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Commun."},{"key":"ref12\/cit12","unstructured":"For other representative studies, see:"},{"key":"ref12\/cit12a","doi-asserted-by":"crossref","first-page":"143","DOI":"10.1007\/430_031","volume":"120","author":"Rabinovich D.","year":"2006","journal-title":"Struct. Bonding (Berlin)"},{"key":"ref12\/cit12b","doi-asserted-by":"crossref","first-page":"4751","DOI":"10.1039\/b712138e","author":"Vahrenkamp H.","year":"2007","journal-title":"Dalton Trans."},{"key":"ref13\/cit13","unstructured":"The structure of [TmBut]HgSPh has also been obtained at a higher temperature (243 K) than described here (170 K). See ref10."},{"key":"ref14\/cit14","doi-asserted-by":"crossref","first-page":"1247","DOI":"10.1016\/S0277-5387(00)84671-9","volume":"3","author":"Christou G.","year":"1984","journal-title":"Polyhedron"},{"key":"ref15\/cit15","doi-asserted-by":"crossref","first-page":"784","DOI":"10.1002\/(SICI)1521-3749(200003)626:3<784::AID-ZAAC784>3.0.CO;2-H","volume":"626","author":"Lang E. 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News"},{"key":"ref31\/cit31","doi-asserted-by":"crossref","first-page":"1286","DOI":"10.1039\/j19710001286","author":"Cameron A. F.","year":"1971","journal-title":"J. Chem. Soc. (A)"},{"key":"ref32\/cit32","doi-asserted-by":"crossref","first-page":"S94","DOI":"10.1002\/mrc.1260291318","volume":"29","author":"Kessler J. M.","year":"1991","journal-title":"Magn. Reson. Chem."},{"key":"ref33\/cit33","doi-asserted-by":"crossref","first-page":"179","DOI":"10.1107\/S0108768187010590","volume":"44","author":"Lobana T. S.","year":"1988","journal-title":"Acta Crystallogr."},{"key":"ref34\/cit34","first-page":"71","volume":"9","author":"F\u00e4lth L.","year":"1976","journal-title":"Chem. Scripta"},{"key":"ref35\/cit35","unstructured":"Although it is well known that M\u2190L dative bonds are very sensitive to the environment of the acceptor atom (Haaland, A.Angew. Chem., Int. Ed. Engl.1989,28, 992\u22121007), the observation of two trends in bond lengths for both [TmBut]MEPh and (Ph3P)2MX2cannot simply be ascribed to the normal covalentversusdative covalent nature of the metal-ligand interactions because these two series of compounds exhibit opposite trends. For example, while the Cd-Cl bond of (Ph3P)2CdCl2is shorter than the Hg-Cl bond of (Ph3P)2HgCl2, the Hg-EPh bonds of [TmBut]HgEPh are shorter than the Cd-EPh bonds of [TmBut]CdEPh. Correspondingly, while the dative Cd-P bonds of (Ph3P)2CdCl2are longer than the Hg-P bonds of (Ph3P)2HgCl2, the Cd-[TmBut] bonds of [TmBut]CdEPh (which possess a 2\/3 dative component) are shorter than the Hg-[TmBut] bonds of [TmBut]HgEPh."},{"key":"ref36\/cit36","unstructured":"Using the standard deviation as an indication of the experimental error in the measurement of the M-E bond length, the errors associated with the differences in Hg-EPh and Cd-EPh bond lengths (Table 1) are estimated to be 0.010 \u00b1 0.001 (S), 0.035 \u00b1 0.001 (Se), and 0.057 \u00b1 0.014 (Te), while the differences in Hg-EPh and Zn-EPh bond lengths are estimated to be 0.177 \u00b1 0.001 (S), 0.130 \u00b1 0.001 (Se), 0.085 \u00b1 0.014 (Te)."},{"key":"ref37\/cit37","unstructured":"Chalcogen covalent radii: S (1.05 \u00c5), Se (1.20 \u00c5), Te (1.38 \u00c5). See ref19."},{"key":"ref38\/cit38","unstructured":"It must be emphasized that this description of the structural changes are relative to the sulfur system and are not absolute. If one were to normalize all values relative to the tellurium system, one would simply conclude that the M\u2212SPh and M\u2212SePh bonds are longer than predicted on the basis of the change in covalent radii of the chalcogens. These are merely different ways of describing the same situation, i.e., the M\u2212EPh bond lengths do not scale equally with the covalent radii of the chalcogens, with the M\u2212TePh bonds being relatively shorter and the M\u2212SPh bonds being relatively longer than expected."},{"key":"ref39\/cit39","doi-asserted-by":"crossref","first-page":"5900","DOI":"10.1021\/ic00127a031","volume":"34","author":"Howard W. A.","year":"1995","journal-title":"Inorg. Chem."},{"key":"ref40\/cit40","doi-asserted-by":"crossref","first-page":"29","DOI":"10.1021\/ic701618a","volume":"47","author":"Gaunt A. 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