{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,8]],"date-time":"2026-04-08T10:36:12Z","timestamp":1775644572558,"version":"3.50.1"},"reference-count":66,"publisher":"American Chemical Society (ACS)","issue":"1","license":[{"start":{"date-parts":[[2021,12,28]],"date-time":"2021-12-28T00:00:00Z","timestamp":1640649600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2021,12,28]],"date-time":"2021-12-28T00:00:00Z","timestamp":1640649600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2021,12,28]],"date-time":"2021-12-28T00:00:00Z","timestamp":1640649600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/100000054","name":"National Cancer Institute","doi-asserted-by":"publisher","award":["CA042056"],"award-info":[{"award-number":["CA042056"]}],"id":[{"id":"10.13039\/100000054","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2022,1,12]]},"DOI":"10.1021\/jacs.1c10971","type":"journal-article","created":{"date-parts":[[2021,12,29]],"date-time":"2021-12-29T01:11:12Z","timestamp":1640740272000},"page":"495-502","source":"Crossref","is-referenced-by-count":11,"title":["Tris(4-bromophenyl)aminium Hexachloroantimonate-Mediated Intermolecular C(sp<sup>2<\/sup>)\u2013C(sp<sup>3<\/sup>) Free Radical Coupling of Vindoline with \u03b2-Ketoesters and Related Compounds"],"prefix":"10.1021","volume":"144","author":[{"given":"Jiajun","family":"Zhang","sequence":"first","affiliation":[{"name":"Department of Chemistry and The Skaggs Institute for Chemical Biology, The Scripps Research Institute, 10550 N. Torrey Pines Road, La Jolla, California 92037, United States"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Srinivas R.","family":"Paladugu","sequence":"additional","affiliation":[{"name":"Department of Chemistry and The Skaggs Institute for Chemical Biology, The Scripps Research Institute, 10550 N. Torrey Pines Road, La Jolla, California 92037, United States"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Rachel M.","family":"Gillard","sequence":"additional","affiliation":[{"name":"Department of Chemistry and The Skaggs Institute for Chemical Biology, The Scripps Research Institute, 10550 N. Torrey Pines Road, La Jolla, California 92037, United States"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Anindya","family":"Sarkar","sequence":"additional","affiliation":[{"name":"Department of Chemistry and The Skaggs Institute for Chemical Biology, The Scripps Research Institute, 10550 N. Torrey Pines Road, La Jolla, California 92037, United States"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3966-3317","authenticated-orcid":true,"given":"Dale L.","family":"Boger","sequence":"additional","affiliation":[{"name":"Department of Chemistry and The Skaggs Institute for Chemical Biology, The Scripps Research Institute, 10550 N. Torrey Pines Road, La Jolla, California 92037, United States"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"316","published-online":{"date-parts":[[2021,12,28]]},"reference":[{"key":"ref1\/cit1a","first-page":"1","volume-title":"The Alkaloids: Chemistry and Pharmacology","volume":"37","author":"Blask\u00d3 G.","year":"1990"},{"key":"ref1\/cit1b","first-page":"77","volume-title":"The Alkaloids: Chemistry and Pharmacology","volume":"37","author":"Kuehne M. E.","year":"1990"},{"key":"ref1\/cit1c","first-page":"133","volume-title":"The Alkaloids: Chemistry and Pharmacology","volume":"37","author":"Borman L. S.","year":"1990"},{"key":"ref1\/cit1d","first-page":"145","volume-title":"The Alkaloids: Chemistry and Pharmacology","volume":"37","author":"Pearce H. L.","year":"1990"},{"key":"ref1\/cit1e","first-page":"205","volume-title":"The Alkaloids: Chemistry and Pharmacology","volume":"37","author":"McCormack J. J.","year":"1990"},{"key":"ref1\/cit1f","first-page":"229","volume-title":"The Alkaloids: Chemistry and Pharmacology","volume":"37","author":"Neuss N.","year":"1990"},{"key":"ref2\/cit2a","doi-asserted-by":"publisher","DOI":"10.1111\/j.1749-6632.1958.tb54906.x"},{"key":"ref2\/cit2b","doi-asserted-by":"publisher","DOI":"10.1002\/jps.3030481115"},{"key":"ref3\/cit3a","doi-asserted-by":"publisher","DOI":"10.1021\/ja106284s"},{"key":"ref3\/cit3b","doi-asserted-by":"publisher","DOI":"10.1021\/ja1027748"},{"key":"ref3\/cit3c","doi-asserted-by":"publisher","DOI":"10.1021\/jm3014376"},{"key":"ref3\/cit3d","doi-asserted-by":"publisher","DOI":"10.1021\/ol402549n"},{"key":"ref3\/cit3e","doi-asserted-by":"publisher","DOI":"10.1039\/C6SC04146A"},{"key":"ref4\/cit4a","doi-asserted-by":"publisher","DOI":"10.2174\/1381612013397483"},{"key":"ref4\/cit4b","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b04330"},{"key":"ref5\/cit5a","doi-asserted-by":"publisher","DOI":"10.1