{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,21]],"date-time":"2026-10-21T17:45:27Z","timestamp":1792604727444,"version":"4.5.0"},"reference-count":52,"publisher":"American Chemical Society (ACS)","issue":"46","license":[{"start":{"date-parts":[[2021,11,10]],"date-time":"2021-11-10T00:00:00Z","timestamp":1636502400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2021,11,10]],"date-time":"2021-11-10T00:00:00Z","timestamp":1636502400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2021,11,10]],"date-time":"2021-11-10T00:00:00Z","timestamp":1636502400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/100000165","name":"Division of Chemistry","doi-asserted-by":"publisher","award":["CHE-1763429"],"award-info":[{"award-number":["CHE-1763429"]}],"id":[{"id":"10.13039\/100000165","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2021,11,24]]},"DOI":"10.1021\/jacs.1c07617","type":"journal-article","created":{"date-parts":[[2021,11,10]],"date-time":"2021-11-10T14:31:44Z","timestamp":1636554704000},"page":"19389-19398","source":"Crossref","is-referenced-by-count":58,"title":["Photoredox Catalysis Mediated by Tungsten(0) Arylisocyanides"],"prefix":"10.1021","volume":"143","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0612-7953","authenticated-orcid":true,"suffix":"Jr.","given":"Javier","family":"Fajardo","sequence":"first","affiliation":[{"name":"Beckman Institute, California Institute of Technology, Pasadena, California 91125, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1813-4029","authenticated-orcid":true,"given":"Alexandra T.","family":"Barth","sequence":"additional","affiliation":[{"name":"Beckman Institute, California Institute of Technology, Pasadena, California 91125, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maryann","family":"Morales","sequence":"additional","affiliation":[{"name":"Beckman Institute, California Institute of Technology, Pasadena, California 91125, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michael K.","family":"Takase","sequence":"additional","affiliation":[{"name":"Beckman Institute, California Institute of Technology, Pasadena, California 91125, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4453-9716","authenticated-orcid":true,"given":"Jay R.","family":"Winkler","sequence":"additional","affiliation":[{"name":"Beckman Institute, California Institute of Technology, Pasadena, California 91125, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7937-7876","authenticated-orcid":true,"given":"Harry B.","family":"Gray","sequence":"additional","affiliation":[{"name":"Beckman Institute, California Institute of Technology, Pasadena, California 91125, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2021,11,10]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"publisher","DOI":"10.1021\/cr300503r"},{"key":"ref2\/cit2","doi-asserted-by":"publisher","DOI":"10.1039\/C4QI00053F"},{"key":"ref3\/cit3","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.6b01449"},{"key":"ref4\/cit4a","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.6b00250"},{"key":"ref4\/cit4b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.6b00296"},{"key":"ref4\/cit4c","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201703602"},{"key":"ref4\/cit4d","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b04094"},{"key":"ref5\/cit5a","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b05934"},{"key":"ref5\/cit5b","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-020-0430-7"},{"key":"ref6\/cit6","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.8b00336"},{"key":"ref7\/cit7","doi-asserted-by":"publisher","DOI":"10.1039\/D0SC01340D"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(00)91697-9"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1021\/ja4047119"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1021\/ja510973h"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.5b01203"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.0c02912"},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b11803"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201605571"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b07373"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.7b03258"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1021\/ja00443a083"},{"key":"ref18\/cit18","doi-asserted-by":"crossref","first-page":"44","DOI":"10.1021\/ba-1978-0168.ch003","volume-title":"Inorganic and Organometallic Photochemistry","volume":"168","author":"Gray H. B.","year":"1978"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.1021\/om00062a019"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1039\/C7DT02632C"},{"key":"ref21\/cit21a","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.0c01518"},{"key":"ref21\/cit21b","doi-asserted-by":"publisher","DOI":"10.1515\/nanoph-2020-0551"},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)82961-7"},{"key":"ref23\/cit23","unstructured":"Performing the photoredox catalysis in the presence\nof increasing\nequivalents of TMP or excess free CNDipp did not improve the conversion\nor TON (Supporting Information, Figures S54\u2013S61)."},{"key":"ref24\/cit24","unstructured":"Decreasing the W(CNDipp)6 loading below 2.5 mol % led\nto further decreases in conversion, but with similar TONs (Supporting\nInformation, Figures S62\u2013S69)."},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1021\/ja991365q"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1021\/ja9928226"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1039\/c1dt11164g"},{"key":"ref28\/cit28","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.0c00948"},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.1055\/s-0040-1705942"},{"key":"ref30\/cit30","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-018-0835-2"},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c12805"},{"key":"ref32\/cit32","doi-asserted-by":"publisher","DOI":"10.1021\/ic00152a021"},{"key":"ref33\/cit33","doi-asserted-by":"publisher","DOI":"10.1021\/ic50094a003"},{"key":"ref34\/cit34","unstructured":"The\nstructure of the related complex [ReI2(CNtBu)5][I3] is available in the Cambridge\nCrystallographic Data Centre (CCDC deposition number 1993025)."},{"key":"ref35\/cit35a","doi-asserted-by":"publisher","DOI":"10.1039\/c3973000202a"},{"key":"ref35\/cit35b","doi-asserted-by":"publisher","DOI":"10.1021\/ja00843a019"},{"key":"ref35\/cit35c","doi-asserted-by":"publisher","DOI":"10.1021\/ic50186a018"},{"key":"ref35\/cit35d","doi-asserted-by":"publisher","DOI":"10.1021\/ja00516a018"},{"key":"ref35\/cit35e","doi-asserted-by":"publisher","DOI":"10.1021\/ic50225a050"},{"key":"ref35\/cit35f","doi-asserted-by":"publisher","DOI":"10.1021\/ic50219a010"},{"key":"ref35\/cit35g","doi-asserted-by":"publisher","DOI":"10.1021\/ic00134a085"},{"key":"ref35\/cit35h","doi-asserted-by":"publisher","DOI":"10.1021\/om00061a025"},{"key":"ref36\/cit36","doi-asserted-by":"publisher","DOI":"10.1021\/ic50109a041"},{"key":"ref37\/cit37a","doi-asserted-by":"publisher","DOI":"10.1021\/ic50197a036"},{"key":"ref37\/cit37b","doi-asserted-by":"publisher","DOI":"10.1021\/ic2015868"},{"key":"ref38\/cit38","doi-asserted-by":"publisher","DOI":"10.1021\/ic00135a031"},{"key":"ref39\/cit39","unstructured":"Attempts\nto generate WI2(CNDipp)5 (i) electrochemically\nfrom W(CNDipp)6 in the presence of tetrabutylammonium iodide\nor (ii) chemically by treatment of W(CNDipp)6 with I2 in C6D6 were also unsuccessful."}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.1c07617","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,4,26]],"date-time":"2023-04-26T20:51:27Z","timestamp":1682542287000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.1c07617"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,11,10]]},"references-count":52,"journal-issue":{"issue":"46","published-print":{"date-parts":[[2021,11,24]]}},"alternative-id":["10.1021\/jacs.1c07617"],"URL":"https:\/\/doi.org\/10.1021\/jacs.1c07617","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2021,11,10]]}}}