{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T15:51:32Z","timestamp":1791474692008,"version":"4.3.4"},"reference-count":56,"publisher":"American Chemical Society (ACS)","issue":"36","license":[{"start":{"date-parts":[[2021,9,3]],"date-time":"2021-09-03T00:00:00Z","timestamp":1630627200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2021,9,3]],"date-time":"2021-09-03T00:00:00Z","timestamp":1630627200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2021,9,3]],"date-time":"2021-09-03T00:00:00Z","timestamp":1630627200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["91956202, 21790330, 21821002"],"award-info":[{"award-number":["91956202, 21790330, 21821002"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"name":"the Science and Technology Commission of Shanghai Municipality","award":["20JC1417000, 21520780100 and 19590750400"],"award-info":[{"award-number":["20JC1417000, 21520780100 and 19590750400"]}]},{"DOI":"10.13039\/501100002367","name":"the Chinese Academy of Sciences","doi-asserted-by":"crossref","award":["XDB20000000 and QYZDJSSW-SLH055"],"award-info":[{"award-number":["XDB20000000 and QYZDJSSW-SLH055"]}],"id":[{"id":"10.13039\/501100002367","id-type":"DOI","asserted-by":"crossref"}]},{"name":"the Research Grants Council of Hong Kong","award":["HKUST 16300620"],"award-info":[{"award-number":["HKUST 16300620"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2021,9,15]]},"DOI":"10.1021\/jacs.1c07190","type":"journal-article","created":{"date-parts":[[2021,9,6]],"date-time":"2021-09-06T13:41:09Z","timestamp":1630935669000},"page":"14451-14457","source":"Crossref","is-referenced-by-count":92,"title":["Enantioselective Copper-Catalyzed Radical Cyanation of Propargylic C\u2013H Bonds: Easy Access to Chiral Allenyl Nitriles"],"prefix":"10.1021","volume":"143","author":[{"given":"Ronghua","family":"Lu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Organometallic Chemistry and Shanghai Hongkong Joint Laboratory in Chemical Synthesis, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tilong","family":"Yang","sequence":"additional","affiliation":[{"name":"Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xin","family":"Chen","sequence":"additional","affiliation":[{"name":"Chang-Kung Chuang Institute, East China Normal University, 3663 North Zhongshan Road, Shanghai 200062, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenzheng","family":"Fan","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Organometallic Chemistry and Shanghai Hongkong Joint Laboratory in Chemical Synthesis, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pinhong","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Organometallic Chemistry and Shanghai Hongkong Joint Laboratory in Chemical Synthesis, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4104-8767","authenticated-orcid":true,"given":"Zhenyang","family":"Lin","sequence":"additional","affiliation":[{"name":"Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0572-9370","authenticated-orcid":true,"given":"Guosheng","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Organometallic Chemistry and Shanghai Hongkong Joint Laboratory in Chemical Synthesis, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China"},{"name":"Chang-Kung Chuang Institute, East China Normal University, 3663 North Zhongshan Road, Shanghai 200062, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2021,9,3]]},"reference":[{"key":"ref1\/cit1a","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200300628"},{"key":"ref1\/cit1b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201108001"},{"key":"ref1\/cit1c","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201101460"},{"key":"ref2\/cit2a","doi-asserted-by":"crossref","DOI":"10.1002\/9783527619573","volume-title":"Modern Allene Chemistry","author":"Krause N.","year":"2004"},{"key":"ref2\/cit2b","doi-asserted-by":"crossref","unstructured":"bBruneau, C.; Renaud, J. L. In\n                      Allenes and Cumulenes in Comprehensive Organic Functional Group Transformations II\n                      ; Katritzky, A. R., Taylor, R. J. K., Cossy, J., Eds. Elsevier Ltd.: Oxford, 2005; Vol. 1, pp 