{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T05:44:06Z","timestamp":1791351846599,"version":"4.3.1"},"reference-count":35,"publisher":"American Chemical Society (ACS)","issue":"44","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2009,11,11]]},"DOI":"10.1021\/ja9068408","type":"journal-article","created":{"date-parts":[[2009,10,16]],"date-time":"2009-10-16T11:20:38Z","timestamp":1255692038000},"page":"16272-16282","source":"Crossref","is-referenced-by-count":255,"title":["Reaction of Hydrogen or Ammonia with Unsaturated Germanium or Tin Molecules under Ambient Conditions: Oxidative Addition versus Arene Elimination"],"prefix":"10.1021","volume":"131","author":[{"given":"Yang","family":"Peng","sequence":"first","affiliation":[{"name":"Department of Chemistry, University of California, Davis, One Shields Avenue, Davis, California, 95616, and Department of Theoretical and Computational Molecular Science, Institute for Molecular Science, Okazaki, Aichi 444-8585, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jing-Dong","family":"Guo","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of California, Davis, One Shields Avenue, Davis, California, 95616, and Department of Theoretical and Computational Molecular Science, Institute for Molecular Science, Okazaki, Aichi 444-8585, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bobby D.","family":"Ellis","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of California, Davis, One Shields Avenue, Davis, California, 95616, and Department of Theoretical and Computational Molecular Science, Institute for Molecular Science, Okazaki, Aichi 444-8585, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhongliang","family":"Zhu","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of California, Davis, One Shields Avenue, Davis, California, 95616, and Department of Theoretical and Computational Molecular Science, Institute for Molecular Science, Okazaki, Aichi 444-8585, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"James C.","family":"Fettinger","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of California, Davis, One Shields Avenue, Davis, California, 95616, and Department of Theoretical and Computational Molecular Science, Institute for Molecular Science, Okazaki, Aichi 444-8585, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shigeru","family":"Nagase","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of California, Davis, One Shields Avenue, Davis, California, 95616, and Department of Theoretical and Computational Molecular Science, Institute for Molecular Science, Okazaki, Aichi 444-8585, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Philip P.","family":"Power","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of California, Davis, One Shields Avenue, Davis, California, 95616, and Department of Theoretical and Computational Molecular Science, Institute for Molecular Science, Okazaki, Aichi 444-8585, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2009,10,16]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"crossref","first-page":"12232","DOI":"10.1021\/ja053247a","volume":"127","author":"Spikes G. H.","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"ref2\/cit2","doi-asserted-by":"crossref","first-page":"6042","DOI":"10.1039\/b813442a","volume":"45","author":"Peng Y.","year":"2008","journal-title":"Chem. Commun."},{"key":"ref3\/cit3","doi-asserted-by":"crossref","first-page":"439","DOI":"10.1126\/science.1141474","volume":"316","author":"Frey G. D.","year":"2007","journal-title":"Science"},{"key":"ref4\/cit4","doi-asserted-by":"crossref","first-page":"1124","DOI":"10.1126\/science.1134230","volume":"314","author":"Welch G. C.","year":"2006","journal-title":"Science"},{"key":"ref5\/cit5","doi-asserted-by":"crossref","first-page":"12268","DOI":"10.1021\/ja805358u","volume":"130","author":"Peng Y.","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"ref6\/cit6","doi-asserted-by":"crossref","first-page":"2031","DOI":"10.1002\/anie.200805982","volume":"48","author":"Zhu Z.","year":"2009","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref7\/cit7","doi-asserted-by":"crossref","first-page":"1535","DOI":"10.1039\/b802575b","volume":"6","author":"Stephan D. W.","year":"2008","journal-title":"Org. Biomol. Chem."