{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,3]],"date-time":"2026-08-03T19:56:06Z","timestamp":1785786966688,"version":"3.56.0"},"reference-count":161,"publisher":"American Chemical Society (ACS)","issue":"20","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2008,5,1]]},"DOI":"10.1021\/ja710669w","type":"journal-article","created":{"date-parts":[[2008,4,30]],"date-time":"2008-04-30T06:00:44Z","timestamp":1209535244000},"page":"6624-6638","source":"Crossref","is-referenced-by-count":190,"title":["The Reactivity Patterns of Low-Coordinate Iron\u2212Hydride Complexes"],"prefix":"10.1021","volume":"130","author":[{"given":"Ying","family":"Yu","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Azwana R.","family":"Sadique","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jeremy M.","family":"Smith","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Thomas R.","family":"Dugan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ryan E.","family":"Cowley","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Rochester, Rochester, New York, 14627, Max-Planck-Institut f\u00fcr Bioanorganische Chemie, D-45470 M\u00fclheim an der Ruhr, Germany, Department of Chemistry and Center for Advanced Scientific Computing and Modeling (CASCaM), University of North Texas, Denton, Texas, 76203"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"William W.","family":"Brennessel","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christine J.","family":"Flaschenriem","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eckhard","family":"Bill","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Thomas R.","family":"Cundari","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Patrick L.","family":"Holland","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2008,4,30]]},"reference":[{"key":"ref1\/cit1a","volume-title":"Recent Advances in Hydride Chemistry","author":"Peruzzini M.","year":"2001"},{"key":"ref1\/cit1b","doi-asserted-by":"crossref","first-page":"383","DOI":"10.1039\/b207999m","volume":"32","author":"McGrady G. S.","year":"2003","journal-title":"Chem. Soc. Rev."},{"key":"ref2\/cit2a","doi-asserted-by":"crossref","first-page":"452","DOI":"10.1007\/s007750100224","volume":"6","author":": Maroney M. J.","year":"2001","journal-title":"J. Biol. Inorg. Chem."},{"key":"ref2\/cit2b","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/S0162-0134(02)00392-6","volume":"91","author":"Nicolet Y.","year":"2002","journal-title":"J. Inorg. Biochem."},{"key":"ref2\/cit2c","doi-asserted-by":"crossref","first-page":"133","DOI":"10.1016\/j.cbpa.2004.02.004","volume":"8","author":"Armstrong F. A.","year":"2004","journal-title":"Curr. Opin. Chem. Biol."},{"key":"ref2\/cit2d","doi-asserted-by":"crossref","first-page":"1641","DOI":"10.1016\/j.ccr.2005.04.009","volume":"249","author":"Liu X.","year":"2005","journal-title":"Coord. Chem. Rev."},{"key":"ref3\/cit3a","doi-asserted-by":"crossref","first-page":"2965","DOI":"10.1021\/cr9500545","volume":"96","author":"Howard J. B.","year":"1996","journal-title":"Chem. Rev."},{"key":"ref3\/cit3b","doi-asserted-by":"crossref","first-page":"2983","DOI":"10.1021\/cr950055x","volume":"96","author":"Burgess B. K.","year":"1996","journal-title":"Chem. Rev."},{"key":"ref3\/cit3c","doi-asserted-by":"crossref","first-page":"3013","DOI":"10.1021\/cr950057h","volume":"96","author":"Eady R. R.","year":"1996","journal-title":"Chem. Rev."},{"key":"ref3\/cit3d","unstructured":"dHolland, P. L.Nitrogen Fixation. InComprehensive Coordination Chemistry II;McCleverty, J. and Meyer, T. J., Eds.; Elsevier:Oxford, U.K. 2004; Vol.8, pp569\u2212599."},{"key":"ref4\/cit4a","doi-asserted-by":"crossref","first-page":"557","DOI":"10.1038\/272557a0","volume":"272","author":"Thorneley R. N. F.","year":"1978","journal-title":"Nature"},{"key":"ref4\/cit4b","doi-asserted-by":"crossref","first-page":"219","DOI":"10.1016\/0022-328X(95)00516-S","volume":"500","author":"Leigh G. J.","year":"1995","journal-title":"J. Organomet. Chem."},{"key":"ref4\/cit4c","unstructured":"cHenderson, R. A.InRecent Advances in Hydride Chemistry;Peruzzini, M. and Poli, R., Eds.; Elsevier:New York, 2001; pp463\u2212505."