{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,20]],"date-time":"2026-09-20T11:11:30Z","timestamp":1789902690252,"version":"4.0.1"},"reference-count":59,"publisher":"American Chemical Society (ACS)","issue":"50","license":[{"start":{"date-parts":[[2015,12,3]],"date-time":"2015-12-03T00:00:00Z","timestamp":1449100800000},"content-version":"vor","delay-in-days":365,"URL":"https:\/\/pubs.acs.org\/page\/policy\/authorchoice_termsofuse.html"}],"funder":[{"DOI":"10.13039\/100000181","name":"Air Force Office of Scientific Research","doi-asserted-by":"publisher","award":["FA9550-11-1-0008"],"award-info":[{"award-number":["FA9550-11-1-0008"]}],"id":[{"id":"10.13039\/100000181","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2014,12,17]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>We report the synthesis and comprehensive study of the electronic structure of a unique series of dinuclear group 5 cyclo-tetraphosphide inverted sandwich complexes. White phosphorus (P4) reacts with niobium(III) and tantalum(III) \u03b2-diketiminate (BDI) tert-butylimido complexes to produce the bridging cyclo-P4 phosphide species {[(BDI)(NtBu)M]2(\u03bc-\u03b73:\u03b73P4)} (1, M = Nb; 2, M = Ta) in fair yields. 1 is alternatively synthesized upon hydrogenolysis of (BDI)Nb(NtBu)Me2 in the presence of P4. The trinuclear side product {[(BDI)NbNtBu]3(\u03bc-P12)} (3) is also identified. Protonation of 1 with [HOEt2][B(C6F5)4] does not occur at the phosphide ring but rather involves the BDI ligand to yield {[(BDI#)Nb(NtBu)]2(\u03bc-\u03b73:\u03b73P4)}[B(C6F5)4]2 (4). The monocation and dication analogues {[(BDI)(NtBu)Nb]2(\u03bc-\u03b73:\u03b73P4)}{B(ArF)4}n (5, n = 1; 6, n = 2) are both synthesized by oxidation of 1 with AgBArF. DFT calculations were used in combination with EPR and UV\u2013visible spectroscopies to probe the nature of the metal\u2013phosphorus bonding.<\/jats:p>","DOI":"10.1021\/ja5107282","type":"journal-article","created":{"date-parts":[[2014,12,3]],"date-time":"2014-12-03T11:15:52Z","timestamp":1417605352000},"page":"17652-17661","source":"Crossref","is-referenced-by-count":58,"title":["Activation\nof White Phosphorus by Low-Valent Group\n5 Complexes: Formation and Reactivity of\n                    <i>cyclo<\/i>\n                    -P4 Inverted Sandwich Compounds"],"prefix":"10.1021","volume":"136","author":[{"given":"Cle\u0301ment","family":"Camp","sequence":"first","affiliation":[{"name":"University of California , , , ,","place":["Berkeley, California, United States, 94720"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Laurent","family":"Maron","sequence":"additional","affiliation":[{"name":"Universite\u0301 de Toulouse , , 135 Avenue de Rangueil , ,","place":["Toulouse, France, 31077"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Robert G.","family":"Bergman","sequence":"additional","affiliation":[{"name":"University of California , , , ,","place":["Berkeley, California, United States, 94720"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"John","family":"Arnold","sequence":"additional","affiliation":[{"name":"University of California , , , ,","place":["Berkeley, California, United States, 94720"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2014,12,3]]},"reference":[{"key":"2026090114191391800_cit1","doi-asserted-by":"crossref","first-page":"11629","DOI":"10.1002\/anie.201404147","volume":"53","author":"Bachhuber","year":"2014","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026090114191391800_cit2","volume-title":"Advanced Inorganic Chemistry","author":"Cotton","year":"1999","edition":"6"},{"key":"2026090114191391800_cit3","doi-asserted-by":"crossref","first-page":"4236","DOI":"10.1021\/cr100010e","volume":"110","author":"Scheer","year":"2010","journal-title":"Chem. Rev."},{"key":"2026090114191391800_cit4","doi-asserted-by":"crossref","first-page":"4164","DOI":"10.1021\/cr9003709","volume":"110","author":"Cossairt","year":"2010","journal-title":"Chem. Rev."