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Today"},{"key":"ref3\/cit3c","doi-asserted-by":"crossref","first-page":"193","DOI":"10.1021\/ar50007a001","volume":"1","author":"Mayo F. R.","year":"1968","journal-title":"Acc. Chem. Res."},{"key":"ref3\/cit3d","doi-asserted-by":"crossref","first-page":"124","DOI":"10.1007\/s11244-008-9099-7","volume":"50","author":"Hermans I.","year":"2008","journal-title":"Top. Catal."},{"key":"ref4\/cit4a","doi-asserted-by":"crossref","first-page":"3400","DOI":"10.1002\/anie.200300630","volume":"43","author":"Stahl S. S.","year":"2004","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref4\/cit4b","unstructured":"bFeringa, B. L.InTransition Metals for Organic Chemistry Volume 2;Beller, M. and Bolm, C., Eds.Wiley-VCH: 1998; p307."},{"key":"ref5\/cit5a","first-page":"317","volume":"47","author":"Neumann R.","year":"1998","journal-title":"Prog. Inorg. Chem."},{"key":"ref5\/cit5b","volume-title":"Catalysts for Fine Chemical Synthesis, Volume 2","author":"Kozhevnikov I. 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Ed."},{"key":"ref6\/cit6f","doi-asserted-by":"crossref","first-page":"235","DOI":"10.1021\/cr9900275","volume":"100","author":"Solomon E. I.","year":"2000","journal-title":"Chem. Rev."},{"key":"ref7\/cit7a","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1080\/01614947408079624","volume":"10","author":"Kilty P. A.","year":"1974","journal-title":"Catal. Rev."},{"key":"ref7\/cit7b","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1023\/A:1021499225395","volume":"22","author":"Barteau M. A.","year":"2003","journal-title":"Top. Catal."},{"key":"ref7\/cit7c","doi-asserted-by":"crossref","first-page":"374","DOI":"10.1016\/j.jcat.2004.04.032","volume":"225","author":"Monnier J. R.","year":"2004","journal-title":"J. Catal."},{"key":"ref8\/cit8a","doi-asserted-by":"crossref","first-page":"3026","DOI":"10.1002\/(SICI)1521-3773(19991018)38:20<3026::AID-ANIE3026>3.0.CO;2-P","volume":"38","author":"D\u00f6bler C.","year":"1999","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref8\/cit8b","doi-asserted-by":"crossref","first-page":"10289","DOI":"10.1021\/ja000802u","volume":"122","author":"D\u00f6bler C.","year":"2000","journal-title":"J. Am. Chem. Soc."},{"key":"ref8\/cit8c","doi-asserted-by":"crossref","first-page":"70","DOI":"10.1016\/S0022-328X(00)00856-1","volume":"621","author":"D\u00f6bler C.","year":"2001","journal-title":"J. Organomet. Chem."},{"key":"ref9\/cit9a","doi-asserted-by":"crossref","first-page":"5790","DOI":"10.1021\/ja00306a029","volume":"107","author":"Groves J. T.","year":"1985","journal-title":"J. Am. Chem. Soc."},{"key":"ref9\/cit9b","doi-asserted-by":"crossref","first-page":"3831","DOI":"10.1021\/ic00270a001","volume":"26","author":"Groves J. T.","year":"1987","journal-title":"Inorg. Chem."},{"key":"ref9\/cit9c","doi-asserted-by":"crossref","first-page":"147","DOI":"10.1016\/0304-5102(87)80025-1","volume":"41","author":"James B. R.","year":"1987","journal-title":"J. Mol. Catal."},{"key":"ref10\/cit10a","doi-asserted-by":"crossref","first-page":"353","DOI":"10.1038\/41039","volume":"388","author":"Neumann R.","year":"1997","journal-title":"Nature"},{"key":"ref10\/cit10b","doi-asserted-by":"crossref","first-page":"11969","DOI":"10.1021\/ja974243b","volume":"120","author":"Neumann R.","year":"1998","journal-title":"J. Am. Chem. Soc."},{"key":"ref11\/cit11","doi-asserted-by":"crossref","first-page":"4178","DOI":"10.1021\/ja043083i","volume":"127","author":"Kim S. O.","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"ref12\/cit12","doi-asserted-by":"crossref","first-page":"140","DOI":"10.1246\/bcsj.79.140","volume":"79","author":"Varala R.","year":"2006","journal-title":"Bull. Chem. Soc. Jpn."},{"key":"ref13\/cit13","doi-asserted-by":"crossref","first-page":"135","DOI":"10.1021\/ic00222a008","volume":"25","author":"Collin J. P.","year":"1986","journal-title":"Inorg. Chem."},{"key":"ref14\/cit14","doi-asserted-by":"crossref","first-page":"360","DOI":"10.1016\/0022-2852(77)90047-9","volume":"67","author":"Verma K. K.","year":"1977","journal-title":"J. Mol. Spectrosc."},{"key":"ref15\/cit15","doi-asserted-by":"crossref","first-page":"618","DOI":"10.1063\/1.450608","volume":"84","author":"Coe J. V.","year":"1986","journal-title":"J. Chem. Phys."},{"key":"ref16\/cit16","unstructured":"Sterically hindered RuII(2,9-dimethyl-1,10-phenanthroline)2(H2O)2has been reported (UV\u2212vis spectra only) to yield dioxo species upon reaction with H2O2. In HFIP the reaction of RuII(2,9-dimethyl-1,10-phenanthroline)2(H2O)2with O2showed no change in the UV\u2212vis spectrum and no formation of Ru-oxo compounds."