{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T06:24:01Z","timestamp":1790144641442,"version":"4.0.1"},"reference-count":46,"publisher":"American Chemical Society (ACS)","issue":"37","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2009,9,23]]},"DOI":"10.1021\/ja905057w","type":"journal-article","created":{"date-parts":[[2009,8,26]],"date-time":"2009-08-26T16:20:11Z","timestamp":1251303611000},"page":"13464-13473","source":"Crossref","is-referenced-by-count":130,"title":["Energetics of C\u2212H Bond Activation of Fluorinated Aromatic Hydrocarbons Using a [Tp\u2032Rh(CNneopentyl)] Complex"],"prefix":"10.1021","volume":"131","author":[{"given":"Meagan E.","family":"Evans","sequence":"first","affiliation":[{"name":"Department of Chemistry, University of Rochester, Rochester, New York 14627, and Institut Charles Gerhardt, Universit\u00e9 Montpellier 2, CNRS 5253, case courrier 1501, Place E. Bataillon, 34095 Montpellier, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Catherine L.","family":"Burke","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Rochester, Rochester, New York 14627, and Institut Charles Gerhardt, Universit\u00e9 Montpellier 2, CNRS 5253, case courrier 1501, Place E. Bataillon, 34095 Montpellier, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sornanong","family":"Yaibuathes","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Rochester, Rochester, New York 14627, and Institut Charles Gerhardt, Universit\u00e9 Montpellier 2, CNRS 5253, case courrier 1501, Place E. Bataillon, 34095 Montpellier, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eric","family":"Clot","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Rochester, Rochester, New York 14627, and Institut Charles Gerhardt, Universit\u00e9 Montpellier 2, CNRS 5253, case courrier 1501, Place E. Bataillon, 34095 Montpellier, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Odile","family":"Eisenstein","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Rochester, Rochester, New York 14627, and Institut Charles Gerhardt, Universit\u00e9 Montpellier 2, CNRS 5253, case courrier 1501, Place E. Bataillon, 34095 Montpellier, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"William D.","family":"Jones","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Rochester, Rochester, New York 14627, and Institut Charles Gerhardt, Universit\u00e9 Montpellier 2, CNRS 5253, case courrier 1501, Place E. Bataillon, 34095 Montpellier, France"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2009,8,26]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"crossref","first-page":"1221","DOI":"10.1126\/science.208.4449.1221","volume":"208","author":"Parshall G. W.","year":"1980","journal-title":"Science"},{"key":"ref2\/cit2","doi-asserted-by":"crossref","first-page":"16170","DOI":"10.1021\/ja807258m","volume":"130","author":"Nakao Y.","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"ref3\/cit3","doi-asserted-by":"crossref","first-page":"6957","DOI":"10.1073\/pnas.0609726104","volume":"104","author":"Vetter A. J.","year":"2007","journal-title":"Proc. Natl. Acad. Sci. U.S.A."},{"key":"ref4\/cit4","doi-asserted-by":"crossref","first-page":"6939","DOI":"10.1073\/pnas.0609454104","volume":"104","author":"Clot E.","year":"2007","journal-title":"Proc. Natl. Acad. Sci. U.S.A."},{"key":"ref5\/cit5","doi-asserted-by":"crossref","first-page":"1444","DOI":"10.1021\/ja00239a026","volume":"109","author":"Bryndza H. E.","year":"1987","journal-title":"J. Am. Chem. Soc."},{"key":"ref6\/cit6","doi-asserted-by":"crossref","first-page":"2179","DOI":"10.1021\/ja00084a082","volume":"116","author":"Bennett J. L.","year":"1994","journal-title":"J. Am. Chem. Soc."},{"key":"ref7\/cit7","doi-asserted-by":"crossref","first-page":"10696","DOI":"10.1021\/ja9707419","volume":"119","author":"Bennett J. L.","year":"1997","journal-title":"J. Am. Chem. Soc."