{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,15]],"date-time":"2026-09-15T04:31:59Z","timestamp":1789446719236,"version":"build-2803163510"},"reference-count":103,"publisher":"American Chemical Society (ACS)","issue":"19","license":[{"start":{"date-parts":[[2022,5,6]],"date-time":"2022-05-06T00:00:00Z","timestamp":1651795200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2022,5,6]],"date-time":"2022-05-06T00:00:00Z","timestamp":1651795200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2022,5,6]],"date-time":"2022-05-06T00:00:00Z","timestamp":1651795200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/100000057","name":"National Institute of General Medical Sciences","doi-asserted-by":"publisher","award":["RO1 GM123062"],"award-info":[{"award-number":["RO1 GM123062"]}],"id":[{"id":"10.13039\/100000057","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2022,5,18]]},"DOI":"10.1021\/jacs.1c07656","type":"journal-article","created":{"date-parts":[[2022,5,6]],"date-time":"2022-05-06T16:03:31Z","timestamp":1651853011000},"page":"8515-8528","source":"Crossref","is-referenced-by-count":13,"title":["Electronic Structure and Reactivity of Dioxygen-Derived Aliphatic Thiolate-Ligated Fe-Peroxo and Fe(IV) Oxo Compounds"],"prefix":"10.1021","volume":"144","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3112-7816","authenticated-orcid":true,"given":"Maksym A.","family":"Dedushko","sequence":"first","affiliation":[{"name":"Department of Chemistry, University of Washington, Campus Box 351700, Seattle, Washington 98195-1700, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maria B.","family":"Greiner","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Washington, Campus Box 351700, Seattle, Washington 98195-1700, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexandra N.","family":"Downing","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Washington, Campus Box 351700, Seattle, Washington 98195-1700, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michael","family":"Coggins","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Washington, Campus Box 351700, Seattle, Washington 98195-1700, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2358-1269","authenticated-orcid":true,"given":"Julie A.","family":"Kovacs","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Washington, Campus Box 351700, Seattle, Washington 98195-1700, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2022,5,6]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b09022"},{"key":"ref2\/cit2","doi-asserted-by":"publisher","DOI":"10.1021\/bi00134a010"},{"key":"ref3\/cit3","doi-asserted-by":"publisher","DOI":"10.1038\/44400"},{"key":"ref4\/cit4","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b04065"},{"key":"ref5\/cit5","doi-asserted-by":"publisher","DOI":"10.1021\/ja071364v"},{"key":"ref6\/cit6","doi-asserted-by":"publisher","DOI":"10.1038\/42990"},{"key":"ref7\/cit7","doi-asserted-by":"publisher","DOI":"10.1021\/bi047478q"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1002\/cbic.202000743"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC03904A"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1021\/ja107514f"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1016\/j.abb.2014.11.004"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1021\/bi500767x"},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.1021\/bi400825c"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1039\/b702158e"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1016\/0304-3940(90)90814-P"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1186\/1471-2407-10-247"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1158\/1078-0432.CCR-12-3751"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1080\/15592294.2016.1241931"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.1371\/journal.pone.0144862"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