},{"key":"ref4\/cit4d","doi-asserted-by":"crossref","first-page":"6328","DOI":"10.1021\/bi052217h","volume":"45","author":"Dance I.","year":"2006","journal-title":"Biochemistry"},{"key":"ref5\/cit5","doi-asserted-by":"crossref","first-page":"6231","DOI":"10.1021\/ja043596p","volume":"127","author":"Igarashi R. Y.","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"ref6\/cit6","doi-asserted-by":"crossref","first-page":"1451","DOI":"10.1073\/pnas.0610975104","volume":"104","author":"Lukoyanov D.","year":"2007","journal-title":"Proc. Natl. Acad. Sci. U.S.A."},{"key":"ref7\/cit7","first-page":"221","volume":"7","author":"Thorneley R. N. F.","year":"1985","journal-title":"Met. Ions Biol."},{"key":"ref8\/cit8","doi-asserted-by":"crossref","first-page":"1696","DOI":"10.1126\/science.1073877","volume":"297","author":"Einsle O.","year":"2002","journal-title":"Science"},{"key":"ref9\/cit9","doi-asserted-by":"crossref","unstructured":"Poli, R.Paramagnetic Mono- and Polyhydrides of the Transition Metals. InRecent Advances in Hydride Chemistry;Peruzzini, M. and Poli, R., Eds.; Elsevier:New York, 2001, pp139\u2212188","DOI":"10.1016\/B978-044450733-4\/50006-1"},{"key":"ref10\/cit10a","doi-asserted-by":"crossref","first-page":"9","DOI":"10.1039\/dt9750000009","author":"Gargano M.","year":"1975","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ref10\/cit10b","doi-asserted-by":"crossref","first-page":"2570","DOI":"10.1021\/ja00842a060","volume":"97","author":"Rakowski M. C.","year":"1975","journal-title":"J. Am. Chem. Soc."},{"key":"ref11\/cit11a","doi-asserted-by":"crossref","first-page":"324","DOI":"10.1039\/b211036a","author":"Dance I.","year":"2003","journal-title":"Chem. Commun."},{"key":"ref11\/cit11b","doi-asserted-by":"crossref","first-page":"1466","DOI":"10.1021\/ja029041g","volume":"125","author":"Hinnemann B.","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"ref11\/cit11c","doi-asserted-by":"crossref","first-page":"8377","DOI":"10.1021\/ja0301572","volume":"125","author":"Lovell T.","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"ref11\/cit11d","doi-asserted-by":"crossref","first-page":"15772","DOI":"10.1021\/ja0367997","volume":"125","author":"Schimpl J.","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"ref11\/cit11e","doi-asserted-by":"crossref","first-page":"2588","DOI":"10.1021\/ja030541z","volume":"126","author":"Huniar U.","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"ref11\/cit11f","doi-asserted-by":"crossref","first-page":"3920","DOI":"10.1021\/ja037792s","volume":"126","author":"Hinnemann B.","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"ref11\/cit11g","doi-asserted-by":"crossref","first-page":"074306","DOI":"10.1063\/1.2008227","volume":"123","author":"K\u00e4stner J.","year":"2005","journal-title":"J. Chem. Phys."},{"key":"ref11\/cit11h","doi-asserted-by":"crossref","first-page":"1076","DOI":"10.1021\/ja0644428","volume":"129","author":"Dance I.","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"ref11\/cit11i","doi-asserted-by":"crossref","first-page":"2998","DOI":"10.1021\/ja068618h","volume":"129","author":"K\u00e4stner J.","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"ref11\/cit11j","doi-asserted-by":"crossref","first-page":"1796","DOI":"10.1002\/jcc.20636","volume":"28","author":"McKee M. L.","year":"2007","journal-title":"J. Comput. Chem."},{"key":"ref12\/cit12a","doi-asserted-by":"crossref","first-page":"1429","DOI":"10.1021\/om00040a001","volume":"11","author":"Hamon P.","year":"1992","journal-title":"Organometallics"},{"key":"ref12\/cit12b","doi-asserted-by":"crossref","first-page":"1602","DOI":"10.1039\/c39920001602","author":"Hamon P.","year":"1992","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"ref13\/cit13","doi-asserted-by":"crossref","first-page":"3461","DOI":"10.1021\/ic961300d","volume":"36","author":"Linn D. E.","year":"1997","journal-title":"Inorg. Chem."