},{"key":"ref8\/cit8","doi-asserted-by":"crossref","first-page":"522","DOI":"10.1021\/om00014a025","volume":"13","author":"Selmeczy A. D.","year":"1994","journal-title":"Organometallics"},{"key":"ref9\/cit9","doi-asserted-by":"crossref","first-page":"554","DOI":"10.1021\/ja00055a027","volume":"115","author":"Jones W. D.","year":"1993","journal-title":"J. Am. Chem. Soc."},{"key":"ref10\/cit10","doi-asserted-by":"crossref","first-page":"495","DOI":"10.1021\/om9808211","volume":"18","author":"Jones W. D.","year":"1999","journal-title":"Organometallics"},{"key":"ref11\/cit11","doi-asserted-by":"crossref","first-page":"6087","DOI":"10.1021\/ja00041a029","volume":"114","author":"Jones W. D.","year":"1992","journal-title":"J. Am. Chem. Soc."},{"key":"ref12\/cit12","doi-asserted-by":"crossref","first-page":"928","DOI":"10.1039\/C39890000928","volume":"14","author":"Belt S. T.","year":"1989","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"ref13\/cit13","doi-asserted-by":"crossref","first-page":"266","DOI":"10.1039\/C39910000266","volume":"4","author":"Belt S. T.","year":"1991","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"ref14\/cit14","doi-asserted-by":"crossref","first-page":"1269","DOI":"10.1039\/a608135e","volume":"8","author":"Higgitt C. L.","year":"1997","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ref15\/cit15","doi-asserted-by":"crossref","first-page":"12315","DOI":"10.1021\/ja042152q","volume":"127","author":"Vetter A. J.","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"ref16\/cit16","doi-asserted-by":"crossref","first-page":"4791","DOI":"10.1021\/ja00850a001","volume":"97","author":"Perutz R. N.","year":"1975","journal-title":"J. Am. Chem. Soc."},{"key":"ref17\/cit17","doi-asserted-by":"crossref","first-page":"7369","DOI":"10.1021\/ja00095a047","volume":"116","author":"Schultz R. H.","year":"1994","journal-title":"J. Am. Chem. Soc."},{"key":"ref18\/cit18","doi-asserted-by":"crossref","first-page":"260","DOI":"10.1126\/science.278.5336.260","volume":"278","author":"Bromberg S. E.","year":"1997","journal-title":"Science"},{"key":"ref19\/cit19","doi-asserted-by":"crossref","first-page":"7734","DOI":"10.1021\/ja970723r","volume":"119","author":"Edelbach B. L.","year":"1997","journal-title":"J. Am. Chem. Soc."},{"key":"ref20\/cit20","doi-asserted-by":"crossref","first-page":"1429","DOI":"10.1021\/ja00057a028","volume":"115","author":"Belt S. T.","year":"1993","journal-title":"J. Am. Chem. Soc."},{"key":"ref21\/cit21","doi-asserted-by":"crossref","first-page":"264","DOI":"10.1039\/C39910000264","volume":"4","author":"Jones W. D.","year":"1991","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"ref22\/cit22","doi-asserted-by":"crossref","first-page":"12634","DOI":"10.1021\/ja9824573","volume":"120","author":"Bosque R.","year":"1998","journal-title":"J. Am. Chem. Soc."},{"key":"ref23\/cit23","doi-asserted-by":"crossref","first-page":"5268","DOI":"10.1021\/ja0396908","volume":"126","author":"Reinhold M.","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"ref24\/cit24","doi-asserted-by":"crossref","first-page":"9304","DOI":"10.1021\/ja074640e","volume":"130","author":"Schaub T.","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"ref25\/cit25","doi-asserted-by":"crossref","first-page":"4920","DOI":"10.1021\/om9705160","volume":"16","author":"Cronin L.","year":"1997","journal-title":"Organometallics"},{"key":"ref26\/cit26","doi-asserted-by":"crossref","first-page":"1452","DOI":"10.1039\/b101101o","author":"Carbo J. J.","year":"2001","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ref27\/cit27","doi-asserted-by":"crossref","first-page":"2039","DOI":"10.1039\/a902573a","volume":"12","author":"Godoy F.","year":"1999","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"ref28\/cit28","doi-asserted-by":"crossref","first-page":"4065","DOI":"10.1039\/B305064E","author":"Clot E.","year":"2003","journal-title":"Dalton Trans."