},{"key":"ref16\/cit16a","doi-asserted-by":"crossref","first-page":"2424","DOI":"10.1021\/ja00085a023","volume":"116","author":"Goldstein A. S.","year":"1994","journal-title":"J. Am. Chem. Soc."},{"key":"ref16\/cit16b","doi-asserted-by":"crossref","first-page":"21","DOI":"10.1039\/c39910000021","author":"Goldstein A. S.","year":"1991","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"ref17\/cit17","doi-asserted-by":"crossref","first-page":"5651","DOI":"10.1021\/ja00015a019","volume":"113","author":"Choi M.-G.","year":"1991","journal-title":"J. Am. Chem. Soc."},{"key":"ref18\/cit18","unstructured":"Frisch, M. J.Gaussian 03,revision E.01; Gaussian, Inc.:Wallingford, CT, 2004."},{"key":"ref19\/cit19","unstructured":"Minnesota Gaussian Functional Module version 3.1;Zhao, Y. and Truhlar, D. G.with assistance fromIron, J. M. A. and Martin, M. L.University of Minnesota,Minneapolis, MN, 2008."},{"key":"ref20\/cit20a","doi-asserted-by":"crossref","first-page":"215","DOI":"10.1007\/s00214-007-0310-x","volume":"120","author":"Zhao Y.","year":"2008","journal-title":"Theor. Chem. Acc."},{"key":"ref20\/cit20b","doi-asserted-by":"crossref","first-page":"157","DOI":"10.1021\/ar700111a","volume":"41","author":"Zhao Y.","year":"2008","journal-title":"Acc. Chem. Res."},{"key":"ref21\/cit21","doi-asserted-by":"crossref","first-page":"194101","DOI":"10.1063\/1.2370993","volume":"125","author":"Zhao Y.","year":"2006","journal-title":"J. Chem. Phys."},{"key":"ref22\/cit22","doi-asserted-by":"crossref","first-page":"1007","DOI":"10.1063\/1.456153","volume":"90","author":"Dunning T. H.","year":"1989","journal-title":"J. Chem. Phys."},{"key":"ref23\/cit23","unstructured":"Dolg, M.Effective Core Potentials. In Modern Methods and Algorithms of Quantum Chemistry;John von Neumann Institute for Computing:J\u00fclich, 2000; Vol.1, p 479."},{"key":"ref24\/cit24","doi-asserted-by":"crossref","first-page":"3408","DOI":"10.1063\/1.1337864","volume":"114","author":"Martin J. M. L.","year":"2001","journal-title":"J. Chem. Phys."},{"key":"ref25\/cit25","doi-asserted-by":"crossref","first-page":"11113","DOI":"10.1063\/1.1622924","volume":"119","author":"Peterson K. A.","year":"2003","journal-title":"J. Chem. Phys."},{"key":"ref26\/cit26a","doi-asserted-by":"crossref","first-page":"3140","DOI":"10.1063\/1.445228","volume":"78","author":"Dunlap B. I.","year":"1983","journal-title":"J. Chem. Phys."},{"key":"ref26\/cit26b","doi-asserted-by":"crossref","first-page":"37","DOI":"10.1016\/S0166-1280(00)00528-5","volume":"529","author":"Dunlap B. I.","year":"2000","journal-title":"THEOCHEM"},{"key":"ref27\/cit27","unstructured":"Truhlar, D. G.\u201c2006 Schr\u00f6dinger Medal Lecture: New Density Functionals with Broad Applicability for Thermochemistry, Thermochemical Kinetics, Noncovalent Interactions, Transition Metals, and Spectroscopy\u201d presented at the Eighth Triennial Congress of the World Association of Theoretical and Computational Chemistry (WATOC), Sydney, Australia, September 14\u221219, 2008."},{"key":"ref28\/cit28a","doi-asserted-by":"crossref","first-page":"5151","DOI":"10.1063\/1.473558","volume":"106","author":"Mennucci B.","year":"1997","journal-title":"J. Chem. Phys."},{"key":"ref28\/cit28b","doi-asserted-by":"crossref","first-page":"3032","DOI":"10.1063\/1.474659","volume":"107","author":"Canc\u00e8s E.","year":"1997","journal-title":"J. Chem. Phys."},{"key":"ref28\/cit28c","doi-asserted-by":"crossref","first-page":"253","DOI":"10.1016\/S0009-2614(98)00106-7","volume":"286","author":"Cossi M.","year":"1998","journal-title":"Chem. Phys. Lett."},{"key":"ref28\/cit28d","doi-asserted-by":"crossref","first-page":"43","DOI":"10.1063\/1.1480445","volume":"117","author":"Cossi M.","year":"2002","journal-title":"J. Chem. Phys."},{"key":"ref28\/cit28e","doi-asserted-by":"crossref","first-page":"10506","DOI":"10.1021\/jp971959k","volume":"101","author":"Mennucci B.","year":"1997","journal-title":"J. Phys. Chem. B"},{"key":"ref28\/cit28f","doi-asserted-by":"crossref","first-page":"211","DOI":"10.1016\/S0166-1280(98)00553-3","volume":"464","author":"Tomasi J.","year":"1999","journal-title":"THEOCHEM"},{"key":"ref29\/cit29","doi-asserted-by":"crossref","first-page":"899","DOI":"10.1021\/cr00088a005","volume":"88","author":"Reed A. E.","year":"1988","journal-title":"Chem. Rev."},{"key":"ref30\/cit30","doi-asserted-by":"crossref","first-page":"1833","DOI":"10.1063\/1.1740588","volume":"23","author":"Mulliken R. S.","year":"1955","journal-title":"J. Chem. 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