{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T22:11:51Z","timestamp":1791324711082,"version":"4.3.1"},"reference-count":56,"publisher":"American Chemical Society (ACS)","issue":"50","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2013,12,18]]},"DOI":"10.1021\/ja411146x","type":"journal-article","created":{"date-parts":[[2013,12,5]],"date-time":"2013-12-05T19:26:16Z","timestamp":1386271576000},"page":"18815-18823","source":"Crossref","is-referenced-by-count":133,"title":["Polycationic Ligands in Gold Catalysis: Synthesis and Applications of Extremely \u03c0-Acidic Catalysts"],"prefix":"10.1021","volume":"135","author":[{"given":"Javier","family":"Carreras","sequence":"first","affiliation":[{"name":"Max-Planck-Institut f\u00fcr Kohlenforschung, Kaiser\rWilhelm Platz 1, M\u00fclheim an der Ruhr, 45470, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gopinadhanpillai","family":"Gopakumar","sequence":"additional","affiliation":[{"name":"Max-Planck-Institut f\u00fcr Kohlenforschung, Kaiser\rWilhelm Platz 1, M\u00fclheim an der Ruhr, 45470, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liangu","family":"Gu","sequence":"additional","affiliation":[{"name":"Max-Planck-Institut f\u00fcr Kohlenforschung, Kaiser\rWilhelm Platz 1, M\u00fclheim an der Ruhr, 45470, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ana","family":"Gimeno","sequence":"additional","affiliation":[{"name":"Max-Planck-Institut f\u00fcr Kohlenforschung, Kaiser\rWilhelm Platz 1, M\u00fclheim an der Ruhr, 45470, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pawel","family":"Linowski","sequence":"additional","affiliation":[{"name":"Max-Planck-Institut f\u00fcr Kohlenforschung, Kaiser\rWilhelm Platz 1, M\u00fclheim an der Ruhr, 45470, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jekaterina","family":"Petu\u0161kova","sequence":"additional","affiliation":[{"name":"Max-Planck-Institut f\u00fcr Kohlenforschung, Kaiser\rWilhelm Platz 1, M\u00fclheim an der Ruhr, 45470, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Walter","family":"Thiel","sequence":"additional","affiliation":[{"name":"Max-Planck-Institut f\u00fcr Kohlenforschung, Kaiser\rWilhelm Platz 1, M\u00fclheim an der Ruhr, 45470, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Manuel","family":"Alcarazo","sequence":"additional","affiliation":[{"name":"Max-Planck-Institut f\u00fcr Kohlenforschung, Kaiser\rWilhelm Platz 1, M\u00fclheim an der Ruhr, 45470, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2013,12,5]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"crossref","first-page":"366","DOI":"10.1002\/anie.200461189","volume":"44","author":"Christmann U.","year":"2005","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref2\/cit2a","doi-asserted-by":"crossref","first-page":"1936","DOI":"10.1021\/ic061926w","volume":"46","author":"Hartwig J. F.","year":"2007","journal-title":"Inorg. Chem."},{"key":"ref2\/cit2b","doi-asserted-by":"crossref","first-page":"12003","DOI":"10.1021\/ja073747z","volume":"129","author":"Barder T. E.","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"ref3\/cit3","doi-asserted-by":"crossref","first-page":"313","DOI":"10.1021\/cr60307a002","volume":"77","author":"Tolman C. A.","year":"1977","journal-title":"Chem. Rev."