},{"key":"ref8\/cit8","doi-asserted-by":"crossref","first-page":"12632","DOI":"10.1021\/ja805493y","volume":"130","author":"Geier S. J.","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"ref9\/cit9","doi-asserted-by":"crossref","first-page":"52","DOI":"10.1021\/ja808506t","volume":"131","author":"Ullrich M.","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"ref10\/cit10","doi-asserted-by":"crossref","first-page":"7433","DOI":"10.1002\/anie.200802596","volume":"47","author":"Chase P. A.","year":"2008","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref11\/cit11","doi-asserted-by":"crossref","first-page":"7428","DOI":"10.1002\/anie.200802705","volume":"47","author":"Holschumacher D.","year":"2008","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref12\/cit12","doi-asserted-by":"crossref","first-page":"6001","DOI":"10.1002\/anie.200800935","volume":"47","author":"Sumerin V.","year":"2008","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref13\/cit13","doi-asserted-by":"crossref","first-page":"14117","DOI":"10.1021\/ja806627s","volume":"130","author":"Sumerin V.","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"ref14\/cit14","doi-asserted-by":"crossref","first-page":"5966","DOI":"10.1039\/b813286k","author":"Wang H.","year":"2008","journal-title":"Chem. Commun."},{"key":"ref15\/cit15","doi-asserted-by":"crossref","first-page":"1920","DOI":"10.1021\/om960929l","volume":"16","author":"Simons R. S.","year":"1997","journal-title":"Organometallics"},{"key":"ref16\/cit16","doi-asserted-by":"crossref","first-page":"1005","DOI":"10.1002\/zaac.200500532","volume":"632","author":"Spikes G. H.","year":"2006","journal-title":"Z. Anorg. Allg. Chem."},{"key":"ref17\/cit17","volume-title":"Gaussian 03","author":"Frisch M. J.","year":"2004"},{"key":"ref18\/cit18","doi-asserted-by":"crossref","first-page":"284","DOI":"10.1063\/1.448800","volume":"82","author":"Wadt W. R.","year":"1985","journal-title":"J. Chem. Phys."},{"key":"ref19\/cit19a","volume-title":"Gaussian Basis Sets for Molecular Calculations","year":"1984"},{"key":"ref19\/cit19b","doi-asserted-by":"crossref","first-page":"469","DOI":"10.1021\/om060993v","volume":"26","author":"Takagi N.","year":"2007","journal-title":"Organometallics"},{"key":"ref20\/cit20a","doi-asserted-by":"crossref","first-page":"117","DOI":"10.1016\/0301-0104(81)85090-2","volume":"55","author":"Miertus S.","year":"1981","journal-title":"Chem. Phys."},{"key":"ref20\/cit20b","doi-asserted-by":"crossref","first-page":"2999","DOI":"10.1021\/cr9904009","volume":"105","author":"Tomasi J.","year":"2005","journal-title":"Chem. Rev."},{"key":"ref21\/cit21","first-page":"1","volume":"41","author":"Hope H.","year":"1995","journal-title":"Prog. Inorg. Chem."},{"key":"ref22\/cit22","volume-title":"SADABS","year":"1998"},{"key":"ref23\/cit23","doi-asserted-by":"crossref","first-page":"3204","DOI":"10.1021\/ja029772g","volume":"125","author":"Richards A. F.","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"ref24\/cit24","doi-asserted-by":"crossref","first-page":"2774","DOI":"10.1021\/ic048362l","volume":"44","author":"Stanciu C.","year":"2005","journal-title":"Inorg. Chem."},{"key":"ref25\/cit25","unstructured":"Aylett, B. J.Organometallic Compounds, Vol. 1, Part 2, 4th ed.Chapman and Hall:London, 1997; p2."},{"key":"ref26\/cit26","unstructured":"Lappert, M. F., Power, P. P., Sanger, A. R., and Srivastava, R.;Metal and Metalloid Amides;Ellis Horwood-Willey:Chichester, 1980; p17."},{"key":"ref27\/cit27","unstructured":"Smith, M. B. and March, J.March\u2019s Advanced Organic Chemistry, 5th ed.Wiley:New York, 2001; p24."},{"key":"ref28\/cit28","unstructured":"As the atomic number increases, the p-block elements display a preference for an oxidation state that is two less than the total number of available valence electrons thereby giving the appearance of increasing stability of the s-electrons (also known as the inert pair effect). This is the result of several factors which are discussed inKutzelnigg, W.Angew. Chem. Int. Ed.1984,23,272. See also:Hall, M. B.Inorg. Chem.1978,17,2261."},{"key":"ref29\/cit29","first-page":"2835","volume":"18","author":"Robiette A. G.","year":"1970","journal-title":"J. Chem. Soc. A"},{"key":"ref30\/cit30","doi-asserted-by":"crossref","first-page":"121","DOI":"10.1016\/S0020-1693(00)85012-4","volume":"201","author":"Chorley R. W.","year":"1992","journal-title":"Inorg. Chim. Acta"},{"key":"ref31\/cit31","doi-asserted-by":"crossref","first-page":"16197","DOI":"10.1021\/ja076453m","volume":"29","author":"Rivard E.","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"ref32\/cit32","doi-asserted-by":"crossref","first-page":"451","DOI":"10.1021\/ja00314a049","volume":"106","author":"Kubas G. J.","year":"1984","journal-title":"J. Am. Chem. Soc."},{"key":"ref33\/cit33","doi-asserted-by":"crossref","first-page":"2948","DOI":"10.1039\/b204299a","author":"Weinert C. S.","year":"2002","journal-title":"J. Chem. Soc., Dalton. Trans."}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/ja9068408","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,3,7]],"date-time":"2023-03-07T17:43:38Z","timestamp":1678211018000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/ja9068408"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2009,10,16]]},"references-count":35,"journal-issue":{"issue":"44","published-print":{"date-parts":[[2009,11,11]]}},"alternative-id":["10.1021\/ja9068408"],"URL":"https:\/\/doi.org\/10.1021\/ja9068408","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2009,10,16]]}}}