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Soc."},{"key":"ref16\/cit16","doi-asserted-by":"crossref","first-page":"40","DOI":"10.1039\/C39750000040","volume":"2","author":"Holloway J. H.","year":"1975","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"ref17\/cit17","doi-asserted-by":"crossref","first-page":"2632","DOI":"10.1021\/ic50211a031","volume":"19","author":"Holloway J. H.","year":"1980","journal-title":"Inorg. Chem."},{"key":"ref18\/cit18","doi-asserted-by":"crossref","first-page":"3363","DOI":"10.1021\/ic50224a043","volume":"20","author":"Holloway J. H.","year":"1981","journal-title":"Inorg. Chem."},{"key":"ref19\/cit19","doi-asserted-by":"crossref","first-page":"2163","DOI":"10.1021\/ic00233a013","volume":"13","author":"Christe K. O.","year":"1986","journal-title":"Inorg. Chem."},{"key":"ref20\/cit20","doi-asserted-by":"crossref","first-page":"906","DOI":"10.1107\/S0567740875004074","volume":"31","author":"Tucker P. A.","year":"1975","journal-title":"Acta Crystallogr."},{"key":"ref21\/cit21","doi-asserted-by":"crossref","first-page":"195","DOI":"10.1016\/0020-1650(72)80110-7","volume":"8","author":"Sladky F.","year":"1972","journal-title":"Inorg. Nucl. Chem. Lett."},{"key":"ref22\/cit22","doi-asserted-by":"crossref","first-page":"1068","DOI":"10.1021\/ic00133a039","volume":"21","author":"Birchall T.","year":"1982","journal-title":"Inorg. Chem."},{"key":"ref23\/cit23","doi-asserted-by":"crossref","first-page":"606","DOI":"10.1016\/j.ccr.2008.07.014","volume":"253","author":"Riedel S.","year":"2009","journal-title":"Coord. Chem. Rev."},{"key":"ref24\/cit24","doi-asserted-by":"crossref","first-page":"2921","DOI":"10.1021\/ja00086a025","volume":"116","author":"Mercier H. P. A.","year":"1994","journal-title":"J. Am. Chem. Soc."},{"key":"ref25\/cit25","doi-asserted-by":"crossref","first-page":"5533","DOI":"10.1021\/ja030649e","volume":"126","author":"Mercier H. P. A.","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"ref26\/cit26","doi-asserted-by":"crossref","first-page":"49","DOI":"10.1021\/ic0400890","volume":"44","author":"Mercier H. P. A.","year":"2005","journal-title":"Inorg. Chem."},{"key":"ref27\/cit27","doi-asserted-by":"crossref","first-page":"269","DOI":"10.1002\/zaac.19332100307","volume":"210","author":"Ebert F.","year":"1933","journal-title":"Z. Anorg. Allg. Chem."},{"key":"ref28\/cit28","doi-asserted-by":"crossref","first-page":"2727","DOI":"10.1021\/ic50129a046","volume":"11","author":"Seppelt K.","year":"1973","journal-title":"Inorg. Chem."},{"key":"ref29\/cit29","doi-asserted-by":"crossref","first-page":"69","DOI":"10.1016\/0022-1902(76)80599-4","author":"Sladky F.","year":"1976","journal-title":"J. Inorg. Nucl. Chem., H. H. Hyman Memorial Volume"},{"key":"ref30\/cit30","first-page":"2743","volume":"11","author":"Riedel S.","year":"2005","journal-title":"Chem.\u2500Eur. J."},{"key":"ref31\/cit31","doi-asserted-by":"crossref","first-page":"441","DOI":"10.1021\/j100785a001","volume":"68","author":"Bondi A.","year":"1964","journal-title":"J. Phys. Chem."},{"key":"ref32\/cit32","doi-asserted-by":"crossref","first-page":"89","DOI":"10.1016\/S0022-1139(01)00416-X","volume":"110","author":"Fir B. A.","year":"2001","journal-title":"J. Fluorine Chem."},{"key":"ref33\/cit33","doi-asserted-by":"crossref","first-page":"2832","DOI":"10.1039\/b801115j","author":"Cordero B.","year":"2008","journal-title":"Dalton Trans."},{"key":"ref34\/cit34","doi-asserted-by":"crossref","first-page":"4478","DOI":"10.1021\/ic900242m","volume":"48","author":"Hughes M. J.","year":"2009","journal-title":"Inorg. Chem."},{"key":"ref35\/cit35","doi-asserted-by":"crossref","first-page":"6153","DOI":"10.1021\/ic100766d","volume":"49","author":"Nieboer J.","year":"2010","journal-title":"Inorg. Chem."},{"key":"ref36\/cit36","doi-asserted-by":"crossref","first-page":"660","DOI":"10.1016\/j.jfluchem.2011.05.010","volume":"132","author":"Hughes M. J.","year":"2011","journal-title":"J. Fluorine Chem."