{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,9]],"date-time":"2026-10-09T21:22:51Z","timestamp":1791580971220,"version":"4.3.4"},"reference-count":41,"publisher":"American Chemical Society (ACS)","issue":"10","license":[{"start":{"date-parts":[[2022,3,7]],"date-time":"2022-03-07T00:00:00Z","timestamp":1646611200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2022,3,7]],"date-time":"2022-03-07T00:00:00Z","timestamp":1646611200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2022,3,7]],"date-time":"2022-03-07T00:00:00Z","timestamp":1646611200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/100000165","name":"Division of Chemistry","doi-asserted-by":"publisher","award":["NSF1531940"],"award-info":[{"award-number":["NSF1531940"]}],"id":[{"id":"10.13039\/100000165","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000997","name":"Arnold and Mabel Beckman Foundation","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100000997","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100004341","name":"Dow Chemical Company","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100004341","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000057","name":"National Institute of General Medical Sciences","doi-asserted-by":"publisher","award":["R01GM109194"],"award-info":[{"award-number":["R01GM109194"]}],"id":[{"id":"10.13039\/100000057","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100007633","name":"Korea Foundation for Advanced Studies","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100007633","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2022,3,16]]},"DOI":"10.1021\/jacs.1c12749","type":"journal-article","created":{"date-parts":[[2022,3,7]],"date-time":"2022-03-07T13:01:06Z","timestamp":1646658066000},"page":"4550-4558","source":"Crossref","is-referenced-by-count":118,"title":["Photoinduced, Copper-Catalyzed Enantioconvergent Alkylations of Anilines by Racemic Tertiary Electrophiles: Synthesis and Mechanism"],"prefix":"10.1021","volume":"144","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6109-5742","authenticated-orcid":true,"given":"Hyungdo","family":"Cho","sequence":"first","affiliation":[{"name":"Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9444-7254","authenticated-orcid":true,"given":"Hidehiro","family":"Suematsu","sequence":"additional","affiliation":[{"name":"Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8761-4667","authenticated-orcid":true,"given":"Paul H.","family":"Oyala","sequence":"additional","affiliation":[{"name":"Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6610-4414","authenticated-orcid":true,"given":"Jonas C.","family":"Peters","sequence":"additional","affiliation":[{"name":"Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0927-680X","authenticated-orcid":true,"given":"Gregory C.","family":"Fu","sequence":"additional","affiliation":[{"name":"Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2022,3,7]]},"reference":[{"key":"ref1\/cit1","volume-title":"Amino Group Chemistry: From Synthesis to the Life Sciences","author":"Ricci A.","year":"2008"},{"key":"ref2\/cit2","volume-title":"Amines: Synthesis, Properties, and Applications","author":"Lawrence S. A.","year":"2004"},{"key":"ref3\/cit3","volume-title":"The Alkaloids","volume":"84","author":"Kn\u00f6lker H.-J.","year":"2020"},{"key":"ref4\/cit4","doi-asserted-by":"crossref","DOI":"10.1002\/9780470871737","volume-title":"The Chemistry of Anilines","author":"Rappoport Z.","year":"2007"},{"key":"ref5\/cit5","first-page":"34","volume-title":"Comprehensive Organic Synthesis","volume":"6","author":"Marvin C. C.","year":"2014","edition":"2"},{"key":"ref6\/cit6","doi-asserted-by":"crossref","DOI":"10.1016\/B978-0-12-812284-6.00001-9","volume-title":"Catalytic Amination for N-Alkyl Amine Synthesis","author":"Shi F.","year":"2018"},{"key":"ref7\/cit7","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201301202"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1021\/ja4126609"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.6b00187"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b09582"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b10907"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2021.05.005"},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-021-00652-8"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1055\/s-0035-1562090"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1021\/ol5007423"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1126\/science.aad8313"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b07875"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c07726"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.1126\/science.aau7797"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-13886-9"},{"key":"ref21\/cit21","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-021-03730-w"},{"key":"ref22\/cit22","unstructured":"Colburn, R. W.; Dax, S. L.; Flores, C. M.; Ludovici, D. W.; Matthews, J. M.; Xia, M.; Xu, X.; Youngman, M. A.; Zhu, B. Cold Menthol Receptor Antagonists. US Patent US20120136006 A1, 2010."},{"key":"ref23\/cit23","doi-asserted-by":"publisher","DOI":"10.2147\/DDDT.S172512"},{"key":"ref24\/cit24","doi-asserted-by":"publisher","DOI":"10.1021\/ol5007423"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c03182"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202100829"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2018.01.005"},{"key":"ref28\/cit28","doi-asserted-by":"publisher","DOI":"10.1021\/cr200057t"},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.202100292"},{"key":"ref30\/cit30","doi-asserted-by":"publisher","DOI":"10.1021\/ol005636+"},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2016.10.012"},{"key":"ref32\/cit32","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201800592"},{"key":"ref33\/cit33","doi-asserted-by":"publisher","DOI":"10.1021\/ja047704j"},{"key":"ref34\/cit34","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201703400"},{"key":"ref35\/cit35","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b07124"},{"key":"ref38\/cit38","volume-title":"EPR Spectroscopy: Fundamentals and Methods","author":"Goldfarb D.","year":"2018"},{"key":"ref39\/cit39","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202013119"},{"key":"ref40\/cit40","doi-asserted-by":"publisher","DOI":"10.1515\/zpch-2016-0815"},{"key":"ref41\/cit41","doi-asserted-by":"publisher","DOI":"10.1063\/1.436479"},{"key":"ref42\/cit42","doi-asserted-by":"publisher","DOI":"10.1021\/ja809834k"},{"key":"ref44\/cit44","doi-asserted-by":"publisher","DOI":"10.1021\/ja5026547"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.1c12749","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,4,25]],"date-time":"2023-04-25T19:05:53Z","timestamp":1682449553000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.1c12749"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,3,7]]},"references-count":41,"journal-issue":{"issue":"10","published-print":{"date-parts":[[2022,3,16]]}},"alternative-id":["10.1021\/jacs.1c12749"],"URL":"https:\/\/doi.org\/10.1021\/jacs.1c12749","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,3,7]]}}}