{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,28]],"date-time":"2026-10-28T07:57:50Z","timestamp":1793174270723,"version":"4.5.0"},"reference-count":127,"publisher":"American Chemical Society (ACS)","issue":"19","license":[{"start":{"date-parts":[[2022,5,3]],"date-time":"2022-05-03T00:00:00Z","timestamp":1651536000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2022,5,3]],"date-time":"2022-05-03T00:00:00Z","timestamp":1651536000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2022,5,3]],"date-time":"2022-05-03T00:00:00Z","timestamp":1651536000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/100000928","name":"Welch Foundation","doi-asserted-by":"publisher","award":["F-0038"],"award-info":[{"award-number":["F-0038"]}],"id":[{"id":"10.13039\/100000928","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000057","name":"National Institute of General Medical Sciences","doi-asserted-by":"publisher","award":["RO1-GM069445"],"award-info":[{"award-number":["RO1-GM069445"]}],"id":[{"id":"10.13039\/100000057","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2022,5,18]]},"DOI":"10.1021\/jacs.2c03614","type":"journal-article","created":{"date-parts":[[2022,5,3]],"date-time":"2022-05-03T19:00:02Z","timestamp":1651604402000},"page":"8861-8869","source":"Crossref","is-referenced-by-count":38,"title":["Stereo- and Site-Selective Conversion of Primary Alcohols to Allylic Alcohols via Ruthenium-Catalyzed Hydrogen Auto-Transfer Mediated by 2-Butyne"],"prefix":"10.1021","volume":"144","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7349-6081","authenticated-orcid":true,"given":"Eliezer","family":"Ortiz","sequence":"first","affiliation":[{"name":"University of Texas at Austin, Department of Chemistry, 105 East 24th Street, Austin, Texas 78712, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1000-135X","authenticated-orcid":true,"given":"Yu-Hsiang","family":"Chang","sequence":"additional","affiliation":[{"name":"University of Texas at Austin, Department of Chemistry, 105 East 24th Street, Austin, Texas 78712, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4865-5973","authenticated-orcid":true,"given":"Jonathan Z.","family":"Shezaf","sequence":"additional","affiliation":[{"name":"University of Texas at Austin, Department of Chemistry, 105 East 24th Street, Austin, Texas 78712, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6345-3371","authenticated-orcid":true,"given":"Weijia","family":"Shen","sequence":"additional","affiliation":[{"name":"University of Texas at Austin, Department of Chemistry, 105 East 24th Street, Austin, Texas 78712, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8418-9709","authenticated-orcid":true,"given":"Michael J.","family":"Krische","sequence":"additional","affiliation":[{"name":"University of Texas at Austin, Department of Chemistry, 105 East 24th Street, Austin, Texas 78712, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2022,5,3]]},"reference":[{"key":"ref1\/cit1a","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199100491"},{"key":"ref1\/cit1b","first-page":"911","volume-title":"Comprehensive Asymmetric Catalysis I\u2013III","volume":"2","author":"Soai K.","year":"1999"},{"key":"ref1\/cit1c","doi-asserted-by":"publisher","DOI":"10.1021\/cr000411y"},{"key":"ref1\/cit1d","doi-asserted-by":"publisher","DOI":"10.1021\/cr020050h"},{"key":"ref1\/cit1e","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.200800776"},{"key":"ref1\/cit1f","volume-title":"Comprehensive Organic Synthesis","volume":"1","author":"Knochel P.","year":"2014","edition":"2"},{"key":"ref2\/cit2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jmedchem.6b00153"},{"key":"ref3\/cit3","first-page":"484","volume":"6","author":"Butlerov A.","year":"1863","journal-title":"Z. Chem. Pharm."},{"key":"ref4\/cit4","first-page":"37","volume":"27","author":"Lewis D. E.","year":"2002","journal-title":"Bull. Hist. Chem."},{"key":"ref5\/cit5","first-page":"1322","volume":"130","author":"Grignard V.","year":"1900","journal-title":"C R Hebd Seances Acad. Sci, Ser. C \u0301"},{"key":"ref6\/cit6a","doi-asserted-by":"publisher","DOI":"10.1016\/0950-4230(94)80059-6"},{"key":"ref6\/cit6b","first-page":"141","volume":"107","author":"Smith J. K.","year":"2000","journal-title":"Chem. Eng."},{"key":"ref6\/cit6c","doi-asserted-by":"publisher","DOI":"10.1016\/S1074-9098(02)00295-2"},{"key":"ref6\/cit6d","doi-asserted-by":"publisher","DOI":"10.1021\/op060145b"},{"key":"ref6\/cit6e","doi-asserted-by":"publisher","DOI":"10.1016\/j.ces.2007.01.013"},{"key":"ref6\/cit6f","doi-asserted-by":"publisher","DOI":"10.1021\/cen-v087n031.p029"},{"key":"ref6\/cit6g","doi-asserted-by":"publisher","DOI":"10.1016\/j.jchas.2010.03.001"},{"key":"ref6\/cit6h","doi-asserted-by":"publisher","DOI":"10.1021\/op500161b"},{"key":"ref6\/cit6i","doi-asserted-by":"publisher","DOI":"10.1021\/acs.oprd.8b00151"},{"key":"ref6\/cit6j","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-019-0375-x"},{"key":"ref6\/cit6k","doi-asserted-by":"publisher","DOI":"10.1021\/acs.oprd.1c00015"},{"key":"ref6\/cit6l","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chas.0c00092"},{"key":"ref7\/cit7a","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200300634"},{"key":"ref7\/cit7b","doi-asserted-by":"publisher","DOI":"10.1007\/128_2007_121"},{"key":"ref7\/cit7c","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