},{"key":"ref14\/cit14","doi-asserted-by":"crossref","first-page":"223","DOI":"10.1126\/science.7384796","volume":"209","author":"Ibers J. A.","year":"1980","journal-title":"Science"},{"key":"ref15\/cit15a","doi-asserted-by":"crossref","first-page":"3595","DOI":"10.1073\/pnas.0630028100","volume":"100","author":"Lee S. C.","year":"2003","journal-title":"Proc. Natl. Acad. Sci. U.S.A."},{"key":"ref15\/cit15b","doi-asserted-by":"crossref","first-page":"10457","DOI":"10.1021\/ja072256b","volume":"129","author":"Ohki Y.","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"ref16\/cit16","doi-asserted-by":"crossref","first-page":"37","DOI":"10.1007\/s007750100263","volume":"7","author":": Krahn E.","year":"2002","journal-title":"J. Biol. Inorg. Chem."},{"key":"ref17\/cit17","unstructured":"Extracted FeMoco is structurally intact but inactive. See ref3b."},{"key":"ref18\/cit18a","doi-asserted-by":"crossref","first-page":"296","DOI":"10.1139\/v05-005","volume":"83","author":"Holland P. L.","year":"2005","journal-title":"Can. J. Chem."},{"key":"ref18\/cit18b","doi-asserted-by":"crossref","unstructured":"bPeters, J. C. and Mehn, M. P.Bio-organometallic approaches to nitrogen fixation chemistry. InActivation of Small MoleculesTolman, W. B., Ed.; Wiley: Weinheim,Germany, 2006; pp81\u2212119.","DOI":"10.1002\/9783527609352.ch3"},{"key":"ref19\/cit19","doi-asserted-by":"crossref","first-page":"3012","DOI":"10.1021\/ja012327l","volume":"124","author":"Andres H.","year":"2002","journal-title":"J. Am. Chem. Soc."},{"key":"ref19\/cit19b","doi-asserted-by":"crossref","first-page":"14416","DOI":"10.1021\/ja025583m","volume":"124","author":"Holland P. L.","year":"2002","journal-title":"J. Am. Chem. Soc."},{"key":"ref19\/cit19c","doi-asserted-by":"crossref","first-page":"4915","DOI":"10.1021\/ic050321h","volume":"44","author":"Stoian S. A.","year":"2005","journal-title":"Inorg. Chem."},{"key":"ref19\/cit19d","doi-asserted-by":"crossref","first-page":"10181","DOI":"10.1021\/ja062051n","volume":"128","author":"Stoian S. A.","year":"2006","journal-title":"J. Am. Chem. Soc."},{"key":"ref20\/cit20","doi-asserted-by":"crossref","first-page":"15752","DOI":"10.1021\/ja038152s","volume":"125","author":"Smith J. M.","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"ref21\/cit21","doi-asserted-by":"crossref","first-page":"7857","DOI":"10.1021\/ja042672l","volume":"127","author":"Vela J.","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"ref22\/cit22a","doi-asserted-by":"crossref","first-page":"10782","DOI":"10.1021\/ja036687f","volume":"125","author":"Betley T. A.","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"ref22\/cit22b","doi-asserted-by":"crossref","first-page":"5074","DOI":"10.1021\/ic0343096","volume":"42","author":"Betley T. A.","year":"2003","journal-title":"Inorg. Chem."},{"key":"ref22\/cit22c","doi-asserted-by":"crossref","first-page":"11162","DOI":"10.1021\/ja036198f","volume":"125","author":"Jenkins D. M.","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"ref22\/cit22d","doi-asserted-by":"crossref","first-page":"6252","DOI":"10.1021\/ja048713v","volume":"126","author":"Betley T. A.","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"ref22\/cit22e","doi-asserted-by":"crossref","first-page":"8","DOI":"10.1021\/ic0350234","volume":"43","author":"Thomas C. M.","year":"2004","journal-title":"Inorg. Chem."},{"key":"ref22\/cit22f","doi-asserted-by":"crossref","first-page":"7148","DOI":"10.1021\/ja045310m","volume":"127","author":"Jenkins D. M.","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"ref22\/cit22g","doi-asserted-by":"crossref","first-page":"17107","DOI":"10.1073\/pnas.0604402103","volume":"103","author":"Hendrich M. P.","year":"2006","journal-title":"Proc. Natl. Acad. Sci. U.S.A."