{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,20]],"date-time":"2026-10-20T00:51:37Z","timestamp":1792457497347,"version":"4.5.0"},"reference-count":76,"publisher":"American Chemical Society (ACS)","issue":"50","funder":[{"DOI":"10.13039\/100000001","name":"National Science Foundation","doi-asserted-by":"publisher","award":["CHE-1352164"],"award-info":[{"award-number":["CHE-1352164"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2014,12,17]]},"DOI":"10.1021\/ja510558d","type":"journal-article","created":{"date-parts":[[2014,11,17]],"date-time":"2014-11-17T22:31:58Z","timestamp":1416263518000},"page":"17634-17644","source":"Crossref","is-referenced-by-count":166,"title":["Reversible Intermolecular E\u2013H Oxidative Addition to a Geometrically Deformed and Structurally Dynamic Phosphorous Triamide"],"prefix":"10.1021","volume":"136","author":[{"given":"Wei","family":"Zhao","sequence":"first","affiliation":[{"name":"Department\rof Chemistry and \u2021X-ray Crystallography Laboratory, Department\rof Biochemistry and Molecular Biology, The Pennsylvania State University, University Park, Pennsylvania 16802, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sean M.","family":"McCarthy","sequence":"additional","affiliation":[{"name":"Department\rof Chemistry and \u2021X-ray Crystallography Laboratory, Department\rof Biochemistry and Molecular Biology, The Pennsylvania State University, University Park, Pennsylvania 16802, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ting Yi","family":"Lai","sequence":"additional","affiliation":[{"name":"Department\rof Chemistry and \u2021X-ray Crystallography Laboratory, Department\rof Biochemistry and Molecular Biology, The Pennsylvania State University, University Park, Pennsylvania 16802, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hemant P.","family":"Yennawar","sequence":"additional","affiliation":[{"name":"Department\rof Chemistry and \u2021X-ray Crystallography Laboratory, Department\rof Biochemistry and Molecular Biology, The Pennsylvania State University, University Park, Pennsylvania 16802, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexander T.","family":"Radosevich","sequence":"additional","affiliation":[{"name":"Department\rof Chemistry and \u2021X-ray Crystallography Laboratory, Department\rof Biochemistry and Molecular Biology, The Pennsylvania State University, University Park, Pennsylvania 16802, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2014,12,3]]},"reference":[{"key":"ref1\/cit1","volume-title":"Structure and Mechanism in Organophosphorus Chemistry","author":"Hudson R. F.","year":"1965"},{"key":"ref2\/cit2","doi-asserted-by":"crossref","first-page":"1339","DOI":"10.1021\/cr00029a008","volume":"94","author":"Gilheany D. G.","year":"1994","journal-title":"Chem. Rev."},{"key":"ref3\/cit3","volume-title":"Organophosphorus Reagents in Organic Synthesis","author":"Cadogan J. I. G.","year":"1980"},{"key":"ref4\/cit4","doi-asserted-by":"crossref","DOI":"10.1002\/9781118299715","volume-title":"Phosphorus(III) Ligands in Homogeneous Catalysis: Design and Synthesis","author":"Kamer P. C. J.","year":"2012"},{"key":"ref5\/cit5a","doi-asserted-by":"crossref","first-page":"1035","DOI":"10.1002\/adsc.200404087","volume":"346","author":"Methot J. L.","year":"2004","journal-title":"Adv. Synth. Catal."