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Semi-empirical calculations (PM3) were performed, which converged to the shown structure regardless of the starting configuration of the olefin (whether in or perpendicular to the metal coordination plane)."},{"key":"ref31\/cit31","doi-asserted-by":"crossref","first-page":"11539","DOI":"10.1021\/ja011055j","volume":"123","author":"Shultz L. H.","year":"2001","journal-title":"J. Am. Chem. Soc."},{"key":"ref32\/cit32","doi-asserted-by":"crossref","first-page":"83","DOI":"10.1021\/cr00054a001","volume":"83","author":"Seeman J. I.","year":"1983","journal-title":"Chem. 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