},{"key":"2026090114191391800_cit5","doi-asserted-by":"crossref","first-page":"832","DOI":"10.1126\/science.1067325","volume":"295","author":"Urnius","year":"2002","journal-title":"Science"},{"key":"2026090114191391800_cit6","doi-asserted-by":"crossref","first-page":"2042","DOI":"10.1002\/anie.199520421","volume":"34","author":"Laplaza","year":"1995","journal-title":"Angew. Chem., Int. Ed.\nEngl."},{"key":"2026090114191391800_cit7","doi-asserted-by":"crossref","first-page":"602","DOI":"10.1126\/science.1168260","volume":"323","author":"Cossairt","year":"2009","journal-title":"Science"},{"key":"2026090114191391800_cit8","doi-asserted-by":"crossref","first-page":"115","DOI":"10.1002\/anie.200803739","volume":"48","author":"Seidel","year":"2009","journal-title":"Angew. Chem.,\nInt. Ed."},{"key":"2026090114191391800_cit9","doi-asserted-by":"crossref","first-page":"3443","DOI":"10.1002\/anie.200353406","volume":"43","author":"Peng","year":"2004","journal-title":"Angew. Chem.,\nInt. Ed."},{"key":"2026090114191391800_cit10","doi-asserted-by":"crossref","first-page":"7283","DOI":"10.1002\/anie.201102361","volume":"50","author":"Schwarzmaier","year":"2011","journal-title":"Angew. Chem., Int.\nEd."},{"key":"2026090114191391800_cit11","doi-asserted-by":"crossref","first-page":"3221","DOI":"10.1039\/C4SC01213E","volume":"5","author":"Heinl","year":"2014","journal-title":"Chem. Sci."},{"key":"2026090114191391800_cit12","first-page":"12064","volume":"16","author":"Demange","year":"2010","journal-title":"Chem.\u2500Eur.\nJ."},{"key":"2026090114191391800_cit13","doi-asserted-by":"crossref","first-page":"3904","DOI":"10.1021\/ic300219w","volume":"51","author":"Du\u0308rr","year":"2012","journal-title":"Inorg. Chem."},{"key":"2026090114191391800_cit14","doi-asserted-by":"crossref","first-page":"7014","DOI":"10.1039\/C4CC02601B","volume":"50","author":"Pelties","year":"2014","journal-title":"Chem.\nCommun."},{"key":"2026090114191391800_cit15","doi-asserted-by":"crossref","first-page":"1652","DOI":"10.1002\/ejic.201400046","volume":"2014","author":"Caporali","year":"2014","journal-title":"Eur. J. Inorg. Chem."},{"key":"2026090114191391800_cit16","doi-asserted-by":"crossref","first-page":"5740","DOI":"10.1021\/ja901045m","volume":"131","author":"Konchenko","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"2026090114191391800_cit17","doi-asserted-by":"crossref","first-page":"9871","DOI":"10.1002\/anie.201005029","volume":"49","author":"Tran","year":"2010","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026090114191391800_cit18","doi-asserted-by":"crossref","first-page":"4178","DOI":"10.1021\/cr900349u","volume":"110","author":"Caporali","year":"2010","journal-title":"Chem. Rev."},{"key":"2026090114191391800_cit19","doi-asserted-by":"crossref","first-page":"1038","DOI":"10.1039\/b510917e","volume":"34","author":"Peruzzini","year":"2005","journal-title":"Chem. Soc. Rev."},{"key":"2026090114191391800_cit20","doi-asserted-by":"crossref","first-page":"42","DOI":"10.1039\/C3CS60163C","volume":"43","author":"Li","year":"2014","journal-title":"Chem. Soc. Rev."},{"key":"2026090114191391800_cit21","doi-asserted-by":"crossref","first-page":"1276","DOI":"10.1126\/science.1129630","volume":"313","author":"Piro","year":"2006","journal-title":"Science"},{"key":"2026090114191391800_cit22","doi-asserted-by":"crossref","first-page":"1595","DOI":"10.1002\/anie.200906633","volume":"49","author":"Cossairt","year":"2010","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026090114191391800_cit23","doi-asserted-by":"crossref","first-page":"13916","DOI":"10.1021\/ja0461522","volume":"126","author":"Figueroa","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"2026090114191391800_cit24","doi-asserted-by":"crossref","first-page":"7639","DOI":"10.1002\/anie.201403295","volume":"53","author":"Heinl","year":"2014","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026090114191391800_cit25","doi-asserted-by":"crossref","first-page":"7643","DOI":"10.1002\/anie.201403581","volume":"53","author":"Ma\u0308dl","year":"2014","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026090114191391800_cit26","doi-asserted-by":"crossref","first-page":"3177","DOI":"10.1002\/asia.201300885","volume":"8","author":"Mirabello","year":"2013","journal-title":"Chem.