},{"key":"ref23\/cit23a","doi-asserted-by":"crossref","first-page":"4538","DOI":"10.1021\/ja0399122","volume":"126","author":"Brown S. D.","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"ref23\/cit23b","doi-asserted-by":"crossref","first-page":"4","DOI":"10.1021\/ja065524z","volume":"129","author":"Lu C. C.","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"ref24\/cit24","doi-asserted-by":"crossref","first-page":"13146","DOI":"10.1021\/ja0544509","volume":"127","author":"Brown S. D.","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"ref25\/cit25a","doi-asserted-by":"crossref","first-page":"3120","DOI":"10.1002\/1521-3773(20000901)39:17<3120::AID-ANIE3120>3.0.CO;2-K","volume":"39","author":"Ohki Y.","year":"2000","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"ref25\/cit25b","doi-asserted-by":"crossref","first-page":"313","DOI":"10.1016\/S0022-3697(02)00305-0","volume":"64","author":"Nowik I.","year":"2003","journal-title":"J. Phys. Chem. Solids"},{"key":"ref26\/cit26a","doi-asserted-by":"crossref","first-page":"6508","DOI":"10.1021\/ic049275w","volume":"43","author":"Koutmos M.","year":"2004","journal-title":"Inorg. Chem."},{"key":"ref26\/cit26b","doi-asserted-by":"crossref","first-page":"3648","DOI":"10.1021\/ic052156b","volume":"45","author":"Koutmos M.","year":"2006","journal-title":"Inorg. Chem."},{"key":"ref27\/cit27","doi-asserted-by":"crossref","first-page":"8112","DOI":"10.1021\/ja069199r","volume":"129","author":"Sadique A. R.","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"ref28\/cit28","doi-asserted-by":"crossref","first-page":"3217","DOI":"10.1021\/om7003805","volume":"26","author":"Yu Y.","year":"2007","journal-title":"Organometallics"},{"key":"ref29\/cit29a","doi-asserted-by":"crossref","first-page":"4522","DOI":"10.1021\/ja049417l","volume":"126","author":"Vela J.","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"ref29\/cit29b","doi-asserted-by":"crossref","first-page":"9344","DOI":"10.1021\/ja0436704","volume":"127","author":"Eckert N. A.","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"ref30\/cit30","doi-asserted-by":"crossref","first-page":"5226","DOI":"10.1021\/om049415+","volume":"23","author":": Vela J.","year":"2004","journal-title":"Organometallics"},{"key":"ref31\/cit31a","doi-asserted-by":"crossref","first-page":"4393","DOI":"10.1021\/bi00261a031","volume":"21","author":"Li J.-G.","year":"1982","journal-title":"Biochemistry"},{"key":"ref31\/cit31b","doi-asserted-by":"crossref","first-page":"6260","DOI":"10.1021\/bi00295a034","volume":"22","author":"Rubinson J. F.","year":"1983","journal-title":"Biochemistry"},{"key":"ref31\/cit31c","doi-asserted-by":"crossref","first-page":"8460","DOI":"10.1021\/bi00447a028","volume":"28","author":"Lowe D. J.","year":"1989","journal-title":"Biochemistry"},{"key":"ref31\/cit31d","doi-asserted-by":"crossref","first-page":"290","DOI":"10.1016\/0167-4838(88)90129-X","volume":"952","author":"Miller R. W.","year":"1988","journal-title":"Biochim. Biophys. Acta"},{"key":"ref32\/cit32","unstructured":"The X-band EPR spectrum of the solutions are consistent with a mixture of at least two compounds. In addition to the signal described in the text, there is a less rhombic signal withg= 2.08, 2.06, 2.00 (seeSupporting Information). These signals are almost identical to those previously identified as LtBuFe(CO)2(33)and LtBuFe(CO)3(47), supporting the assignment of the more rhombic signal as LMeFe(CNtBu)2and the less rhombic signal as LMeFe(CNtBu)3. The solution behavior of iron(I) isocyanide complexes will be described at length in a future publication."},{"key":"ref33\/cit33","doi-asserted-by":"crossref","first-page":"784","DOI":"10.1021\/ic701914m","volume":"47","author":"Sadique A. R.","year":"2008","journal-title":"Inorg. Chem."},{"key":"ref34\/cit34","doi-asserted-by":"crossref","unstructured":"Cambridge Structural Database, 2006, update:Allen, F. H.Acta Crystallogr.2002,B58,380. We used only high-quality (i.e.R< 10%) non-polymeric structures with no crystallographic disorder.","DOI":"10.1107\/S0108768102003890"},{"key":"ref35\/cit35","doi-asserted-by":"crossref","unstructured":"Similarly soft bending potentials have been seen in metal-imido complexes:Cundari, T. R. and Russo, M.J. Chem. Inf. Comput. Sci.2001,41,281\u2212287.","DOI":"10.1021\/ci0000068"},{"key":"ref37\/cit37","unstructured":"Yates, M. G. \u201cMolybdenum-Dependent Nitrogen Fixation\u201d. InBiological Nitrogen Fixation;Stacey, G., Burris, R. H., and Evans, H. J., Eds.; Chapman & Hall:New York, 1992; pp685\u2212735"},{"key":"ref38\/cit38","doi-asserted-by":"crossref","first-page":"208","DOI":"10.1021\/ar040050z","volume":"38","author":"Dos Santos P. C.","year":"2005","journal-title":"Acc. Chem. Res."