},{"key":"ref5\/cit5a","doi-asserted-by":"crossref","first-page":"225","DOI":"10.1038\/166225a0","volume":"166","author":"Bennet F. W.","year":"1950","journal-title":"Nature"},{"key":"ref5\/cit5b","doi-asserted-by":"crossref","first-page":"4280","DOI":"10.1002\/chem.200701786","volume":"14","author":"Drews T.","year":"2008","journal-title":"Chem.\u2014Eur. J."},{"key":"ref6\/cit6a","doi-asserted-by":"crossref","first-page":"16753","DOI":"10.1021\/ja306947m","volume":"134","author":"Carreras J.","year":"2012","journal-title":"J. Am. Chem. Soc."},{"key":"ref6\/cit6b","doi-asserted-by":"crossref","first-page":"20758","DOI":"10.1021\/ja210223s","volume":"133","author":"Petu\u0161kova J.","year":"2011","journal-title":"J. Am. Chem. Soc."},{"key":"ref6\/cit6c","doi-asserted-by":"crossref","first-page":"16321","DOI":"10.1021\/ja106172d","volume":"132","author":"Weigand J. J.","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"ref7\/cit7a","doi-asserted-by":"crossref","first-page":"1401","DOI":"10.1016\/j.inoche.2008.09.004","volume":"11","author":"Andrieu J.","year":"2008","journal-title":"Inorg. Chem. Commun."},{"key":"ref7\/cit7b","doi-asserted-by":"crossref","first-page":"39","DOI":"10.1016\/j.inoche.2012.08.001","volume":"25","author":"Digard E.","year":"2012","journal-title":"Inorg. Chem. Commun."},{"key":"ref7\/cit7c","doi-asserted-by":"crossref","first-page":"3799","DOI":"10.1002\/anie.201100338","volume":"50","author":"Petu\u0161kova J.","year":"2011","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref7\/cit7d","doi-asserted-by":"crossref","first-page":"5562","DOI":"10.1021\/ic900348x","volume":"48","author":"Canac Y.","year":"2009","journal-title":"Inorg. Chem."},{"key":"ref7\/cit7e","doi-asserted-by":"crossref","first-page":"13095","DOI":"10.1002\/chem.201001721","volume":"16","author":"Abdellah I.","year":"2010","journal-title":"Chem.\u2014Eur. J."},{"key":"ref7\/cit7f","doi-asserted-by":"crossref","first-page":"17","DOI":"10.1039\/C1NJ20808J","volume":"36","author":"Canac Y.","year":"2012","journal-title":"New J. Chem."},{"key":"ref8\/cit8","doi-asserted-by":"crossref","first-page":"5229","DOI":"10.1039\/b710923g","author":"Coles M. P.","year":"2007","journal-title":"Chem. Commun."},{"key":"ref9\/cit9a","doi-asserted-by":"crossref","first-page":"4711","DOI":"10.1002\/chem.200701926","volume":"14","author":"Schoeller W. W.","year":"2008","journal-title":"Chem.\u2014Eur. J."},{"key":"ref9\/cit9b","doi-asserted-by":"crossref","first-page":"16321","DOI":"10.1021\/ja106172d","volume":"132","author":"Weigand J. J.","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"ref10\/cit10","doi-asserted-by":"crossref","first-page":"1236","DOI":"10.1021\/ic801870w","volume":"48","author":"Azuori M.","year":"2009","journal-title":"Inorg. Chem."},{"key":"ref11\/cit11","doi-asserted-by":"crossref","first-page":"1210","DOI":"10.1021\/om000687w","volume":"20","author":"Smith J. M.","year":"2001","journal-title":"Organometallics"},{"key":"ref12\/cit12","doi-asserted-by":"crossref","first-page":"763","DOI":"10.1021\/om800933x","volume":"28","author":"Gusev D. G.","year":"2009","journal-title":"Organometallics"},{"key":"ref13\/cit13a","doi-asserted-by":"crossref","first-page":"3326","DOI":"10.1021\/cr0684319","volume":"108","author":"Jim\u00e9nez-N\u00fa\u00f1ez E.","year":"2008","journal-title":"Chem. Rev."},{"key":"ref13\/cit13b","doi-asserted-by":"crossref","first-page":"3351","DOI":"10.1021\/cr068430g","volume":"108","author":"Gorin D. J.","year":"2008","journal-title":"Chem. Rev."