},{"key":"ref5\/cit5b","doi-asserted-by":"crossref","first-page":"11588","DOI":"10.1039\/c3cc47368f","volume":"49","author":"Fan Y. C.","year":"2013","journal-title":"Chem. Commun."},{"key":"ref6\/cit6a","unstructured":"aBurdett, J. K.Molecular Shapes;Wiley-Interscience:New York, 1980; pp54\u201358."},{"key":"ref6\/cit6b","doi-asserted-by":"crossref","first-page":"25","DOI":"10.1016\/0166-1280(83)85006-4","volume":"103","author":"Pearson R. G.","year":"1983","journal-title":"J. Mol. Struct.: THEOCHEM"},{"key":"ref7\/cit7","volume-title":"Orbital Interactions in Chemistry","author":"Albright T. A.","year":"1985"},{"key":"ref8\/cit8a","doi-asserted-by":"crossref","first-page":"3090","DOI":"10.1021\/ja00713a028","volume":"92","author":"Baechler R. D.","year":"1970","journal-title":"J. Am. Chem. Soc."},{"key":"ref8\/cit8b","doi-asserted-by":"crossref","first-page":"4758","DOI":"10.1021\/ja00718a061","volume":"92","author":"Baechler R. D.","year":"1970","journal-title":"J. Am. Chem. Soc."},{"key":"ref8\/cit8c","doi-asserted-by":"crossref","first-page":"773","DOI":"10.1021\/ja00732a036","volume":"93","author":"Mislow K.","year":"1971","journal-title":"J. Am. Chem. Soc."},{"key":"ref8\/cit8d","doi-asserted-by":"crossref","first-page":"1805","DOI":"10.1021\/ja00736a053","volume":"93","author":"Mislow K.","year":"1971","journal-title":"J. Am. Chem. Soc."},{"key":"ref9\/cit9a","doi-asserted-by":"crossref","first-page":"2264","DOI":"10.1002\/1521-3749(200011)626:11<2264::AID-ZAAC2264>3.0.CO;2-F","volume":"626","author":"Driess M.","year":"2000","journal-title":"Z. Anorg. Allg. Chem."},{"key":"ref9\/cit9b","doi-asserted-by":"crossref","first-page":"43","DOI":"10.1007\/b100981","volume":"250","author":"Marque S.","year":"2005","journal-title":"Top. Curr. Chem."},{"key":"ref9\/cit9c","doi-asserted-by":"crossref","first-page":"3414","DOI":"10.1021\/ja4012113","volume":"135","author":"Pan X.","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"ref10\/cit10a","unstructured":"a."},{"key":"ref10\/cit10b","doi-asserted-by":"crossref","first-page":"9293","DOI":"10.1021\/ja970369x","volume":"119","author":"Vedejs E.","year":"1997","journal-title":"J. Am. Chem. Soc."},{"key":"ref10\/cit10c","doi-asserted-by":"crossref","first-page":"5116","DOI":"10.1021\/ja973685k","volume":"120","author":"Wolfe B.","year":"1998","journal-title":"J. Am. Chem. Soc."},{"key":"ref10\/cit10d","doi-asserted-by":"crossref","first-page":"9354","DOI":"10.1021\/ja404943x","volume":"135","author":"Reichl K. D.","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"ref11\/cit11","doi-asserted-by":"crossref","first-page":"1164","DOI":"10.1021\/ja00316a084","volume":"106","author":"Culley S. A.","year":"1984","journal-title":"J. Am. Chem. Soc."},{"key":"ref12\/cit12","doi-asserted-by":"crossref","first-page":"1215","DOI":"10.1021\/cr00029a003","volume":"94","author":"Arduengo A. J.","year":"1994","journal-title":"Chem. Rev."},{"key":"ref13\/cit13","doi-asserted-by":"crossref","first-page":"1247","DOI":"10.1021\/cr990358h","volume":"101","author":"Minkin V. I.","year":"2001","journal-title":"Chem. Rev."},{"key":"ref14\/cit14","unstructured":"Arduengo, A. J.; Dixon, D. A.InHeteroatom Chemistry;Block, E., Ed.VCH:New York, 1990; p47."