},{"key":"ref29\/cit29","doi-asserted-by":"crossref","first-page":"926","DOI":"10.1021\/om00094a022","volume":"7","author":"Labinger J. A.","year":"1988","journal-title":"Organometallics"},{"key":"ref30\/cit30","doi-asserted-by":"crossref","first-page":"490","DOI":"10.1039\/b210036n","author":"Clot E.","year":"2003","journal-title":"Chem. Commun."},{"key":"ref31\/cit31","doi-asserted-by":"crossref","first-page":"7817","DOI":"10.1021\/ja901640m","volume":"131","author":"Clot E.","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"ref32\/cit32","doi-asserted-by":"crossref","first-page":"495","DOI":"10.1021\/om9808211","volume":"18","author":"Wick D. D.","year":"1999","journal-title":"Organometallics"},{"key":"ref33\/cit33","first-page":"3897","volume":"118","author":"Lian T.","year":"1996","journal-title":"J. Am. Chem. Soc."},{"key":"ref35\/cit35","doi-asserted-by":"crossref","first-page":"10696","DOI":"10.1021\/ja9707419","volume":"119","author":"Bennett J. L.","year":"1997","journal-title":"J. Am. Chem. Soc."},{"key":"ref36\/cit36","doi-asserted-by":"crossref","first-page":"8350","DOI":"10.1021\/ja061803a","volume":"128","author":"Clot E.","year":"2006","journal-title":"J. Am. Chem. Soc."},{"key":"ref37\/cit37","doi-asserted-by":"crossref","first-page":"1444","DOI":"10.1021\/ja00239a026","volume":"109","author":"Bryndza H. E.","year":"1987","journal-title":"J. Am. Chem. Soc."},{"key":"ref38\/cit38","doi-asserted-by":"crossref","first-page":"1496","DOI":"10.1021\/om00040a020","volume":"11","author":"Hessell E. T.","year":"1992","journal-title":"Organometallics"},{"key":"ref39\/cit39","doi-asserted-by":"crossref","first-page":"10742","DOI":"10.1021\/ja9002316","volume":"131","author":"Vetter A. J.","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"ref40\/cit40","doi-asserted-by":"crossref","first-page":"4814","DOI":"10.1021\/ja00276a019","volume":"108","author":"Jones W. D.","year":"1986","journal-title":"J. Am. Chem. Soc."},{"key":"ref41\/cit41","volume-title":"Gaussian 03","author":"Frisch M. J.","year":"2004"},{"key":"ref42\/cit42","doi-asserted-by":"crossref","first-page":"5648","DOI":"10.1063\/1.464913","volume":"98","author":"Becke A. D.","year":"1993","journal-title":"J. Chem. Phys."},{"key":"ref43\/cit43","doi-asserted-by":"crossref","first-page":"13244","DOI":"10.1103\/PhysRevB.45.13244","volume":"45","author":"Perdew J. P.","year":"1992","journal-title":"Phys. Rev. B"},{"key":"ref44\/cit44","doi-asserted-by":"crossref","first-page":"123","DOI":"10.1007\/BF01114537","volume":"77","author":"Andrae D.","year":"1990","journal-title":"Theor. Chim. Acta"},{"key":"ref45\/cit45","doi-asserted-by":"crossref","first-page":"111","DOI":"10.1016\/0009-2614(93)80086-5","volume":"208","author":"Ehlers A. W.","year":"1993","journal-title":"Chem. Phys. Lett."},{"key":"ref46\/cit46","doi-asserted-by":"crossref","first-page":"213","DOI":"10.1007\/BF00533485","volume":"28","author":"Hariharan P. C.","year":"1973","journal-title":"Theor. Chim. Acta"},{"key":"ref47\/cit47","unstructured":"Frieden, C.KINSIM;Washington University School of Medicine:St. Louis, MO, 1997; http:\/\/www.biochem.wustl.edu\/cflab\/message.html."}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/ja905057w","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,3,13]],"date-time":"2023-03-13T08:03:07Z","timestamp":1678694587000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/ja905057w"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2009,8,26]]},"references-count":46,"journal-issue":{"issue":"37","published-print":{"date-parts":[[2009,9,23]]}},"alternative-id":["10.1021\/ja905057w"],"URL":"https:\/\/doi.org\/10.1021\/ja905057w","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2009,8,26]]}}}