},{"key":"ref13\/cit13c","doi-asserted-by":"crossref","first-page":"3410","DOI":"10.1002\/anie.200604335","volume":"46","author":"F\u00fcrstner A.","year":"2007","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref13\/cit13d","doi-asserted-by":"crossref","first-page":"2448","DOI":"10.1039\/C1CS15279C","volume":"41","author":"Rudolph M.","year":"2012","journal-title":"Chem. Soc. Rev."},{"key":"ref14\/cit14","doi-asserted-by":"crossref","first-page":"4556","DOI":"10.1002\/chem.200400220","volume":"10","author":"Mamane V.","year":"2004","journal-title":"Chem.\u2014Eur. J."},{"key":"ref15\/cit15","doi-asserted-by":"crossref","first-page":"4105","DOI":"10.1021\/jo00278a023","volume":"54","author":"Singh S. B.","year":"1989","journal-title":"J. Org. Chem."},{"key":"ref16\/cit16","doi-asserted-by":"crossref","first-page":"4542","DOI":"10.1021\/om0605332","volume":"25","author":"Soriano E.","year":"2006","journal-title":"Organometallics"},{"key":"ref17\/cit17","doi-asserted-by":"crossref","first-page":"1084","DOI":"10.1016\/j.phytochem.2007.12.005","volume":"69","author":"Kov\u00e1cs A.","year":"2008","journal-title":"Phytochemistry"},{"key":"ref18\/cit18","doi-asserted-by":"crossref","first-page":"2083","DOI":"10.1016\/S0031-9422(00)83127-1","volume":"9","author":"Majumder P. L.","year":"1985","journal-title":"Phytochemistry"},{"key":"ref19\/cit19","doi-asserted-by":"crossref","first-page":"605","DOI":"10.1021\/np200788u","volume":"75","author":"Yoshikawa K.","year":"2012","journal-title":"J. Nat. Prod."},{"key":"ref20\/cit20","doi-asserted-by":"crossref","first-page":"5726","DOI":"10.1002\/ejoc.200700583","author":"Stavrakov G.","year":"2007","journal-title":"Eur. J. Org. Chem."},{"key":"ref21\/cit21","doi-asserted-by":"crossref","first-page":"2005","DOI":"10.1081\/SCC-200066658","volume":"35","author":"Potenziano J.","year":"2005","journal-title":"Synth. Commun."},{"key":"ref22\/cit22a","doi-asserted-by":"crossref","first-page":"561","DOI":"10.1080\/00397918908050700","volume":"19","author":"Ohira S.","year":"1989","journal-title":"Synth. Commun."},{"key":"ref22\/cit22b","doi-asserted-by":"crossref","first-page":"521","DOI":"10.1055\/s-1996-5474","author":"Muller S.","year":"1996","journal-title":"Synlett."},{"key":"ref23\/cit23","doi-asserted-by":"crossref","first-page":"1131","DOI":"10.1039\/p19820001131","author":"Majumder P.","year":"1982","journal-title":"J. Chem. Soc. Perkin I"},{"key":"ref24\/cit24a","doi-asserted-by":"crossref","first-page":"2717","DOI":"10.1021\/ct900441f","volume":"5","author":"Pernpointner M.","year":"2009","journal-title":"J. Chem. Theory Comput."},{"key":"ref24\/cit24b","doi-asserted-by":"crossref","first-page":"2206","DOI":"10.1021\/om900710v","volume":"29","author":"Lein M.","year":"2010","journal-title":"Organometallics"},{"key":"ref25\/cit25a","doi-asserted-by":"crossref","first-page":"41","DOI":"10.1016\/0301-0104(73)80059-X","volume":"2","author":"Baerends E. J.","year":"1973","journal-title":"Chem. Phys."},{"key":"ref25\/cit25b","doi-asserted-by":"crossref","first-page":"931","DOI":"10.1002\/jcc.1056","volume":"22","author":"Velde G. T.","year":"2001","journal-title":"J. Comput. Chem."},{"key":"ref25\/cit25c","unstructured":"cSCM.ADF 2010.02;Theoretical Chemistry,Vrije Universiteit:Amsterdam, The Netherlands, 2008; http:\/\/www.scm.com\/."