1007\/s13277-015-3443-x"},{"key":"ref21\/cit21","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b12670"},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.1021\/ja111742z"},{"key":"ref23\/cit23","doi-asserted-by":"publisher","DOI":"10.1021\/ar700024g"},{"key":"ref24\/cit24","doi-asserted-by":"publisher","DOI":"10.1126\/science.1081792"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1021\/ar030160q"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1021\/cr020628n"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1038\/nature10535"},{"key":"ref28\/cit28","doi-asserted-by":"publisher","DOI":"10.1021\/ja012722b"},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200801832"},{"key":"ref30\/cit30","doi-asserted-by":"publisher","DOI":"10.1021\/ja207048h"},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1126\/science.1119092"},{"key":"ref32\/cit32","doi-asserted-by":"publisher","DOI":"10.1021\/ja1047818"},{"key":"ref33\/cit33","doi-asserted-by":"publisher","DOI":"10.1021\/ja100366c"},{"key":"ref34\/cit34","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200500485"},{"key":"ref35\/cit35","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200462631"},{"key":"ref36\/cit36","doi-asserted-by":"publisher","DOI":"10.1126\/science.299.5609.1037"},{"key":"ref37\/cit37","doi-asserted-by":"publisher","DOI":"10.1021\/ja00233a021"},{"key":"ref38\/cit38","doi-asserted-by":"publisher","DOI":"10.1021\/ja00400a075"},{"key":"ref39\/cit39","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b05274"},{"key":"ref40\/cit40","doi-asserted-by":"publisher","DOI":"10.1021\/ja043083i"},{"key":"ref41\/cit41","doi-asserted-by":"publisher","DOI":"10.1021\/ja00538a059"},{"key":"ref42\/cit42","doi-asserted-by":"publisher","DOI":"10.1039\/b913945a"},{"key":"ref43\/cit43","doi-asserted-by":"publisher","DOI":"10.1021\/ja109923a"},{"key":"ref44\/cit44","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200461527"},{"key":"ref45\/cit45","doi-asserted-by":"publisher","DOI":"10.1126\/science.1244373"},{"key":"ref46\/cit46","doi-asserted-by":"publisher","DOI":"10.1126\/science.1193478"},{"key":"ref47\/cit47","doi-asserted-by":"publisher","DOI":"10.1016\/j.cbpa.2009.02.028"},{"key":"ref48\/cit48","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c13001"},{"key":"ref49\/cit49","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b04729"},{"key":"ref50\/cit50","doi-asserted-by":"publisher","DOI":"10.1039\/C8CC06247A"},{"key":"ref51\/cit51","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms6440"},{"key":"ref52\/cit52","doi-asserted-by":"publisher","DOI":"10.1021\/ja504410s"},{"key":"ref53\/cit53","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201502367"},{"key":"ref54\/cit54","doi-asserted-by":"crossref","DOI":"10.1201\/9781420007282","volume-title":"Comprehensive Handbook of Chemical Bond Energies","author":"Luo Y.-R.","year":"2007"},{"key":"ref55\/cit55","doi-asserted-by":"publisher","DOI":"10.1021\/ic101776m"},{"key":"ref56\/cit56","doi-asserted-by":"publisher","DOI":"10.1021\/ic048818z"},{"key":"ref57\/cit57","doi-asserted-by":"publisher","DOI":"10.1021\/ar600059h"},{"key":"ref58\/cit58","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.1c00336"},{"key":"ref59\/cit59","doi-asserted-by":"publisher","DOI":"10.1021\/ja107551u"},{"key":"ref60\/cit60","doi-asserted-by":"publisher","DOI":"10.1021\/ic010221l"},{"key":"ref61\/cit61","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.0637029100"},{"key":"ref62\/cit62","unstructured":"Dedushko, M. A. Insights into Dioxygen Bond Activation and Formation by Small Biomimetic Complexes. Ph.D. Dissertation; University of Washington, 2020."