},{"key":"ref39\/cit39","doi-asserted-by":"crossref","first-page":"9563","DOI":"10.1021\/ja048714n","volume":"126","author":"Lee H.-I.","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"ref40\/cit40","doi-asserted-by":"crossref","first-page":"4808","DOI":"10.1021\/om020571v","volume":"21","author":"Smith J. M.","year":"2002","journal-title":"Organometallics"},{"key":"ref41\/cit41a","doi-asserted-by":"crossref","first-page":"1317","DOI":"10.1073\/pnas.57.5.1317","volume":"57","author":"Sch\u00f6llhorn R.","year":"1967","journal-title":"Proc. Natl. Acad. Sci. U.S.A."},{"key":"ref41\/cit41b","doi-asserted-by":"crossref","first-page":"971","DOI":"10.1042\/bj1930971","volume":"193","author":"Dilworth M. J.","year":"1981","journal-title":"Biochem. J."},{"key":"ref42\/cit42","doi-asserted-by":"crossref","first-page":"1234","DOI":"10.1016\/j.ccr.2005.10.002","volume":"250","author":"Cenini S.","year":"2006","journal-title":"Coord. Chem. Rev."},{"key":"ref43\/cit43a","doi-asserted-by":"crossref","first-page":"1542","DOI":"10.1039\/b103635c","author":"Smith J. M.","year":"2001","journal-title":"Chem. Commun."},{"key":"ref43\/cit43b","doi-asserted-by":"crossref","first-page":"4808","DOI":"10.1021\/om020571v","volume":"21","author":"Smith J. M.","year":"2002","journal-title":"Organometallics"},{"key":"ref44\/cit44","doi-asserted-by":"crossref","first-page":"1913","DOI":"10.1021\/ja0453073","volume":"127","author":"Brown S. D.","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"ref45\/cit45","doi-asserted-by":"crossref","first-page":"677","DOI":"10.1021\/ic961017e","volume":"36","author":"Cortes R.","year":"1997","journal-title":"Inorg. Chem."},{"key":"ref46\/cit46","doi-asserted-by":"crossref","first-page":"301","DOI":"10.1016\/0020-1650(76)80170-5","volume":"12","author":"Adeosun S. O.","year":"1976","journal-title":"Inorg. Nucl. Chem. Lett."},{"key":"ref47\/cit47","doi-asserted-by":"crossref","first-page":"756","DOI":"10.1021\/ja052707x","volume":"128","author":"Smith J. M.","year":"2006","journal-title":"J. Am. Chem. Soc."},{"key":"ref48\/cit48a","doi-asserted-by":"crossref","first-page":"C40","DOI":"10.1016\/S0022-328X(00)93183-8","volume":"224","author":"Burgess K.","year":"1982","journal-title":"J. Organomet. Chem."},{"key":"ref48\/cit48b","doi-asserted-by":"crossref","first-page":"135","DOI":"10.1016\/S0022-328X(00)87091-6","volume":"228","author":"Johnson B. F. G.","year":"1982","journal-title":"J. Organomet. Chem."},{"key":"ref49\/cit49","doi-asserted-by":"crossref","first-page":"1025","DOI":"10.1021\/om00068a003","volume":"1","author":"Hillhouse G. L.","year":"1982","journal-title":"Organometallics"},{"key":"ref50\/cit50","doi-asserted-by":"crossref","first-page":"87","DOI":"10.1016\/S0022-328X(00)00039-5","volume":"601","author":"Wang Z. X.","year":"2000","journal-title":"J. Organomet. Chem."},{"key":"ref51\/cit51","doi-asserted-by":"crossref","first-page":"C23","DOI":"10.1016\/S0022-328X(00)82044-6","volume":"162","author":"Hillhouse G. L.","year":"1978","journal-title":"J. Organomet. Chem."},{"key":"ref52\/cit52","doi-asserted-by":"crossref","first-page":"3306","DOI":"10.1021\/ic035483x","volume":"43","author":"Eckert N. A.","year":"2004","journal-title":"Inorg. Chem."},{"key":"ref53\/cit53","doi-asserted-by":"crossref","first-page":"17113","DOI":"10.1073\/pnas.0602130103","volume":"103","author":"Barney B. M.","year":"2006","journal-title":"Proc. Natl. Acad. Sci. U.S.A."},{"key":"ref54\/cit54","doi-asserted-by":"crossref","first-page":"4502","DOI":"10.1021\/bi950964g","volume":"35","author":"McKenna C. E.","year":"1996","journal-title":"Biochemistry"},{"key":"ref55\/cit55","doi-asserted-by":"crossref","first-page":"14960","DOI":"10.1021\/ja0539342","volume":"127","author":"Barney B. M.","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"ref56\/cit56","doi-asserted-by":"crossref","first-page":"1161","DOI":"10.1039\/DT9940001161","author":"Atkinson F. L.","year":"1994","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ref57\/cit57","doi-asserted-by":"crossref","first-page":"5742","DOI":"10.1021\/ic052136+","volume":"45","author":"Yu Y.","year":"2006","journal-title":"Inorg. Chem."