{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T04:08:21Z","timestamp":1791346101296,"version":"4.3.1"},"reference-count":100,"publisher":"American Chemical Society (ACS)","issue":"39","license":[{"start":{"date-parts":[[2021,9,21]],"date-time":"2021-09-21T00:00:00Z","timestamp":1632182400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2021,9,21]],"date-time":"2021-09-21T00:00:00Z","timestamp":1632182400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2021,9,21]],"date-time":"2021-09-21T00:00:00Z","timestamp":1632182400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100001665","name":"Agence Nationale de la Recherche","doi-asserted-by":"publisher","award":["ICC-ANR-17-CE07-0015"],"award-info":[{"award-number":["ICC-ANR-17-CE07-0015"]}],"id":[{"id":"10.13039\/501100001665","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004718","name":"Universit?? de Toulouse","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100004718","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004794","name":"Centre National de la Recherche Scientifique","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100004794","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100013415","name":"Conseil R????gional Midi-Pyr????n????es","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100013415","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2021,10,6]]},"DOI":"10.1021\/jacs.1c07872","type":"journal-article","created":{"date-parts":[[2021,9,21]],"date-time":"2021-09-21T15:46:02Z","timestamp":1632239162000},"page":"16274-16283","source":"Crossref","is-referenced-by-count":40,"title":["Enantioselective Reductive Oligomerization of Carbon Dioxide into <scp>l<\/scp>-Erythrulose via a Chemoenzymatic Catalysis"],"prefix":"10.1021","volume":"143","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-9548-3185","authenticated-orcid":true,"given":"Sarah","family":"Desmons","sequence":"first","affiliation":[{"name":"LCC-CNRS, Universit\u00e9 de Toulouse, CNRS, F-31077 Toulouse Cedex 4, France"},{"name":"TBI, Universit\u00e9 de Toulouse, CNRS, INRAE, INSA, 31077 Toulouse, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Katie","family":"Grayson-Steel","sequence":"additional","affiliation":[{"name":"TBI, Universit\u00e9 de Toulouse, CNRS, INRAE, INSA, 31077 Toulouse, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nelson","family":"Nu\u00f1ez-Dallos","sequence":"additional","affiliation":[{"name":"LCC-CNRS, Universit\u00e9 de Toulouse, CNRS, F-31077 Toulouse Cedex 4, France"},{"name":"Department of Chemistry, Universidad de los Andes, Carrera 1 No. 18A-12, 111711 Bogot\u00e1, Colombia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Laure","family":"Vendier","sequence":"additional","affiliation":[{"name":"LCC-CNRS, Universit\u00e9 de Toulouse, CNRS, F-31077 Toulouse Cedex 4, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0511-9719","authenticated-orcid":true,"given":"John","family":"Hurtado","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Universidad de los Andes, Carrera 1 No. 18A-12, 111711 Bogot\u00e1, Colombia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5541-4794","authenticated-orcid":true,"given":"Pere","family":"Clap\u00e9s","sequence":"additional","affiliation":[{"name":"Biological Chemistry Department, Institute for Advanced Chemistry of Catalonia, IQAC-CSIC, Jordi Girona 18-26, 08034 Barcelona, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5107-9009","authenticated-orcid":true,"given":"R\u00e9gis","family":"Faur\u00e9","sequence":"additional","affiliation":[{"name":"TBI, Universit\u00e9 de Toulouse, CNRS, INRAE, INSA, 31077 Toulouse, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Claire","family":"Dumon","sequence":"additional","affiliation":[{"name":"TBI, Universit\u00e9 de Toulouse, CNRS, INRAE, INSA, 31077 Toulouse, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4950-9452","authenticated-orcid":true,"given":"S\u00e9bastien","family":"Bontemps","sequence":"additional","affiliation":[{"name":"LCC-CNRS, Universit\u00e9 de Toulouse, CNRS, F-31077 Toulouse Cedex 