},{"key":"ref15\/cit15a","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1038\/nature08634","volume":"463","author":"Power P. P.","year":"2010","journal-title":"Nature"},{"key":"ref15\/cit15b","doi-asserted-by":"crossref","first-page":"389","DOI":"10.1039\/C0SC00388C","volume":"2","author":"Martin D.","year":"2011","journal-title":"Chem. Sci."},{"key":"ref15\/cit15c","doi-asserted-by":"crossref","first-page":"46","DOI":"10.1002\/anie.200903708","volume":"49","author":"Stephan D. W.","year":"2010","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref16\/cit16","doi-asserted-by":"crossref","first-page":"11330","DOI":"10.1021\/ja302963p","volume":"134","author":"Dunn N. L.","year":"2012","journal-title":"J. Am. Chem. Soc."},{"key":"ref17\/cit17","doi-asserted-by":"crossref","first-page":"4640","DOI":"10.1021\/ja412469e","volume":"136","author":"McCarthy S. M.","year":"2014","journal-title":"J. Am. Chem. Soc."},{"key":"ref18\/cit18","doi-asserted-by":"crossref","first-page":"210","DOI":"10.1039\/b306615k","volume":"33","author":"Bouhadir G.","year":"2004","journal-title":"Chem. Soc. Rev."},{"key":"ref19\/cit19","doi-asserted-by":"crossref","first-page":"12673","DOI":"10.1021\/ja9621861","volume":"118","author":"Mitzel N. W.","year":"1996","journal-title":"J. Am. Chem. Soc."},{"key":"ref20\/cit20","doi-asserted-by":"crossref","first-page":"6506","DOI":"10.1021\/ja00800a087","volume":"95","author":"Cowley A. H.","year":"1973","journal-title":"J. Am. Chem. Soc."},{"key":"ref21\/cit21","volume-title":"Encyclopedia of Reagents for Organic Synthesis","author":"Harvey R. G.","year":"2001"},{"key":"ref22\/cit22","doi-asserted-by":"crossref","first-page":"7084","DOI":"10.1021\/ja200270k","volume":"133","author":"Ren P.","year":"2011","journal-title":"J. Am. Chem. Soc."},{"key":"ref23\/cit23","doi-asserted-by":"crossref","first-page":"3307","DOI":"10.1021\/ja808542j","volume":"131","author":"Nguyen A. I.","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"ref24\/cit24","unstructured":"NBO 6.0:Glendening, E. D.; Badenhoop, J. K.; Reed, A. E.; Carpenter, J. E.; Bohmann, J. A.; Morales, C. M.; Landis, C. R.; Weinhold, F., Theoretical Chemistry Institute, University of Wisconsin, Madison, WI, 2013."},{"key":"ref26\/cit26","doi-asserted-by":"crossref","first-page":"51","DOI":"10.1039\/dt9820000051","author":"Allen D. W.","year":"1982","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ref27\/cit27","doi-asserted-by":"crossref","first-page":"1025","DOI":"10.1002\/(SICI)1521-3749(199906)625:6<1025::AID-ZAAC1025>3.0.CO;2-V","volume":"625","author":"Vogt H.","year":"1999","journal-title":"Z. Anorg. Allg. Chem."},{"key":"ref28\/cit28","doi-asserted-by":"crossref","first-page":"469","DOI":"10.1021\/ic50192a059","volume":"18","author":"Kroshefsky R. D.","year":"1979","journal-title":"Inorg. Chem."},{"key":"ref29\/cit29","doi-asserted-by":"crossref","first-page":"187","DOI":"10.3891\/acta.chem.scand.33a-0187","volume":"33","author":"R\u00f8mming C.","year":"1979","journal-title":"Acta Chem. Scand."},{"key":"ref30\/cit30a","doi-asserted-by":"crossref","first-page":"2461","DOI":"10.1021\/ja00269a063","volume":"108","author":"Dixon D. A.","year":"1986","journal-title":"J. Am. Chem. Soc."},{"key":"ref30\/cit30b","doi-asserted-by":"crossref","first-page":"6821","DOI":"10.1021\/ja00281a070","volume":"108","author":"Arduengo A. J.","year":"1986","journal-title":"J. Am. Chem. Soc."