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Chem."},{"key":"ref35\/cit35","doi-asserted-by":"crossref","first-page":"2171","DOI":"10.1002\/pola.26584","volume":"51","author":"Heine D.","year":"2013","journal-title":"J. Polym. Sci., Polym. Chem."},{"key":"ref36\/cit36","doi-asserted-by":"crossref","first-page":"551","DOI":"10.1007\/s007750000146","volume":"5","author":"Gray H. B.","year":"2000","journal-title":"J. Biol. Inorg. Chem."},{"key":"ref37\/cit37","doi-asserted-by":"crossref","first-page":"7252","DOI":"10.1021\/ja111275t","volume":"133","author":"Yuhas B. D.","year":"2011","journal-title":"J. Am. Chem. Soc."},{"key":"ref38\/cit38","doi-asserted-by":"crossref","first-page":"2330","DOI":"10.1021\/ja311310k","volume":"135","author":"Shim Y.","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"ref39\/cit39","doi-asserted-by":"crossref","first-page":"10353","DOI":"10.1021\/ja303640s","volume":"134","author":"Yuhas B. D.","year":"2012","journal-title":"J. Am. Chem. 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