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We report here a general solution to this challenge catalyzed by a combination of Ni and Pd with Zn reductant and LiBr as an additive. The reaction has broad scope, as demonstrated in 33 examples (65% \u00b1 11% average yield). Mechanistic studies show that Pd strongly prefers the aryl triflate, the Ni catalyst has a small preference for the aryl tosylate, aryl transfer between catalysts is mediated by Zn, and Pd improves yields by consuming arylzinc intermediates.<\/jats:p>","DOI":"10.1021\/jacs.0c04670","type":"journal-article","created":{"date-parts":[[2020,6,2]],"date-time":"2020-06-02T22:17:25Z","timestamp":1591136245000},"page":"10634-10640","source":"Crossref","is-referenced-by-count":111,"title":["Sulfonate\nVersus Sulfonate: Nickel and Palladium Multimetallic\nCross-Electrophile Coupling of Aryl Triflates with Aryl Tosylates"],"prefix":"10.1021","volume":"142","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7625-1661","authenticated-orcid":true,"given":"Kai","family":"Kang","sequence":"first","affiliation":[{"name":"University of Wisconsin-Madison , , ,","place":["Madison, Wisconsin, United States, 53706"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9450-9454","authenticated-orcid":true,"given":"Liangbin","family":"Huang","sequence":"additional","affiliation":[{"name":"South China University of Technology , , , ,","place":["Guangzhou, People\u2019s Republic of China, 510641"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9552-3378","authenticated-orcid":true,"given":"Daniel J.","family":"Weix","sequence":"additional","affiliation":[{"name":"University of Wisconsin-Madison , , ,","place":["Madison, Wisconsin, United States, 53706"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2020,6,2]]},"reference":[{"key":"2026081721085157900_cit1a","doi-asserted-by":"publisher","first-page":"2337","DOI":"10.1039\/b602413k","article-title":"Analysis of\nthe Reactions Used for the Preparation of Drug Candidate Molecules","volume":"4","author":"Carey","year":"2006","journal-title":"Org. 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Source: eMolecules\ndatabase, accessed 2018-07-18 using Elsevier REAXYS."},{"key":"2026081721085157900_cit5a","doi-asserted-by":"crossref","DOI":"10.1002\/9783527619467","volume-title":"Handbook\nof Functionalized Organometallics: Applications in Synthesis","author":"Knochel","year":"2005"},{"key":"2026081721085157900_cit5b","doi-asserted-by":"publisher","first-page":"890","DOI":"10.1021\/cr900206p","article-title":"C-H Activation\nfor the Construction of C-B Bonds","volume":"110","author":"Mkhalid","year":"2010","journal-title":"Chem. Rev."},{"key":"2026081721085157900_cit5c","doi-asserted-by":"publisher","first-page":"4253","DOI":"10.1021\/jo500297r","article-title":"Strategies\nto Prepare and Use Functionalized Organometallic Reagents","volume":"79","author":"Klatt","year":"2014","journal-title":"J. Org. 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