4, France"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2021,9,21]]},"reference":[{"key":"ref1\/cit1a","doi-asserted-by":"publisher","DOI":"10.1021\/jm900819p"},{"key":"ref1\/cit1b","doi-asserted-by":"publisher","DOI":"10.1039\/np9971400099"},{"key":"ref2\/cit2a","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jcim.9b00874"},{"key":"ref2\/cit2b","doi-asserted-by":"publisher","DOI":"10.1093\/glycob\/cwn026"},{"key":"ref2\/cit2c","doi-asserted-by":"publisher","DOI":"10.1126\/science.1059820"},{"key":"ref3\/cit3a","doi-asserted-by":"publisher","DOI":"10.1039\/C1CS15144D"},{"key":"ref3\/cit3b","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(20000103)39:1<44::AID-ANIE44>3.0.CO;2-L"},{"key":"ref3\/cit3c","doi-asserted-by":"publisher","DOI":"10.1016\/j.biotechadv.2017.01.004"},{"key":"ref4\/cit4a","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c05419"},{"key":"ref4\/cit4b","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00213K"},{"key":"ref5\/cit5","doi-asserted-by":"publisher","DOI":"10.1126\/science.1101710"},{"key":"ref6\/cit6a","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00104"},{"key":"ref6\/cit6b","doi-asserted-by":"publisher","DOI":"10.3762\/bjoc.9.281"},{"key":"ref6\/cit6c","doi-asserted-by":"publisher","DOI":"10.1007\/s10295-012-1089-x"},{"key":"ref7\/cit7a","doi-asserted-by":"publisher","DOI":"10.1046\/j.1365-2486.2001.00448.x"},{"key":"ref7\/cit7b","doi-asserted-by":"publisher","DOI":"10.1126\/science.1184984"},{"key":"ref7\/cit7c","doi-asserted-by":"publisher","DOI":"10.1098\/rstb.2008.0041"},{"key":"ref8\/cit8a","doi-asserted-by":"publisher","DOI":"10.1111\/pbi.12246"},{"key":"ref8\/cit8b","doi-asserted-by":"publisher","DOI":"10.1016\/j.copbio.2017.07.017"},{"key":"ref9\/cit9a","doi-asserted-by":"publisher","DOI":"10.1016\/j.ymben.2018.04.003"},{"key":"ref9\/cit9b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202102333"},{"key":"ref9\/cit9c","doi-asserted-by":"publisher","DOI":"10.1016\/j.cell.2016.05.064"},{"key":"ref10\/cit10a","doi-asserted-by":"publisher","DOI":"10.1021\/cr300463y"},{"key":"ref10\/cit10b","unstructured":"bCalvin, M. Nobel Lecture: The Path of Carbon in Photosynthesis. http:\/\/www.nobelprize.org\/nobel_prizes\/chemistry\/laureates\/1961\/calvin-lecture.html (accessed Thursday August 26, 2021)."},{"key":"ref10\/cit10c","doi-asserted-by":"publisher","DOI":"10.1126\/science.105.2738.648"},{"key":"ref10\/cit10d","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9258(18)56368-7"},{"key":"ref10\/cit10e","doi-asserted-by":"publisher","DOI":"10.1126\/science.109.2824.140"},{"key":"ref10\/cit10f","doi-asserted-by":"publisher","DOI":"10.1126\/science.107.2784.476"},{"key":"ref11\/cit11a","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS00218F"},{"key":"ref11\/cit11b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00435"},{"key":"ref11\/cit11c","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201507458"},{"key":"ref11\/cit11d","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00122B"},{"key":"ref11\/cit11e","doi-asserted-by":"publisher","DOI":"10.1039\/b700658f"},{"key":"ref12\/cit12","unstructured":"A NASA\nchallenge was recently launched on this specific topic. See: https:\/\/www.co2conversionchallenge.org\/#home (accessed Thursday August 26, 2021)."},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201601591"},{"key":"ref14\/cit14a","doi-asserted-by":"publisher","DOI":"10.6023\/cjoc202002032"},{"key":"ref14\/cit14b","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.7b02306"},{"key":"ref15\/cit15a","doi-asserted-by":"publisher","DOI":"10.1039\/D0GC04124F"},{"key":"ref15\/cit15b","doi-asserted-by":"publisher","DOI":"10.1002\/tcr.201600022"},{"key":"ref15\/cit15c","volume-title":"Ullmann\u2019s Encyclopedia of Industrial Chemistry","author":"Reuss G.","year":"2003"},{"key":"ref16\/cit16a","first-page":"145","volume":"53","author":"Butlerow A.","year":"1861","journal-title":"C. R. Acad. Sci., Paris"},{"key":"ref16\/cit16b","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201400040"},{"key":"ref16\/cit16c","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b03128"},{"key":"ref17\/cit17a","doi-asserted-by":"publisher","DOI":"10.1021\/cr2004844"},{"key":"ref17\/cit17b","doi-asserted-by":"publisher","DOI":"10.3390\/life3030486"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1039\/CT9211901025"},{"key":"ref19\/cit19a","doi-asserted-by":"publisher","DOI":"10.1039\/C8EE00936H"},{"key":"ref19\/cit19b","unstructured":"bA patent entitled \u201cHydrogenation\nof formic acid to formaldehyde claimed the electroreduction of CO2 into formic acid, the hydrogenation of formic acid into formaldehyde\nand the Ca-catalyzed formose reaction as a pathway to a mixture of\ncarbohydrates. See: Masel, R. I.; Ni, Z. R.; Chen, Q.; Rosen, B. A. Hydrogenation of formic acid to formaldehyde. US 9193593 B2, 2015."},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c00412"},{"key":"ref21\/cit21","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201801875"},{"key":"ref22\/cit22a","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201400349"},{"key":"ref22\/cit22b","unstructured":"bCantat, T.; Gomes, C.; Blondiaux, E.; Jacquet, O. Method for preparing oxyborane compounds for subsequent hydrolysis to give methane derivatives. WO2014162266 A1, 2014."