\u2500Asian J."},{"key":"2026090114191391800_cit27","doi-asserted-by":"crossref","first-page":"4425","DOI":"10.1002\/anie.200800723","volume":"47","author":"Barbaro","year":"2008","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026090114191391800_cit28","doi-asserted-by":"crossref","first-page":"8628","DOI":"10.1002\/anie.201203908","volume":"51","author":"Barbaro","year":"2012","journal-title":"Angew. Chem., Int.\nEd."},{"key":"2026090114191391800_cit29","doi-asserted-by":"crossref","first-page":"969","DOI":"10.1002\/anie.199109691","volume":"103","author":"Scheer","year":"1991","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"2026090114191391800_cit30","doi-asserted-by":"crossref","first-page":"1355","DOI":"10.1002\/anie.198913551","volume":"28","author":"Scherer","year":"1989","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"2026090114191391800_cit31","doi-asserted-by":"crossref","first-page":"1377","DOI":"10.1002\/anie.199213771","volume":"31","author":"Scheer","year":"1992","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"2026090114191391800_cit32","doi-asserted-by":"crossref","first-page":"2022","DOI":"10.1039\/c1nj20163h","volume":"35","author":"Frey","year":"2011","journal-title":"New J. Chem."},{"key":"2026090114191391800_cit33","unstructured":"Stephens, F. H.\n          \n          Activation\nof White Phosphorus by Molybdenum and Uranium tris-Amides. Ph.D. Thesis, Massachussets Institute of Technology, 2004."},{"key":"2026090114191391800_cit34","doi-asserted-by":"crossref","first-page":"1117","DOI":"10.1021\/ic0514445","volume":"45","author":"Kraus","year":"2006","journal-title":"Inorg. Chem."},{"key":"2026090114191391800_cit35","doi-asserted-by":"crossref","first-page":"4030","DOI":"10.1002\/anie.200351776","volume":"42","author":"Kraus","year":"2003","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026090114191391800_cit36","doi-asserted-by":"crossref","first-page":"1003","DOI":"10.1039\/c2sc00931e","volume":"3","author":"Velian","year":"2012","journal-title":"Chem. Sci."},{"key":"2026090114191391800_cit37","doi-asserted-by":"crossref","first-page":"5296","DOI":"10.1021\/ic025759l","volume":"41","author":"Smith","year":"2002","journal-title":"Inorg. Chem."},{"key":"2026090114191391800_cit38","doi-asserted-by":"crossref","first-page":"544","DOI":"10.1002\/anie.198205442","volume":"21","author":"Niecke","year":"1982","journal-title":"Angew.\nChem., Int. Ed. Engl."},{"key":"2026090114191391800_cit39","doi-asserted-by":"crossref","first-page":"7815","DOI":"10.1021\/cr400547x","volume":"114","author":"He","year":"2014","journal-title":"Chem. Rev."},{"key":"2026090114191391800_cit40","doi-asserted-by":"crossref","first-page":"5010","DOI":"10.1021\/om1002528","volume":"29","author":"Tomson","year":"2010","journal-title":"Organometallics"},{"key":"2026090114191391800_cit41","doi-asserted-by":"crossref","first-page":"10046","DOI":"10.1039\/c4dt00923a","volume":"43","author":"Kriegel","year":"2014","journal-title":"Dalton Trans."},{"key":"2026090114191391800_cit42","doi-asserted-by":"crossref","first-page":"14904","DOI":"10.1021\/ja206016s","volume":"133","author":"Gianetti","year":"2011","journal-title":"J. Am. Chem. Soc."},{"key":"2026090114191391800_cit43","doi-asserted-by":"crossref","first-page":"2517","DOI":"10.1039\/c4sc00006d","volume":"5","author":"Gianetti","year":"2014","journal-title":"Chem. Sci."