{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T08:16:39Z","timestamp":1788336999733,"version":"build-2803163510"},"reference-count":47,"publisher":"American Chemical Society (ACS)","issue":"36","license":[{"start":{"date-parts":[[2015,7,29]],"date-time":"2015-07-29T00:00:00Z","timestamp":1438128000000},"content-version":"vor","delay-in-days":365,"URL":"https:\/\/pubs.acs.org\/page\/policy\/authorchoice_termsofuse.html"}],"funder":[{"DOI":"10.13039\/100000062","name":"National Institute of Diabetes and Digestive and Kidney Diseases","doi-asserted-by":"publisher","award":["DK068139"],"award-info":[{"award-number":["DK068139"]}],"id":[{"id":"10.13039\/100000062","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000165","name":"Division of Chemistry","doi-asserted-by":"publisher","award":["CHE-0953102"],"award-info":[{"award-number":["CHE-0953102"]}],"id":[{"id":"10.13039\/100000165","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000968","name":"American Heart Association","doi-asserted-by":"publisher","award":["NA"],"award-info":[{"award-number":["NA"]}],"id":[{"id":"10.13039\/100000968","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100002108","name":"Friedreich's Ataxia Research Alliance","doi-asserted-by":"publisher","award":["12PRE11720005"],"award-info":[{"award-number":["12PRE11720005"]}],"id":[{"id":"10.13039\/100002108","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/na","name":"University of Georgia","doi-asserted-by":"publisher","award":["NA"],"award-info":[{"award-number":["NA"]}],"id":[{"id":"10.13039\/na","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2014,9,10]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Research on the one-electron reduced analogue of NO, namely nitroxyl (HNO\/NO\u2013), has revealed distinguishing properties regarding its utility as a therapeutic. However, the fleeting nature of HNO requires the design of donor molecules. Metal nitrosyl (MNO) complexes could serve as potential HNO donors. The synthesis, spectroscopic\/structural characterization, and HNO donor properties of a {CoNO}8 complex in a pyrrole\/imine ligand frame are reported. The {CoNO}8 complex [Co(LN4PhCl)(NO)] (1) does not react with established HNO targets such as FeIII hemes or Ph3P. However, in the presence of stoichiometric H+1 behaves as an HNO donor. Complex 1 readily reacts with [Fe(TPP)Cl] or Ph3P to afford the {FeNO}7 porphyrin or Ph3P\u2550O\/Ph3P\u2550NH, respectively. In the absence of an HNO target, the {Co(NO)2}10 dinitrosyl (3) is the end product. Complex 1 also reacts with O2 to yield the corresponding CoIII-\u03b71-ONO2 (2) nitrato analogue. This report is the first to suggest an HNO donor role for {CoNO}8 with biotargets such as FeIII-porphyrins.<\/jats:p>","DOI":"10.1021\/ja5064444","type":"journal-article","created":{"date-parts":[[2014,7,29]],"date-time":"2014-07-29T17:55:16Z","timestamp":1406656516000},"page":"12560-12563","source":"Crossref","is-referenced-by-count":66,"title":["Proton-Induced Reactivity\nof NO\u2013 from a {CoNO}8 Complex"],"prefix":"10.1021","volume":"136","author":[{"given":"Melody A.","family":"Rhine","sequence":"first","affiliation":[{"name":"The University of Georgia , , , ,","place":["Athens, Georgia, United States, 30602"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andria V.","family":"Rodrigues","sequence":"additional","affiliation":[{"name":"Wayne State University , , , ,","place":["Detroit, Michigan, United States, 48201"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ramona J. Bieber","family":"Urbauer","sequence":"additional","affiliation":[{"name":"The University of Georgia , , , ,","place":["Athens, Georgia, United States, 30602"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jeffrey L.","family":"Urbauer","sequence":"additional","affiliation":[{"name":"The University of Georgia , , , ,","place":["Athens, Georgia, United States, 30602"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Timothy L.","family":"Stemmler","sequence":"additional","affiliation":[{"name":"Wayne State University , , , ,","place":["Detroit, Michigan, United States, 48201"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Todd C.","family":"Harrop","sequence":"additional","affiliation":[{"name":"The University of Georgia , , , ,","place":["Athens, Georgia, United States, 30602"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2014,7,29]]},"reference":[{"key":"2026090203373483200_cit1","doi-asserted-by":"crossref","first-page":"S193","DOI":"10.1038\/sj.bjp.0706458","volume":"147","author":"Moncada","year":"2006","journal-title":"Br. 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Chem."}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/ja5064444","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/136\/36\/12560\/8121118\/ja5064444.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/136\/36\/12560\/8121118\/ja5064444.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T07:37:43Z","timestamp":1788334663000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/jacsat\/article\/136\/36\/12560\/788943\/Proton-Induced-Reactivity-of-NO-from-a-CoNO-8"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2014,7,29]]},"references-count":47,"journal-issue":{"issue":"36","published-online":{"date-parts":[[2014,7,29]]},"published-print":{"date-parts":[[2014,9,10]]}},"URL":"https:\/\/doi.org\/10.1021\/ja5064444","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2014,7,29]]}}}