},{"key":"ref58\/cit58","doi-asserted-by":"crossref","first-page":"5382","DOI":"10.1021\/bi00016a009","volume":"34","author":"Seefeldt L. C.","year":"1995","journal-title":"Biochemistry"},{"key":"ref59\/cit59a","doi-asserted-by":"crossref","first-page":"8522","DOI":"10.1021\/ja00204a037","volume":"111","author":"Tolman W. B.","year":"1989","journal-title":"J. Am. Chem. Soc."},{"key":"ref59\/cit59b","doi-asserted-by":"crossref","first-page":"152","DOI":"10.1021\/ja00001a023","volume":"113","author":"Tolman W. B.","year":"1991","journal-title":"J. Am. Chem. Soc."},{"key":"ref59\/cit59c","doi-asserted-by":"crossref","first-page":"334","DOI":"10.1021\/ic00002a035","volume":"30","author":"Sessler J. L.","year":"1991","journal-title":"Inorg. Chem."},{"key":"ref60\/cit60","doi-asserted-by":"crossref","first-page":"2981","DOI":"10.1039\/b202851d","author":"Overgaard J.","year":"2002","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ref61\/cit61","doi-asserted-by":"crossref","first-page":"3653","DOI":"10.1021\/ja00324a041","volume":"106","author":"Armstrong W. H.","year":"1984","journal-title":"J. Am. Chem. Soc."},{"key":"ref62\/cit62a","doi-asserted-by":"crossref","first-page":"5632","DOI":"10.1021\/ic991399z","volume":"39","author":"Field L. D.","year":"2000","journal-title":"Inorg. Chem."},{"key":"ref62\/cit62b","doi-asserted-by":"crossref","first-page":"46","DOI":"10.1039\/b108492e","author":"Field L. D.","year":"2002","journal-title":"Chem. Commun."},{"key":"ref62\/cit62c","doi-asserted-by":"crossref","first-page":"4","DOI":"10.1021\/ja065524z","volume":"129","author":"Lu C. C.","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"ref63\/cit63","doi-asserted-by":"crossref","unstructured":"Another coordinatively unsaturated bis(\u03bc-hydroxo)diiron(II) complex has more acute angles at iron, presumably from steric clashes between bulky tris(pyrazolyl)borate ligands:Kisko, J. L., Hascall, T., and Parkin, G.J. Am. Chem. Soc.1998,120,10561\u221210562.","DOI":"10.1021\/ja982323p"},{"key":"ref65\/cit65","doi-asserted-by":"crossref","first-page":"63","DOI":"10.1016\/S0022-328X(96)06290-0","volume":"524","author":"Almeida S. S. P.","year":"1996","journal-title":"J. Organomet. Chem."},{"key":"ref66\/cit66a","doi-asserted-by":"crossref","first-page":"138","DOI":"10.1021\/om00037a029","volume":"11","author":"Bianchini C.","year":"1992","journal-title":"Organometallics"},{"key":"ref66\/cit66b","doi-asserted-by":"crossref","first-page":"75","DOI":"10.1039\/dt9930000075","author":"Hughes D. L.","year":"1993","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ref67\/cit67","doi-asserted-by":"crossref","first-page":"909","DOI":"10.1039\/a809099h","author":"Hughes D. L.","year":"1999","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ref68\/cit68a","doi-asserted-by":"crossref","first-page":"337","DOI":"10.1016\/S0022-328X(00)89809-5","volume":"35","author":"Bianco V. D.","year":"1972","journal-title":"J. Organomet. Chem."},{"key":"ref68\/cit68b","doi-asserted-by":"crossref","first-page":"5759","DOI":"10.1021\/om010598z","volume":"20","author":"Matsubara T.","year":"2001","journal-title":"Organometallics"},{"key":"ref68\/cit68c","doi-asserted-by":"crossref","first-page":"5632","DOI":"10.1021\/ic991399z","volume":"39","author":"Field L. D.","year":"2000","journal-title":"Inorg. Chem."},{"key":"ref68\/cit68d","doi-asserted-by":"crossref","first-page":"3491","DOI":"10.1021\/om0100030","volume":"20","author":"Field L. D.","year":"2001","journal-title":"Organometallics"},{"key":"ref69\/cit69","doi-asserted-by":"crossref","first-page":"2325","DOI":"10.1021\/om00005a034","volume":"14","author":"Hogarth G.","year":"1995","journal-title":"Organometallics"},{"key":"ref70\/cit70a","doi-asserted-by":"crossref","first-page":"4685","DOI":"10.1021\/ja00431a078","volume":"98","author":"Collman J. P.","year":"1976","journal-title":"J. Am. Chem. Soc."},{"key":"ref70\/cit70b","doi-asserted-by":"crossref","first-page":"950","DOI":"10.1021\/ic00227a014","volume":"25","author":"Albertin G.","year":"1986","journal-title":"Inorg. Chem."