},{"key":"ref37\/cit37","doi-asserted-by":"crossref","first-page":"842","DOI":"10.1126\/science.139.3557.842","volume":"139","author":"Agron P. A.","year":"1963","journal-title":"Science"},{"key":"ref38\/cit38","doi-asserted-by":"crossref","first-page":"2831","DOI":"10.1039\/DT9910002831","author":"Al-Mukhtar M.","year":"1991","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ref39\/cit39","doi-asserted-by":"crossref","first-page":"974","DOI":"10.1126\/science.140.3570.974.b","volume":"140","author":"Turner J. 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B.","year":"2000","journal-title":"Chem. Health Saf."},{"key":"ref45\/cit45","doi-asserted-by":"crossref","first-page":"4310","DOI":"10.1021\/ic951059n","volume":"35","author":"Casteel W. J.","year":"1996","journal-title":"Inorg. Chem."},{"key":"ref46\/cit46","doi-asserted-by":"crossref","first-page":"386","DOI":"10.1021\/ic00056a009","volume":"32","author":"Mercier H. P. A.","year":"1993","journal-title":"Inorg. Chem."},{"key":"ref47\/cit47","doi-asserted-by":"crossref","unstructured":"Kinkead, S. A.; FitzPatrick, J. R.; Foropoulos, J., Jr.; Kissane, R. J.; Purson, J. D. In  Fluorine Chemistry Toward the 21st Century; Thrasher, J. S., Strauss, S. H., Eds.; ACS Symposium Series 555; American Chemical Society: Washington, DC, 1994; Chapter 3, pp 40\u201355.","DOI":"10.1021\/bk-1994-0555.ch003"},{"key":"ref48\/cit48","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/S0010-8545(02)00202-3","volume":"233","author":"Lehmann J. F.","year":"2002","journal-title":"Coord. Chem. Rev."},{"key":"ref49\/cit49","doi-asserted-by":"crossref","first-page":"1323","DOI":"10.1021\/ic00034a008","volume":"31","author":"Emara A. A. A.","year":"1992","journal-title":"Inorg. Chem."},{"key":"ref50\/cit50","doi-asserted-by":"crossref","first-page":"311","DOI":"10.1021\/ic50084a027","volume":"9","author":"Schack C.","year":"1970","journal-title":"Inorg. Chem."},{"key":"ref51\/cit51","doi-asserted-by":"crossref","first-page":"4244","DOI":"10.1021\/ic000259i","volume":"39","author":"Gerken M.","year":"2000","journal-title":"Inorg. Chem."},{"key":"ref52\/cit52","unstructured":"APEX2, release v2011.6-1; Bruker\nAXS Inc.: Madison, WI, 1995."},{"key":"ref53\/cit53","unstructured":"Sheldrick, G. M. SADABS (Siemens Area Detector Absorption Corrections), version 2.03; Siemens Analytical X-ray Instruments, Inc.: Madison, WI, 1999."},{"key":"ref54\/cit54","unstructured":"Sheldrick, G. M. 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A.","year":"1992","journal-title":"J. Chem. Phys."},{"key":"ref59\/cit59","doi-asserted-by":"crossref","first-page":"11113","DOI":"10.1063\/1.1622924","volume":"119","author":"Peterson K. A.","year":"2003","journal-title":"J. Chem. Phys."},{"key":"ref60\/cit60","doi-asserted-by":"crossref","first-page":"283","DOI":"10.1007\/s00214-005-0681-9","volume":"114","author":"Peterson K. A.","year":"2005","journal-title":"Theor. Chem. Acc."},{"key":"ref61\/cit61","doi-asserted-by":"crossref","first-page":"3297","DOI":"10.1039\/b508541a","volume":"7","author":"Weigend F.","year":"2005","journal-title":"Phys. Chem. Chem. Phys."},{"key":"ref62\/cit62","doi-asserted-by":"crossref","first-page":"735","DOI":"10.1063\/1.449486","volume":"83","author":"Reed A. E.","year":"1985","journal-title":"J. Chem. Phys."},{"key":"ref63\/cit63","doi-asserted-by":"crossref","first-page":"899","DOI":"10.1021\/cr00088a005","volume":"88","author":"Reed A. E.","year":"1998","journal-title":"Chem. Rev."},{"key":"ref64\/cit64","unstructured":"Glendening, E. D.; Reed, A. E.; Carpenter, J. E.; Weinhold, F. NBO Version 3.1; Gaussian Inc.: Pittsburgh, PA, 1990."},{"key":"ref65\/cit65","unstructured":"Glendening, E. D.; Badenhoop, J. K.; Reed, A. E.; Carpenter, J. E.; Bohmann, C. M.; Morales, C. M.; Weinhold, F. NBO Version 5.0; Theoretical Chemistry Institute, University of Wisconsin: Madison, WI, 2001."},{"key":"ref66\/cit66","unstructured":"Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Mennucci, B.; Petersson, G. A.; Nakatsuji, H.; Caricato, M.; Li, X.; Hratchian, H. P.; Izmaylov, A. F.; Bloino, J.; Zheng, G.; Sonnenberg, J. L.; Hada, M.; Ehara, M.; Toyota, K.; Fukuda, R.; Hasegawa, J.; Ishida, M.; Nakajima, T.; Honda, Y.; Kitao, O.; Nakai, H.; Vreven, T.; Montgomery, J. A., Jr.; Peralta, J. E.; Ogliaro, F.; Bearpark, M.; Heyd, J. J.; Brothers, E.; Kudin, K. N.; Staroverov, V. 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