},{"key":"ref63\/cit63","doi-asserted-by":"publisher","DOI":"10.1021\/ja012722b"},{"key":"ref64\/cit64","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.5b00244"},{"key":"ref65\/cit65","doi-asserted-by":"publisher","DOI":"10.1021\/ar400149m"},{"key":"ref66\/cit66","doi-asserted-by":"publisher","DOI":"10.1021\/cr9900275"},{"key":"ref67\/cit67","volume-title":"CRC Handbook of Chemistry and Physics: A Ready-Reference of Chemical and Physical Data","volume":"127","author":"Tanko J. M.","year":"2004","edition":"85"},{"key":"ref68\/cit68","doi-asserted-by":"publisher","DOI":"10.1063\/1.1732351"},{"key":"ref69\/cit69","doi-asserted-by":"publisher","DOI":"10.1021\/ic0491884"},{"key":"ref70\/cit70","volume-title":"Oxygen and Ozone","volume":"7","author":"Battino R.","year":"1981"},{"key":"ref71\/cit71","doi-asserted-by":"publisher","DOI":"10.1080\/00401706.1969.10490657"},{"key":"ref72\/cit72","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.9b02079"},{"key":"ref73\/cit73","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b03329"},{"key":"ref74\/cit74","doi-asserted-by":"publisher","DOI":"10.1039\/C2SC21400H"},{"key":"ref75\/cit75","doi-asserted-by":"publisher","DOI":"10.1021\/ic0487068"},{"key":"ref76\/cit76","doi-asserted-by":"publisher","DOI":"10.1063\/1.476193"},{"key":"ref77\/cit77","doi-asserted-by":"publisher","DOI":"10.1063\/1.1419058"},{"key":"ref78\/cit78","doi-asserted-by":"publisher","DOI":"10.1039\/C3SC52755G"},{"key":"ref79\/cit79","doi-asserted-by":"publisher","DOI":"10.1126\/science.1119092"},{"key":"ref80\/cit80","doi-asserted-by":"publisher","DOI":"10.1126\/science.1096897"},{"key":"ref81\/cit81","doi-asserted-by":"publisher","DOI":"10.1021\/ja026279w"},{"key":"ref82\/cit82","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201208044"},{"key":"ref83\/cit83","doi-asserted-by":"publisher","DOI":"10.1126\/science.287.5458.1615"},{"key":"ref84\/cit84","doi-asserted-by":"publisher","DOI":"10.1126\/science.1133417"},{"key":"ref85\/cit85","doi-asserted-by":"publisher","DOI":"10.1021\/ja063590v"},{"key":"ref86\/cit86","doi-asserted-by":"publisher","DOI":"10.1021\/ic051823y"},{"key":"ref87\/cit87","doi-asserted-by":"publisher","DOI":"10.1021\/ic3027896"},{"key":"ref88\/cit88","doi-asserted-by":"publisher","DOI":"10.1021\/ja025590a"},{"key":"ref89\/cit89","doi-asserted-by":"publisher","DOI":"10.1021\/jp014121c"},{"key":"ref90\/cit90","doi-asserted-by":"publisher","DOI":"10.1021\/ja029806k"},{"key":"ref91\/cit91","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.5b00053"},{"key":"ref92\/cit92","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2306"},{"key":"ref93\/cit93","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.0603159103"},{"key":"ref94\/cit94","doi-asserted-by":"publisher","DOI":"10.1021\/bi030011f"},{"key":"ref95\/cit95","doi-asserted-by":"publisher","DOI":"10.1021\/ja048255q"},{"key":"ref96\/cit96","doi-asserted-by":"publisher","DOI":"10.1021\/ja8022576"},{"key":"ref97\/cit97","doi-asserted-by":"publisher","DOI":"10.1021\/ar700027f"},{"key":"ref98\/cit98","doi-asserted-by":"publisher","DOI":"10.1016\/j.jinorgbio.2005.12.013"},{"key":"ref99\/cit99","doi-asserted-by":"publisher","DOI":"10.1021\/ja037288n"},{"key":"ref100\/cit100","doi-asserted-by":"publisher","DOI":"10.1021\/ic051213y"},{"key":"ref101\/cit101","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.0636830100"},{"key":"ref102\/cit102","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200502686"},{"key":"ref103\/cit103","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200900863"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.1c07656","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.1c07656","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,4,28]],"date-time":"2023-04-28T00:28:23Z","timestamp":1682641703000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.1c07656"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,5,6]]},"references-count":103,"journal-issue":{"issue":"19","published-print":{"date-parts":[[2022,5,18]]}},"alternative-id":["10.1021\/jacs.1c07656"],"URL":"https:\/\/doi.org\/10.1021\/jacs.1c07656","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,5,6]]}}}