},{"key":"ref71\/cit71","doi-asserted-by":"crossref","first-page":"79","DOI":"10.1016\/S0277-5387(00)84717-8","volume":"3","author":"Chiu K. W.","year":"1984","journal-title":"Polyhedron"},{"key":"ref72\/cit72","doi-asserted-by":"crossref","first-page":"87","DOI":"10.1016\/S0022-328X(00)00039-5","volume":"601","author":"Wang Z. X.","year":"2000","journal-title":"J. Organomet. Chem."},{"key":"ref73\/cit73a","doi-asserted-by":"crossref","first-page":"3133","DOI":"10.1016\/0277-5387(95)00043-R","volume":"14","author":"Field L. D.","year":"1995","journal-title":"Polyhedron"},{"key":"ref74\/cit74","doi-asserted-by":"crossref","first-page":"1025","DOI":"10.1021\/om00068a003","volume":"1","author":"Hillhouse G. L.","year":"1982","journal-title":"Organometallics"},{"key":"ref75\/cit75a","doi-asserted-by":"crossref","first-page":"13794","DOI":"10.1021\/ja046753t","volume":"126","author":"Bart S. C.","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"ref75\/cit75b","doi-asserted-by":"crossref","first-page":"5518","DOI":"10.1021\/om050625b","volume":"24","author":"Bart S. C.","year":"2005","journal-title":"Organometallics"},{"key":"ref75\/cit75c","doi-asserted-by":"crossref","first-page":"4269","DOI":"10.1021\/om060441c","volume":"25","author":"Archer A. M.","year":"2006","journal-title":"Organometallics"},{"key":"ref76\/cit76","doi-asserted-by":"crossref","first-page":"4538","DOI":"10.1021\/ja0399122","volume":"126","author":"Brown S. D.","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"ref77\/cit77","doi-asserted-by":"crossref","first-page":"3111","DOI":"10.1021\/om0602963","volume":"25","author":"Ohki Y.","year":"2006","journal-title":"Organometallics"},{"key":"ref78\/cit78","unstructured":"For an iron-containing example, see:Gao, Y., Holah, D. G., Hughes, A. N., Spivak, G. J., Havighurst, M. D., Magnuson, V. R., and Polyakov, V.Polyhedron1997,16,2797\u22122807."},{"key":"ref79\/cit79a","doi-asserted-by":"crossref","first-page":"9472","DOI":"10.1021\/ja061508q","volume":"128","author":"MacKay B. A.","year":"2006","journal-title":"J. Am. Chem. Soc."},{"key":"ref79\/cit79b","doi-asserted-by":"crossref","first-page":"3234","DOI":"10.1021\/ja034303f","volume":"125","author":"Fryzuk M. D.","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"ref79\/cit79c","first-page":"3969","volume":"123","author":"Fryzuk M. D.","year":"2001","journal-title":"J. Am. Chem. Soc."},{"key":"ref80\/cit80","doi-asserted-by":"crossref","first-page":"1445","DOI":"10.1126\/science.275.5305.1445","volume":"275","author":"Fryzuk M. D.","year":"1997","journal-title":"Science"},{"key":"ref81\/cit81","doi-asserted-by":"crossref","first-page":"1205","DOI":"10.1021\/ic061570o","volume":"46","author":"Gilbertson J. D.","year":"2007","journal-title":"Inorg. Chem."},{"key":"ref82\/cit82a","doi-asserted-by":"crossref","first-page":"C41","DOI":"10.1016\/0022-328X(90)85070-F","volume":"391","author":"Hills A.","year":"1990","journal-title":"J. Organomet. Chem."},{"key":"ref82\/cit82b","doi-asserted-by":"crossref","first-page":"1785","DOI":"10.1039\/DT9910001785","author":"Evans D. J.","year":"1991","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ref82\/cit82c","doi-asserted-by":"crossref","first-page":"522","DOI":"10.1039\/c39910000522","author":"Hills A.","year":"1991","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"ref82\/cit82d","doi-asserted-by":"crossref","first-page":"3041","DOI":"10.1039\/dt9930003041","author":"Hills A.","year":"1993","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ref82\/cit82e","doi-asserted-by":"crossref","first-page":"1213","DOI":"10.1039\/a810001b","author":"Helleren C. A.","year":"1999","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ref82\/cit82f","doi-asserted-by":"crossref","first-page":"909","DOI":"10.1039\/a809099h","author":"Hughes D. L.","year":"1999","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ref83\/cit83a","doi-asserted-by":"crossref","first-page":"803","DOI":"10.1246\/cl.1997.803","volume":"26","author":"Nakayama Y.","year":"1997","journal-title":"Chem. Lett."