},{"key":"ref22\/cit22c","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b06077"},{"key":"ref23\/cit23","doi-asserted-by":"publisher","DOI":"10.1021\/ja103982t"},{"key":"ref24\/cit24a","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2015.06.003"},{"key":"ref24\/cit24b","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5b00428"},{"key":"ref25\/cit25a","doi-asserted-by":"publisher","DOI":"10.1021\/ic200221a"},{"key":"ref25\/cit25b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201304025"},{"key":"ref25\/cit25c","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201107352"},{"key":"ref25\/cit25d","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b03894"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1021\/ja500708w"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.7b00497"},{"key":"ref28\/cit28","doi-asserted-by":"publisher","DOI":"10.3791\/60348"},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC03072B"},{"key":"ref30\/cit30","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201901634"},{"key":"ref31\/cit31a","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b08342"},{"key":"ref31\/cit31b","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5b00734"},{"key":"ref31\/cit31c","doi-asserted-by":"publisher","DOI":"10.1039\/C9GC04342J"},{"key":"ref31\/cit31d","doi-asserted-by":"publisher","DOI":"10.1002\/cjoc.202000521"},{"key":"ref31\/cit31e","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.0c02963"},{"key":"ref31\/cit31f","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.8b01155"},{"key":"ref31\/cit31g","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.7b01906"},{"key":"ref32\/cit32a","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201612462"},{"key":"ref32\/cit32b","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.6b00758"},{"key":"ref32\/cit32c","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201100655"},{"key":"ref32\/cit32d","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b09348"},{"key":"ref33\/cit33a","doi-asserted-by":"publisher","DOI":"10.1074\/jbc.M008061200"},{"key":"ref33\/cit33b","doi-asserted-by":"publisher","DOI":"10.1002\/cbic.201800135"},{"key":"ref33\/cit33c","first-page":"31","volume-title":"Biocatalysis in Organic Synthesis","volume":"2","author":"Clap\u00e9s P.","year":"2015"},{"key":"ref34\/cit34","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2321"},{"key":"ref35\/cit35a","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.1500545112"},{"key":"ref35\/cit35b","doi-asserted-by":"publisher","DOI":"10.1002\/cbic.201500228"},{"key":"ref36\/cit36a","doi-asserted-by":"publisher","DOI":"10.1016\/j.cbpa.2020.02.004"},{"key":"ref36\/cit36b","doi-asserted-by":"publisher","DOI":"10.1021\/cs400633a"},{"key":"ref37\/cit37","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-017-0010-4"},{"key":"ref38\/cit38","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201804612"},{"key":"ref39\/cit39","doi-asserted-by":"publisher","DOI":"10.1039\/C9DT04749B"},{"key":"ref42\/cit42","doi-asserted-by":"publisher","DOI":"10.1111\/febs.14696"},{"key":"ref43\/cit43","doi-asserted-by":"publisher","DOI":"10.1016\/j.bioorg.2006.09.002"},{"key":"ref45\/cit45b","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.200900772"},{"key":"ref46\/cit46","doi-asserted-by":"publisher","DOI":"10.1039\/C7CY01062A"},{"key":"ref47\/cit47a","doi-asserted-by":"publisher","DOI":"10.1016\/j.biortech.2017.09.168"},{"key":"ref47\/cit47b","doi-asserted-by":"publisher","DOI":"10.1002\/open.201700201"},{"key":"ref48\/cit48","doi-asserted-by":"publisher","DOI":"10.1126\/science.aah5237"},{"key":"ref49\/cit49a","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(88)80660-0"},{"key":"ref49\/cit49b","doi-asserted-by":"publisher","DOI":"10.1021\/ja00072a016"},{"key":"ref49\/cit49c","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b00895"},{"key":"ref50\/cit50a","doi-asserted-by":"publisher","DOI":"10.1021\/ja00808a057"},{"key":"ref50\/cit50b","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(03)00316-4"},{"key":"ref51\/cit51","doi-asserted-by":"publisher","DOI":"10.1021\/ic00262a015"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.1c07872","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,4,25]],"date-time":"2023-04-25T21:34:44Z","timestamp":1682458484000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.1c07872"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,9,21]]},"references-count":100,"journal-issue":{"issue":"39","published-print":{"date-parts":[[2021,10,6]]}},"alternative-id":["10.1021\/jacs.1c07872"],"URL":"https:\/\/doi.org\/10.1021\/jacs.1c07872","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2021,9,21]]}}}