039\/C39750000670"},{"key":"ref5\/cit5b","doi-asserted-by":"publisher","DOI":"10.1021\/ja00438a046"},{"key":"ref5\/cit5c","doi-asserted-by":"publisher","DOI":"10.1021\/ja00502a072"},{"key":"ref5\/cit5d","doi-asserted-by":"publisher","DOI":"10.1021\/np50007a004"},{"key":"ref6\/cit6a","doi-asserted-by":"publisher","DOI":"10.1002\/hlca.19760590824"},{"key":"ref6\/cit6b","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(01)85824-5"},{"key":"ref6\/cit6c","doi-asserted-by":"publisher","DOI":"10.1021\/ar00034a007"},{"key":"ref7\/cit7a","doi-asserted-by":"publisher","DOI":"10.1021\/jo00002a008"},{"key":"ref7\/cit7b","doi-asserted-by":"publisher","DOI":"10.1021\/jo00032a029"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1021\/ja00178a079"},{"key":"ref9\/cit9a","doi-asserted-by":"publisher","DOI":"10.1021\/ja0177049"},{"key":"ref9\/cit9b","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.0401323101"},{"key":"ref10\/cit10a","doi-asserted-by":"publisher","DOI":"10.1021\/ja078192m"},{"key":"ref10\/cit10b","doi-asserted-by":"publisher","DOI":"10.1021\/ja809842b"},{"key":"ref10\/cit10c","doi-asserted-by":"publisher","DOI":"10.1021\/ja306229x"},{"key":"ref10\/cit10d","doi-asserted-by":"publisher","DOI":"10.1021\/ar500400w"},{"key":"ref11\/cit11a","doi-asserted-by":"publisher","DOI":"10.1039\/C6SC00932H"},{"key":"ref11\/cit11b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.7b03694"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1021\/jo00195a035"},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.1021\/ol400135n"},{"key":"ref14\/cit14a","doi-asserted-by":"publisher","DOI":"10.1021\/ja00088a003"},{"key":"ref14\/cit14b","doi-asserted-by":"publisher","DOI":"10.1021\/jo000953f"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b06968"},{"key":"ref16\/cit16a","doi-asserted-by":"publisher","DOI":"10.1021\/ja00393a061"},{"key":"ref16\/cit16b","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1099-1395(199608)9:8<529::AID-POC813>3.0.CO;2-1"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1021\/ja00341a060"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1016\/0040-4039(95)00721-N"},{"key":"ref19\/cit19a","doi-asserted-by":"publisher","DOI":"10.1002\/047084289X.rt397.pub2"},{"key":"ref19\/cit19b","doi-asserted-by":"publisher","DOI":"10.1039\/j39690002719"},{"key":"ref20\/cit20a","doi-asserted-by":"publisher","DOI":"10.1021\/ol990735c"},{"key":"ref20\/cit20b","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b09690"},{"key":"ref21\/cit21a","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.5b00244"},{"key":"ref21\/cit21b","doi-asserted-by":"publisher","DOI":"10.1021\/jo401018v"},{"key":"ref21\/cit21c","doi-asserted-by":"publisher","DOI":"10.1055\/s-0035-1560509"},{"key":"ref22\/cit22a","doi-asserted-by":"publisher","DOI":"10.1007\/3-540-17871-6_11"},{"key":"ref22\/cit22b","doi-asserted-by":"publisher","DOI":"10.1021\/cr940053x"},{"key":"ref23\/cit23","doi-asserted-by":"publisher","DOI":"10.1021\/jo00109a016"},{"key":"ref24\/cit24","doi-asserted-by":"publisher","DOI":"10.1039\/C9OB00901A"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1126\/science.aba2419"},{"key":"ref26\/cit26a","doi-asserted-by":"publisher","DOI":"10.1039\/j29700000227"},{"key":"ref26\/cit26b","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(01)01078-4"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-021-00284-3"},{"key":"ref29\/cit29a","doi-asserted-by":"publisher","DOI":"10.1055\/s-0035-1561320"},{"key":"ref29\/cit29b","doi-asserted-by":"publisher","DOI":"10.1021\/ol101146f"},{"key":"ref29\/cit29c","doi-asserted-by":"publisher","DOI":"10.1021\/ol902703k"},{"key":"ref30\/cit30a","doi-asserted-by":"publisher","DOI":"10.1021\/ol7026416"},{"key":"ref30\/cit30b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.5b02222"},{"key":"ref30\/cit30c","doi-asserted-by":"publisher","DOI":"10.1039\/c3ob42454e"},{"key":"ref30\/cit30d","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-018-06020-8"},{"key":"ref30\/cit30e","doi-asserted-by":"publisher","DOI":"10.1039\/D0QO01609H"},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201409694"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.1c10971","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,4,26]],"date-time":"2023-04-26T22:37:25Z","timestamp":1682548645000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.1c10971"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,12,28]]},"references-count":66,"journal-issue":{"issue":"1","published-print":{"date-parts":[[2022,1,12]]}},"alternative-id":["10.1021\/jacs.1c10971"],"URL":"https:\/\/doi.org\/10.1021\/jacs.1c10971","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2021,12,28]]}}}