{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,3]],"date-time":"2026-10-03T11:42:37Z","timestamp":1791027757606,"version":"4.1.0"},"reference-count":29,"publisher":"American Chemical Society (ACS)","issue":"13","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2009,4,8]]},"DOI":"10.1021\/ja900953d","type":"journal-article","created":{"date-parts":[[2009,3,12]],"date-time":"2009-03-12T13:44:07Z","timestamp":1236865447000},"page":"4604-4605","source":"Crossref","is-referenced-by-count":93,"title":["Activation of an Alkyl C\u2212H Bond Geminal to an Agostic Interaction: An Unusual Mode of Base-Induced C\u2212H Activation"],"prefix":"10.1021","volume":"131","author":[{"given":"L. Jonas L.","family":"H\u00e4ller","sequence":"first","affiliation":[{"name":"School of Engineering and Physical Sciences, Perkin Building, Heriot-Watt University, Edinburgh, EH14 4AS, U.K., and Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, U.K."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michael J.","family":"Page","sequence":"additional","affiliation":[{"name":"School of Engineering and Physical Sciences, Perkin Building, Heriot-Watt University, Edinburgh, EH14 4AS, U.K., and Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, U.K."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Stuart A.","family":"Macgregor","sequence":"additional","affiliation":[{"name":"School of Engineering and Physical Sciences, Perkin Building, Heriot-Watt University, Edinburgh, EH14 4AS, U.K., and Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, U.K."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mary F.","family":"Mahon","sequence":"additional","affiliation":[{"name":"School of Engineering and Physical Sciences, Perkin Building, Heriot-Watt University, Edinburgh, EH14 4AS, U.K., and Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, U.K."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michael K.","family":"Whittlesey","sequence":"additional","affiliation":[{"name":"School of Engineering and Physical Sciences, Perkin Building, Heriot-Watt University, Edinburgh, EH14 4AS, U.K., and Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, U.K."}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2009,3,12]]},"reference":[{"key":"ref1\/cit1a","doi-asserted-by":"crossref","first-page":"395","DOI":"10.1016\/0022-328X(83)85065-7","volume":"250","author":"Brookhart M.","year":"1983","journal-title":"J. Organomet. Chem."},{"key":"ref1\/cit1b","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1002\/9780470166376.ch1","volume":"36","author":"Brookhart M.","year":"1988","journal-title":"Prog. Inorg. Chem."},{"key":"ref1\/cit1c","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1007\/b97940","volume":"113","author":"Clot E.","year":"2004","journal-title":"Struct. Bonding (Berlin)"},{"key":"ref2\/cit2a","unstructured":"aGoldman, A. S. and Goldberg, K. I.InActivation and Functionalization of C\u2212H Bonds;Goldman, A. S. and Goldberg, K. I.,Eds.ACS Symposium Series885; American Chemical Society: Washington, DC, 2004; p 1."},{"key":"ref2\/cit2b","doi-asserted-by":"crossref","first-page":"403","DOI":"10.1021\/cr00100a004","volume":"90","author":"Ryabov A. D.","year":"1990","journal-title":"Chem. Rev."},{"key":"ref2\/cit2c","doi-asserted-by":"crossref","first-page":"2879","DOI":"10.1021\/cr9411886","volume":"97","author":"Shilov A. E.","year":"1997","journal-title":"Chem. Rev."},{"key":"ref2\/cit2d","doi-asserted-by":"crossref","first-page":"2437","DOI":"10.1039\/b103147n","author":"Crabtree R. H.","year":"2001","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ref2\/cit2e","doi-asserted-by":"crossref","DOI":"10.1007\/b113929","volume-title":"Metal Dihydrogen and \u03c3-Bond Complexes","author":"Kubas G. J.","year":"2001"},{"key":"ref3\/cit3","unstructured":"Direct observation of this process is rather rare. Aromatic C\u2212H bonds:"},{"key":"ref3\/cit3a","doi-asserted-by":"crossref","first-page":"426","DOI":"10.1021\/om00121a052","volume":"4","author":"Speckman D. M.","year":"1985","journal-title":"Organometallics"},{"key":"ref3\/cit3b","doi-asserted-by":"crossref","first-page":"7122.","DOI":"10.1021\/ja00282a058","volume":"108","author":"Kanamori K.","year":"1986","journal-title":"J. Am. Chem. Soc."