},{"key":"ref30\/cit30c","doi-asserted-by":"crossref","first-page":"498","DOI":"10.1039\/c39870000498","author":"Dixon D. A.","year":"1987","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"ref31\/cit31","doi-asserted-by":"crossref","first-page":"361","DOI":"10.1070\/RC1983v052n04ABEH002823","volume":"52","author":"Pudovik M. A.","year":"1983","journal-title":"Russ. Chem. Rev."},{"key":"ref32\/cit32","doi-asserted-by":"crossref","first-page":"1349","DOI":"10.1039\/DT9840001349","author":"Addison A. W.","year":"1984","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ref33\/cit33","volume-title":"Phosphorus-31 NMR Spectroscopy: A Concise Introduction for the Synthetic Organic and Organometallic Chemist","author":"K\u00fchl O.","year":"2008"},{"key":"ref34\/cit34a","doi-asserted-by":"crossref","first-page":"1141","DOI":"10.1351\/pac198052041141","volume":"52","author":"Wolf R.","year":"1980","journal-title":"Pure Appl. Chem."},{"key":"ref34\/cit34b","unstructured":"bBurgada, R.; Setton, R.InThe Chemistry of Organophosphorus Compounds;Hartley, F., Ed.Wiley:Chichester, U.K., 1994; Vol.3, p185."},{"key":"ref35\/cit35","volume-title":"Chemistry of Hypervalent Compounds","author":"Akiba K.","year":"1998"},{"key":"ref36\/cit36","doi-asserted-by":"crossref","first-page":"62","DOI":"10.1016\/j.ica.2010.11.022","volume":"369","author":"Mukhlall J. A.","year":"2011","journal-title":"Inorg. Chim. Acta"},{"key":"ref37\/cit37","doi-asserted-by":"crossref","first-page":"1053","DOI":"10.1351\/pac198759081053","volume":"59","author":"Arduengo A. J.","year":"1987","journal-title":"Pure Appl. Chem."},{"key":"ref38\/cit38","doi-asserted-by":"crossref","first-page":"18127","DOI":"10.1021\/ja105306s","volume":"132","author":"Couzijn E. P. A.","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"ref39\/cit39a","doi-asserted-by":"crossref","first-page":"1434","DOI":"10.1021\/ja00160a022","volume":"112","author":"Reed A. E.","year":"1990","journal-title":"J. Am. Chem. Soc."},{"key":"ref39\/cit39b","doi-asserted-by":"crossref","first-page":"13154","DOI":"10.1021\/ja026776c","volume":"124","author":"Matsukawa S.","year":"2002","journal-title":"J. Am. Chem. Soc."},{"key":"ref40\/cit40","unstructured":"Weinhold, F.; Landis, C. R.Valency and Bonding: A Natural Bond Orbital Donor-Acceptor Perspective;Cambridge University Press:Cambridge, U.K., New York, 2005; pp275\u2013305."},{"key":"ref41\/cit41","doi-asserted-by":"crossref","first-page":"3318","DOI":"10.1021\/ja00452a021","volume":"99","author":"Holmes R. R.","year":"1977","journal-title":"J. Am. Chem. Soc."},{"key":"ref42\/cit42","doi-asserted-by":"crossref","first-page":"21","DOI":"10.1016\/S0010-8545(02)00294-1","volume":"238","author":"Comba P.","year":"2003","journal-title":"Coord. Chem. Rev."},{"key":"ref43\/cit43a","doi-asserted-by":"crossref","first-page":"87","DOI":"10.1080\/10426509008038016","volume":"53","author":"Murillo A.","year":"1990","journal-title":"Phosphorus, Sulfur Silicon Relat. Elem."},{"key":"ref43\/cit43b","doi-asserted-by":"crossref","first-page":"189","DOI":"10.1080\/10426509408021945","volume":"91","author":"Camacho-Camacho C.","year":"1994","journal-title":"Phosphorus, Sulfur Silicon Relat. Elem."},{"key":"ref44\/cit44","doi-asserted-by":"crossref","first-page":"2657","DOI":"10.1021\/ic00090a030","volume":"33","author":"Khasnis D. V.","year":"1994","journal-title":"Inorg. Chem."