},{"key":"ref83\/cit83b","doi-asserted-by":"crossref","first-page":"1143","DOI":"10.1021\/ic00005a048","volume":"30","author":"Hill J. E.","year":"1991","journal-title":"Inorg. Chem."},{"key":"ref84\/cit84","doi-asserted-by":"crossref","first-page":"429","DOI":"10.1021\/ic50085a001","volume":"9","author":"Doedens R. J.","year":"1970","journal-title":"Inorg. Chem."},{"key":"ref85\/cit85","doi-asserted-by":"crossref","first-page":"785","DOI":"10.1515\/znb-1993-0613","volume":"48","author":"Klein H. F.","year":"1993","journal-title":"Z. Naturforsch. B"},{"key":"ref86\/cit86","doi-asserted-by":"crossref","first-page":"107","DOI":"10.1016\/S0010-8545(02)00030-9","volume":"233","author":"Hoskin A. J.","year":"2002","journal-title":"Coord. Chem. Rev."},{"key":"ref87\/cit87a","doi-asserted-by":"crossref","first-page":"2481","DOI":"10.1021\/om050071c","volume":"24","author":"Henry R. M.","year":"2005","journal-title":"Organometallics"},{"key":"ref87\/cit87b","doi-asserted-by":"crossref","first-page":"4964","DOI":"10.1021\/om700510b","volume":"26","author":"Jacobsen G. M.","year":"2007","journal-title":"Organometallics"},{"key":"ref88\/cit88a","doi-asserted-by":"crossref","first-page":"875","DOI":"10.1021\/ja00003a022","volume":"113","author":"Jia G.","year":"1991","journal-title":"J. Am. Chem. Soc."},{"key":"ref88\/cit88b","doi-asserted-by":"crossref","first-page":"3375","DOI":"10.1021\/ja00087a024","volume":"116","author":"Cappellani E. P.","year":"1994","journal-title":"J. Am. Chem. Soc."},{"key":"ref89\/cit89a","doi-asserted-by":"crossref","first-page":"1670","DOI":"10.1039\/C39870001670","author":"Henderson R. A.","year":"1987","journal-title":"Chem. Commun."},{"key":"ref89\/cit89b","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/0010-8545(85)85020-7","volume":"65","author":"Hlatky G. G.","year":"1985","journal-title":"Coord. Chem. Rev."},{"key":"ref89\/cit89c","doi-asserted-by":"crossref","first-page":"441","DOI":"10.1039\/c39920000441","author":"Oglieve K. E.","year":"1992","journal-title":"Chem. Commun."},{"key":"ref90\/cit90","first-page":", 65","volume":"12","author":"Husseini , A.;","year":"1985","journal-title":"Dirasat. Univ. Jordan"},{"key":"ref91\/cit91","unstructured":"We are not aware that any researchers have investigated the reduction of formate by nitrogenase. This would be a fruitful area of investigation."},{"key":"ref92\/cit92a","doi-asserted-by":"crossref","first-page":"62","DOI":"10.1021\/ed069p62.1","volume":"69","author":"Schubert E. M.","year":"1992","journal-title":"J. Chem. Educ."},{"key":"ref92\/cit92b","doi-asserted-by":"crossref","first-page":"2003","DOI":"10.1039\/jr9590002003","author":"Evans D. F.","year":"1959","journal-title":"J. Chem. Soc."},{"key":"ref93\/cit93","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1007\/3-540-54261-2_1","volume":"78","author":"Trautwein A. X.","year":"1991","journal-title":"Struct. Bonding (Berlin)"},{"key":"ref94\/cit94","unstructured":"Frisch, M. J.et al.Gaussian03; Gaussian Inc.Pittsburgh, PA, 1998."},{"key":"ref95\/cit95","doi-asserted-by":"crossref","first-page":"19357","DOI":"10.1021\/jp962071j","volume":"100","author":"Svensson M.","year":"1996","journal-title":"J. Phys. Chem."},{"key":"ref96\/cit96a","doi-asserted-by":"crossref","first-page":"10024","DOI":"10.1021\/ja00051a040","volume":"114","author":"Rapp\u00e9 A. K.","year":"1992","journal-title":"J. Am. Chem. Soc."},{"key":"ref96\/cit96b","doi-asserted-by":"crossref","first-page":"10035","DOI":"10.1021\/ja00051a041","volume":"114","author":"Casewit C. J.","year":"1992","journal-title":"J. Am. Chem. Soc."}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/ja710669w","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,3,6]],"date-time":"2023-03-06T01:32:52Z","timestamp":1678066372000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/ja710669w"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2008,4,30]]},"references-count":161,"journal-issue":{"issue":"20","published-print":{"date-parts":[[2008,5,1]]}},"alternative-id":["10.1021\/ja710669w"],"URL":"https:\/\/doi.org\/10.1021\/ja710669w","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2008,4,30]]}}}