1019\u20131081.","DOI":"10.1016\/B0-08-044655-8\/00020-9"},{"key":"ref2\/cit2c","doi-asserted-by":"publisher","DOI":"10.1021\/cr020024j"},{"key":"ref2\/cit2d","doi-asserted-by":"publisher","DOI":"10.1039\/c3cs60182j"},{"key":"ref2\/cit2e","doi-asserted-by":"publisher","DOI":"10.1021\/ar4002069"},{"key":"ref2\/cit2f","doi-asserted-by":"publisher","DOI":"10.1039\/C6QO00207B"},{"key":"ref3\/cit3a","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2004.09.094"},{"key":"ref3\/cit3b","doi-asserted-by":"publisher","DOI":"10.1055\/s-2007-965963"},{"key":"ref3\/cit3c","doi-asserted-by":"publisher","DOI":"10.1039\/C0CC05640E"},{"key":"ref3\/cit3d","doi-asserted-by":"publisher","DOI":"10.1039\/C4QO00208C"},{"key":"ref3\/cit3e","doi-asserted-by":"publisher","DOI":"10.1002\/asia.201500951"},{"key":"ref3\/cit3f","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.9b00023"},{"key":"ref3\/cit3g","doi-asserted-by":"publisher","DOI":"10.1002\/cjoc.201900277"},{"key":"ref4\/cit4a","doi-asserted-by":"publisher","DOI":"10.1021\/ja0543705"},{"key":"ref4\/cit4b","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201000301"},{"key":"ref4\/cit4c","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201204796"},{"key":"ref5\/cit5a","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200802158"},{"key":"ref5\/cit5b","doi-asserted-by":"publisher","DOI":"10.1021\/ja806602h"},{"key":"ref5\/cit5c","doi-asserted-by":"publisher","DOI":"10.1039\/C4QO00151F"},{"key":"ref5\/cit5d","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms8946"},{"key":"ref6\/cit6a","doi-asserted-by":"publisher","DOI":"10.1021\/jo802079b"},{"key":"ref6\/cit6b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201511776"},{"key":"ref7\/cit7a","doi-asserted-by":"publisher","DOI":"10.1021\/jo00118a031"},{"key":"ref7\/cit7b","doi-asserted-by":"publisher","DOI":"10.1055\/s-0029-1219542"},{"key":"ref8\/cit8a","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetasy.2008.11.039"},{"key":"ref8\/cit8b","doi-asserted-by":"publisher","DOI":"10.1021\/cs401007m"},{"key":"ref8\/cit8c","doi-asserted-by":"publisher","DOI":"10.1039\/C7CY01319A"},{"key":"ref8\/cit8d","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b08279"},{"key":"ref8\/cit8e","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b09674"},{"key":"ref8\/cit8f","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b10883"},{"key":"ref8\/cit8g","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b07582"},{"key":"ref8\/cit8h","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b02637"},{"key":"ref8\/cit8i","doi-asserted-by":"publisher","DOI":"10.1021\/ja406135t"},{"key":"ref8\/cit8j","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c02876"},{"key":"ref8\/cit8k","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(20000317)39:6<1042::AID-ANIE1042>3.0.CO;2-7"},{"key":"ref8\/cit8l","doi-asserted-by":"publisher","DOI":"10.1021\/ja401606e"},{"key":"ref9\/cit9a","doi-asserted-by":"publisher","DOI":"10.1021\/jo01362a030"},{"key":"ref9\/cit9b","doi-asserted-by":"publisher","DOI":"10.1021\/ja901528b"},{"key":"ref10\/cit10a","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.8b00265"},{"key":"ref10\/cit10b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.9b00381"},{"key":"ref11\/cit11a","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201803668"},{"key":"ref11\/cit11b","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b11499"},{"key":"ref12\/cit12a","doi-asserted-by":"publisher","DOI":"10.1126\/science.aaf7783"},{"key":"ref12\/cit12b","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b03781"},{"key":"ref12\/cit12c","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201902191"},{"key":"ref12\/cit12d","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c05373"},{"key":"ref12\/cit12e","doi-asserted-by":"publisher","DOI":"10.31635\/ccschem.020.202000435"},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-019-1655-8"},{"key":"ref14\/cit14a","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c06177"},{"key":"ref14\/cit14b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202013022"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1021\/ol016117p"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201300174"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b02338"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.1c07190","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,4,25]],"date-time":"2023-04-25T13:11:41Z","timestamp":1682428301000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.1c07190"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,9,3]]},"references-count":56,"journal-issue":{"issue":"36","published-print":{"date-parts":[[2021,9,15]]}},"alternative-id":["10.1021\/jacs.1c07190"],"URL":"https:\/\/doi.org\/10.1021\/jacs.1c07190","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2021,9,3]]}}}