},{"key":"ref26\/cit26a","doi-asserted-by":"crossref","first-page":"9783","DOI":"10.1063\/1.467943","volume":"101","author":"van Lenthe E.","year":"1994","journal-title":"J. Chem. Phys."},{"key":"ref26\/cit26b","doi-asserted-by":"crossref","first-page":"8943","DOI":"10.1063\/1.478813","volume":"110","author":"van Lenthe E.","year":"1999","journal-title":"J. Chem. Phys."},{"key":"ref27\/cit27","doi-asserted-by":"crossref","first-page":"3098","DOI":"10.1103\/PhysRevA.38.3098","volume":"38","author":"Becke A. D.","year":"1988","journal-title":"Phys. Rev. A"},{"key":"ref28\/cit28","doi-asserted-by":"crossref","first-page":"8822","DOI":"10.1103\/PhysRevB.33.8822","volume":"33","author":"Perdew J. P.","year":"1986","journal-title":"Phys. Rev. B"},{"key":"ref29\/cit29a","doi-asserted-by":"crossref","first-page":"2571","DOI":"10.1063\/1.463096","volume":"97","author":"Sch\u00e4fer A.","year":"1992","journal-title":"J. Chem. Phys."},{"key":"ref29\/cit29b","doi-asserted-by":"crossref","first-page":"3297","DOI":"10.1039\/b508541a","volume":"7","author":"Weigend F.","year":"2005","journal-title":"Phys. Chem. Chem. Phys."},{"key":"ref29\/cit29c","doi-asserted-by":"crossref","first-page":"1057","DOI":"10.1039\/b515623h","volume":"8","author":"Weigend F.","year":"2006","journal-title":"Phys. Chem. Chem. Phys."},{"key":"ref30\/cit30","doi-asserted-by":"crossref","first-page":"123","DOI":"10.1007\/BF01114537","volume":"77","author":"Andrae D.","year":"1990","journal-title":"Theor. Chim. Acta"},{"key":"ref31\/cit31a","doi-asserted-by":"crossref","first-page":"652","DOI":"10.1016\/0009-2614(95)00838-U","volume":"242","author":"Eichkorn K.","year":"1995","journal-title":"Chem. Phys. Lett."},{"key":"ref31\/cit31b","doi-asserted-by":"crossref","first-page":"119","DOI":"10.1007\/s002140050244","volume":"97","author":"Eichkorn K.","year":"1997","journal-title":"Theor. Chem. Acc."},{"key":"ref31\/cit31c","doi-asserted-by":"crossref","first-page":"4285","DOI":"10.1039\/b204199p","volume":"4","author":"Weigend F.","year":"2002","journal-title":"Phys. Chem. Chem. Phys."},{"key":"ref32\/cit32","doi-asserted-by":"crossref","first-page":"799","DOI":"10.1039\/P29930000799","volume":"5","author":"Klamt A.","year":"1993","journal-title":"J. Chem. Soc. Perkin Trans. 2"},{"key":"ref33\/cit33","doi-asserted-by":"crossref","first-page":"154104","DOI":"10.1063\/1.3382344","volume":"132","author":"Grimme S.","year":"2010","journal-title":"J. Chem. Phys."},{"key":"ref34\/cit34a","doi-asserted-by":"crossref","first-page":"165","DOI":"10.1016\/0009-2614(89)85118-8","volume":"162","author":"Ahlrichs R.","year":"1989","journal-title":"Chem. Phys. Lett."},{"key":"ref34\/cit34b","unstructured":"bTURBOMOLEversion 6.4;University of Karlsruhe and Forschungszentrum Karlsruhe GmbH:Germany, 2012; http:\/\/www.turbomole.com."}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/ja411146x","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,4,6]],"date-time":"2023-04-06T06:23:48Z","timestamp":1680762228000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/ja411146x"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2013,12,5]]},"references-count":56,"journal-issue":{"issue":"50","published-print":{"date-parts":[[2013,12,18]]}},"alternative-id":["10.1021\/ja411146x"],"URL":"https:\/\/doi.org\/10.1021\/ja411146x","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2013,12,5]]}}}