},{"key":"ref45\/cit45","doi-asserted-by":"crossref","first-page":"1234","DOI":"10.1021\/ja00395a049","volume":"103","author":"Ross M. R.","year":"1981","journal-title":"J. Am. Chem. Soc."},{"key":"ref46\/cit46","doi-asserted-by":"crossref","first-page":"6607","DOI":"10.1021\/ja00462a023","volume":"99","author":"Milbrath D. S.","year":"1977","journal-title":"J. Am. Chem. Soc."},{"key":"ref47\/cit47a","doi-asserted-by":"crossref","first-page":"3387","DOI":"10.1021\/ja0056264","volume":"123","author":"Kobayashi J.","year":"2001","journal-title":"J. Am. Chem. Soc."},{"key":"ref47\/cit47b","doi-asserted-by":"crossref","first-page":"1249","DOI":"10.1016\/j.crci.2010.06.010","volume":"13","author":"Kobayashi J.","year":"2010","journal-title":"C. R. Chim."},{"key":"ref48\/cit48","doi-asserted-by":"crossref","first-page":"9988","DOI":"10.1021\/ja4032874","volume":"135","author":"Myers T. W.","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"ref49\/cit49a","doi-asserted-by":"crossref","first-page":"798","DOI":"10.1021\/ic801964u","volume":"48","author":"Jana A.","year":"2009","journal-title":"Inorg. Chem."},{"key":"ref49\/cit49b","doi-asserted-by":"crossref","first-page":"3038","DOI":"10.1021\/ja910305p","volume":"132","author":"Meltzer A.","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"ref49\/cit49c","doi-asserted-by":"crossref","first-page":"6490","DOI":"10.1021\/om200970s","volume":"30","author":"Wang W.","year":"2011","journal-title":"Organometallics"},{"key":"ref50\/cit50a","doi-asserted-by":"crossref","first-page":"3755","DOI":"10.1021\/cr9601371","volume":"100","author":"Nifantiev E. E.","year":"2000","journal-title":"Chem. Rev."},{"key":"ref50\/cit50b","first-page":"842","volume":"183","author":"Pudovik A. N.","year":"1968","journal-title":"Dokl. Akad. Nauk SSSR"},{"key":"ref51\/cit51","doi-asserted-by":"crossref","first-page":"204","DOI":"10.1021\/ar50054a003","volume":"5","author":"Hudson R. F.","year":"1972","journal-title":"Acc. Chem. Res."},{"key":"ref52\/cit52","doi-asserted-by":"crossref","first-page":"18798","DOI":"10.1021\/ja411467p","volume":"135","author":"Moerdyk J. P.","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"ref53\/cit53","first-page":"2","volume":"3","author":"Reich H. J.","year":"1996","journal-title":"J. Chem. Educ.: Software"},{"key":"ref54\/cit54","volume-title":"Gaussian 09","author":"Frisch M. J.","year":"2009"},{"key":"ref55\/cit55a","doi-asserted-by":"crossref","first-page":"215","DOI":"10.1007\/s00214-007-0310-x","volume":"120","author":"Zhao Y.","year":"2008","journal-title":"Theor. Chem. Acc."},{"key":"ref55\/cit55b","doi-asserted-by":"crossref","first-page":"157","DOI":"10.1021\/ar700111a","volume":"41","author":"Zhao Y.","year":"2008","journal-title":"Acc. Chem. Res."}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/ja510558d","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,4,4]],"date-time":"2023-04-04T06:22:26Z","timestamp":1680589346000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/ja510558d"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2014,12,3]]},"references-count":76,"journal-issue":{"issue":"50","published-print":{"date-parts":[[2014,12,17]]}},"alternative-id":["10.1021\/ja510558d"],"URL":"https:\/\/doi.org\/10.1021\/ja510558d","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2014,12,3]]}}}