},{"key":"2026090114191391800_cit44","doi-asserted-by":"crossref","first-page":"8145","DOI":"10.1021\/ja4033007","volume":"135","author":"Gianetti","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"2026090114191391800_cit45","doi-asserted-by":"crossref","first-page":"3224","DOI":"10.1021\/ja311966h","volume":"135","author":"Gianetti","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"2026090114191391800_cit46","doi-asserted-by":"crossref","first-page":"2994","DOI":"10.1021\/ja413194z","volume":"136","author":"Obenhuber","year":"2014","journal-title":"J. Am. Chem. Soc."},{"key":"2026090114191391800_cit47","doi-asserted-by":"crossref","first-page":"2926","DOI":"10.1021\/om1001827","volume":"29","author":"Tomson","year":"2010","journal-title":"Organometallics"},{"key":"2026090114191391800_cit48","doi-asserted-by":"crossref","first-page":"817","DOI":"10.1002\/anie.198408171","volume":"23","author":"Ho\u0308nle","year":"1984","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"2026090114191391800_cit49","doi-asserted-by":"crossref","first-page":"13334","DOI":"10.1002\/anie.201306492","volume":"52","author":"Patel","year":"2013","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026090114191391800_cit50","doi-asserted-by":"crossref","first-page":"2216","DOI":"10.1039\/c2cc17638f","volume":"48","author":"Huang","year":"2012","journal-title":"Chem. Commun."},{"key":"2026090114191391800_cit51","doi-asserted-by":"crossref","first-page":"3630","DOI":"10.1002\/anie.201001630","volume":"50","author":"Scharfe","year":"2011","journal-title":"Angew. Chem.,\nInt. Ed."},{"key":"2026090114191391800_cit52","doi-asserted-by":"crossref","first-page":"258","DOI":"10.1002\/zaac.19956210215","volume":"621","author":"Bo\u0308cker","year":"1995","journal-title":"Z. Anorg. Allg. Chem."},{"key":"2026090114191391800_cit53","doi-asserted-by":"crossref","first-page":"243","DOI":"10.1021\/cr00083a012","volume":"88","author":"Von Schnering","year":"1988","journal-title":"Chem. Rev."},{"key":"2026090114191391800_cit54","doi-asserted-by":"crossref","first-page":"33","DOI":"10.1002\/anie.198100331","volume":"20","author":"Von Schnering","year":"1981","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"2026090114191391800_cit55","doi-asserted-by":"crossref","first-page":"14180","DOI":"10.1021\/ja077296u","volume":"129","author":"Masuda","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"2026090114191391800_cit56","doi-asserted-by":"crossref","first-page":"53","DOI":"10.1002\/cber.19961290112","volume":"129","author":"Scherer","year":"1996","journal-title":"Chem. Ber."},{"key":"2026090114191391800_cit57","doi-asserted-by":"publisher","DOI":"10.1039\/C4SC02705A","author":"Gianetti","year":"2014","journal-title":"Chem. Sci."},{"key":"2026090114191391800_cit58","unstructured":"Camp, C.; Arnold, J. Manuscript submitted."},{"key":"2026090114191391800_cit59","doi-asserted-by":"crossref","first-page":"105","DOI":"10.1006\/jmrb.1994.1062","volume":"104","author":"Duling","year":"1994","journal-title":"J. Magn. Reson.\nSer. B"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/ja5107282","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/136\/50\/17652\/8124626\/ja5107282.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/136\/50\/17652\/8124626\/ja5107282.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,1]],"date-time":"2026-09-01T18:19:32Z","timestamp":1788286772000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/jacsat\/article\/136\/50\/17652\/789229\/Activation-of-White-Phosphorus-by-Low-Valent-Group"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2014,12,3]]},"references-count":59,"journal-issue":{"issue":"50","published-online":{"date-parts":[[2014,12,3]]},"published-print":{"date-parts":[[2014,12,17]]}},"URL":"https:\/\/doi.org\/10.1021\/ja5107282","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2014,12,3]]}}}