},{"key":"ref3\/cit3c","doi-asserted-by":"crossref","first-page":"12539","DOI":"10.1021\/ja982534u","volume":"120","author":"Vigalok A.","year":"1998","journal-title":"J. Am. Chem. Soc."},{"key":"ref3\/cit3d","doi-asserted-by":"crossref","first-page":"1734","DOI":"10.1021\/om000085c","volume":"19","author":"Gusev D. G.","year":"2000","journal-title":"Organometallics"},{"key":"ref4\/cit4","doi-asserted-by":"crossref","first-page":"1987","DOI":"10.1021\/ja065790c","volume":"129","author":"Burling S.","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"ref5\/cit5","unstructured":"NHC abbreviations: IiPr2Me2= 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene, IiPrMe = 1-isopropyl-3-methylimidazol-2-ylidene, IMe2= 1,3-dimethylimidazol-2-ylidene, IMe4= 1,3,4,5-tetramethylimidazol-2-ylidene."},{"key":"ref6\/cit6a","doi-asserted-by":"crossref","first-page":"2004","DOI":"10.1002\/anie.199720041","volume":"36","author":"Huang D.","year":"1997","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref6\/cit6b","doi-asserted-by":"crossref","first-page":"1629","DOI":"10.1002\/(SICI)1521-3773(19990601)38:11<1629::AID-ANIE1629>3.0.CO;2-L","volume":"38","author":"Baratta W.","year":"1999","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref6\/cit6c","doi-asserted-by":"crossref","first-page":"5549","DOI":"10.1021\/ja038986a","volume":"126","author":"Baratta W.","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"ref7\/cit7","unstructured":"C\u2212H reductive elimination from1and deuteration of the resultant Ru(0) intermediate would account for the exclusive formation of2-D."},{"key":"ref8\/cit8","unstructured":"Frisch, M.et al.Gaussian 03, revision D.01;Gaussian, Inc.:Pittsburgh, PA, 2001. The BP86 functional was employed with SDD RECPs and basis sets on Ru and P (with d-orbital polarisation on the latter) and 6\u221231G** basis sets on all other atoms. Energies include a correction for zero-point energies. SeeSupporting Informationfor full details."},{"key":"ref9\/cit9a","doi-asserted-by":"crossref","first-page":"3516","DOI":"10.1021\/ja043249f","volume":"127","author":"Scott N. M.","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"ref9\/cit9b","doi-asserted-by":"crossref","first-page":"4002","DOI":"10.1021\/om060343r","volume":"25","author":"Corber\u00e1n R.","year":"2006","journal-title":"Organometallics"},{"key":"ref10\/cit10a","doi-asserted-by":"crossref","first-page":"11041","DOI":"10.1021\/ja029197g","volume":"125","author":"Rybtchinski B.","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"ref10\/cit10b","doi-asserted-by":"crossref","first-page":"1854","DOI":"10.1016\/j.ica.2003.11.014","volume":"357","author":"van der Boom M. E.","year":"2004","journal-title":"Inorg. Chim. Acta"},{"key":"ref11\/cit11","doi-asserted-by":"crossref","first-page":"8717","DOI":"10.1021\/ja038973x","volume":"126","author":"Magill A. M.","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"ref12\/cit12","unstructured":"Solvent effects (THF, PCM method) reduce \u0394E\u2021to 10.3 kcal\/mol."},{"key":"ref13\/cit13","doi-asserted-by":"crossref","first-page":"13754","DOI":"10.1021\/ja052047w","volume":"127","author":"Davies D. L.","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"ref14\/cit14a","doi-asserted-by":"crossref","first-page":"793","DOI":"10.1021\/om060465j","volume":"26","author":"Paul A.","year":"2007","journal-title":"Organometallics"},{"key":"ref14\/cit14b","doi-asserted-by":"crossref","first-page":"511","DOI":"10.1021\/om0101691","volume":"21","author":"Kua J.","year":"2002","journal-title":"Organometallics"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/ja900953d","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,3,11]],"date-time":"2024-03-11T15:53:30Z","timestamp":1710172410000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/ja900953d"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2009,3,12]]},"references-count":29,"journal-issue":{"issue":"13","published-print":{"date-parts":[[2009,4,8]]}},"alternative-id":["10.1021\/ja900953d"],"URL":"https:\/\/doi.org\/10.1021\/ja900953d","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2009,3,12]]}}}