cit10x","doi-asserted-by":"crossref","first-page":"5762","DOI":"10.1021\/ol2023328","volume":"13","author":"Matou\u0161ek V.","year":"2011","journal-title":"Org. Lett."},{"key":"ref10\/cit10y","doi-asserted-by":"crossref","first-page":"6976","DOI":"10.1021\/ja302552e","volume":"134","author":"Herrmann A. T.","year":"2012","journal-title":"J. Am. Chem. Soc."},{"key":"ref10\/cit10z","doi-asserted-by":"crossref","first-page":"10769","DOI":"10.1021\/ja3039773","volume":"134","author":"Deng Q.-H.","year":"2012","journal-title":"J. Am. Chem. Soc."},{"key":"ref10\/cit10aa","doi-asserted-by":"crossref","first-page":"2636","DOI":"10.1016\/j.tet.2012.01.075","volume":"68","author":"Ohtsuka Y.","year":"2012","journal-title":"Tetrahedron"},{"key":"ref11\/cit11","doi-asserted-by":"crossref","first-page":"6632","DOI":"10.1039\/c1cc11765c","volume":"47","author":"Zhang C.-P.","year":"2011","journal-title":"Chem. Commun."},{"key":"ref12\/cit12a","first-page":"942","author":"Belen\u2019kii G. G.","year":"1974","journal-title":"Izv. Akad. Nauk SSSR, Ser. Khim"},{"key":"ref12\/cit12b","doi-asserted-by":"crossref","first-page":"43","DOI":"10.1055\/s-1989-27144","author":"Kamitori Y.","year":"1989","journal-title":"Synthesis"},{"key":"ref12\/cit12c","doi-asserted-by":"crossref","first-page":"217","DOI":"10.1016\/S0022-1139(00)00339-0","volume":"106","author":"Kirij N. V.","year":"2000","journal-title":"J. Fluorine Chem."},{"key":"ref12\/cit12d","doi-asserted-by":"crossref","first-page":"19","DOI":"10.1016\/S0022-1139(00)82989-9","volume":"14","author":"Fields R.","year":"1979","journal-title":"J. Fluorine Chem."},{"key":"ref12\/cit12e","doi-asserted-by":"crossref","first-page":"299","DOI":"10.1016\/S0022-1139(00)81290-7","volume":"17","author":"Tordeux M.","year":"1981","journal-title":"J. Fluorine Chem."},{"key":"ref12\/cit12f","doi-asserted-by":"crossref","first-page":"99","DOI":"10.1016\/S0022-1139(00)81235-X","volume":"21","author":"Tordeux M.","year":"1982","journal-title":"J. Fluorine Chem."},{"key":"ref12\/cit12g","doi-asserted-by":"crossref","first-page":"9085","DOI":"10.1002\/anie.201103526","volume":"50","author":"Morandi B.","year":"2011","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref13\/cit13","doi-asserted-by":"crossref","first-page":"757","DOI":"10.1021\/cr9408991","volume":"97","author":"Prakash G. K. S.","year":"1997","journal-title":"Chem. Rev."},{"key":"ref15\/cit15","first-page":"31","volume":"28","author":"McClinton M. A.","year":"1995","journal-title":"Aldrichimica Acta"},{"key":"ref17\/cit17","doi-asserted-by":"crossref","first-page":"o661","DOI":"10.1107\/S1600536802008590","volume":"58","author":"Cox P. J.","year":"2002","journal-title":"Acta Crystallogr., Sect. E"},{"key":"ref18\/cit18a","doi-asserted-by":"crossref","first-page":"4253","DOI":"10.1021\/ja00993a001","volume":"89","author":"Pople J. A.","year":"1967","journal-title":"J. Am. Chem. Soc."},{"key":"ref18\/cit18b","doi-asserted-by":"crossref","first-page":"2337","DOI":"10.1021\/ja00842a004","volume":"97","author":"Holmes S. A.","year":"1975","journal-title":"J. Am. Chem. Soc."},{"key":"ref18\/cit18c","doi-asserted-by":"crossref","first-page":"225","DOI":"10.1016\/S0166-1280(00)00391-2","volume":"500","author":"Palmer M. H.","year":"2000","journal-title":"J. Mol. Struct."},{"key":"ref18\/cit18d","doi-asserted-by":"crossref","first-page":"4236","DOI":"10.1021\/ja9005699","volume":"131","author":"Goodman J.","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"ref18\/cit18e","doi-asserted-by":"crossref","first-page":"12013","DOI":"10.1021\/ja1039693","volume":"132","author":"Goodman J.","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"ref18\/cit18f","doi-asserted-by":"crossref","first-page":"1467","DOI":"10.1021\/om2011003","volume":"31","author":"Algarra A. G.","year":"2012","journal-title":"Organometallics"},{"key":"ref19\/cit19","doi-asserted-by":"crossref","first-page":"10240","DOI":"10.1021\/ja0467768","volume":"126","author":"Malosh C. F.","year":"2004","journal-title":"J. Am. Chem. Soc."}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/ja307783w","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,4,22]],"date-time":"2023-04-22T09:51:16Z","timestamp":1682157076000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/ja307783w"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2012,9,21]]},"references-count":80,"journal-issue":{"issue":"39","published-print":{"date-parts":[[2012,10,3]]}},"alternative-id":["10.1021\/ja307783w"],"URL":"https:\/\/doi.org\/10.1021\/ja307783w","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2012,9,21]]}}}