200800904"},{"key":"ref7\/cit7d","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201402509"},{"key":"ref7\/cit7e","doi-asserted-by":"publisher","DOI":"10.1126\/science.aah5133"},{"key":"ref7\/cit7f","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00213"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c01109"},{"key":"ref9\/cit9a","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.200700324"},{"key":"ref9\/cit9b","doi-asserted-by":"publisher","DOI":"10.1055\/s-0036-1589457"},{"key":"ref9\/cit9c","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00144"},{"key":"ref10\/cit10a","doi-asserted-by":"publisher","DOI":"10.1002\/hlca.19920750114"},{"key":"ref10\/cit10b","doi-asserted-by":"publisher","DOI":"10.1021\/ja00057a064"},{"key":"ref10\/cit10c","doi-asserted-by":"publisher","DOI":"10.1039\/p19940001257"},{"key":"ref10\/cit10d","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(00)77062-6"},{"key":"ref10\/cit10e","doi-asserted-by":"publisher","DOI":"10.1016\/0040-4039(95)00351-C"},{"key":"ref10\/cit10f","doi-asserted-by":"publisher","DOI":"10.1021\/jo9811827"},{"key":"ref10\/cit10g","doi-asserted-by":"publisher","DOI":"10.1021\/jo000463n"},{"key":"ref10\/cit10h","doi-asserted-by":"publisher","DOI":"10.1021\/ol016954r"},{"key":"ref10\/cit10i","doi-asserted-by":"publisher","DOI":"10.1021\/ja027271p"},{"key":"ref10\/cit10j","doi-asserted-by":"publisher","DOI":"10.1021\/jo026551k"},{"key":"ref10\/cit10k","doi-asserted-by":"publisher","DOI":"10.1021\/ja035213d"},{"key":"ref10\/cit10l","doi-asserted-by":"publisher","DOI":"10.1021\/ol050255n"},{"key":"ref10\/cit10m","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.200606193"},{"key":"ref10\/cit10n","doi-asserted-by":"publisher","DOI":"10.1021\/ja0762285"},{"key":"ref10\/cit10o","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201007351"},{"key":"ref11\/cit11a","doi-asserted-by":"publisher","DOI":"10.1021\/ja034366y"},{"key":"ref11\/cit11b","doi-asserted-by":"publisher","DOI":"10.1021\/ol051075g"},{"key":"ref11\/cit11c","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.200505175"},{"key":"ref11\/cit11d","doi-asserted-by":"publisher","DOI":"10.1021\/ja072992f"},{"key":"ref11\/cit11e","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201410118"},{"key":"ref11\/cit11f","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b04583"},{"key":"ref11\/cit11g","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c03527"},{"key":"ref12\/cit12a","doi-asserted-by":"publisher","DOI":"10.1021\/ja056474l"},{"key":"ref12\/cit12b","doi-asserted-by":"publisher","DOI":"10.1021\/ja0664786"},{"key":"ref12\/cit12c","doi-asserted-by":"publisher","DOI":"10.1021\/ja0673027"},{"key":"ref12\/cit12d","doi-asserted-by":"publisher","DOI":"10.1021\/ol061485k"},{"key":"ref12\/cit12e","doi-asserted-by":"publisher","DOI":"10.1021\/ol7015548"},{"key":"ref13\/cit13a","doi-asserted-by":"publisher","DOI":"10.1021\/ja809456u"},{"key":"ref13\/cit13b","doi-asserted-by":"publisher","DOI":"10.1021\/ja500666h"},{"key":"ref13\/cit13c","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b04198"},{"key":"ref13\/cit13d","doi-asserted-by":"publisher","DOI":"10.1039\/D1SC02625A"},{"key":"ref14\/cit14","first-page":"83","volume-title":"Ullman\u2019s Encyclopedia of Industrial Chemistry","volume":"20","author":"Weitz H. M.","year":"2012"},{"key":"ref15\/cit15a","doi-asserted-by":"publisher","DOI":"10.1039\/b417466f"},{"key":"ref15\/cit15b","doi-asserted-by":"publisher","DOI":"10.1039\/c3np70076c"},{"key":"ref15\/cit15c","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b02019"},{"key":"ref15\/cit15d","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201812982"},{"key":"ref15\/cit15e","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201905532"},{"key":"ref15\/cit15f","doi-asserted-by":"publisher","DOI":"10.1039\/C9NP00070D"},{"key":"ref16\/cit16a","doi-asserted-by":"publisher","DOI":"10.1007\/128_2015_651"},{"key":"ref16\/cit16b","doi-asserted-by":"publisher","DOI":"10.1007\/128_2015_653"},{"key":"ref16\/cit16c","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00022"},{"key":"ref16\/cit16d","doi-asserted-by":"publisher","DOI":"10.1002\/ijch.201700088"},{"key":"ref16\/cit16e","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00442"},{"key":"ref17\/cit17a","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201209863"},{"key":"ref17\/cit17b","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201404065"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1023\/A:1013832630565"},{"key":"ref19\/cit19a","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b00747"},{"key":"ref19\/cit19b","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c12242"},{"key":"ref19\/cit19c","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c07857"},{"key":"ref20\/cit20a","doi-asserted-by":"publisher","DOI":"10.1039\/b410128f"},{"key":"ref20\/cit20b","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20020104)41:1<26::AID-ANIE26>3.0.CO;2-9"},{"key":"ref21\/cit21","doi-asserted-by":"publisher","DOI":"10.1021\/ja505962w"},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.1021\/jo00884a002"},{"key":"ref23\/cit23a","doi-asserted-by":"publisher","DOI":"10.1039\/c39820000348"},{"key":"ref23\/cit23b","doi-asserted-by":"publisher","DOI":"10.1021\/ja00325a030"},{"key":"ref23\/cit23c","doi-asserted-by":"publisher","DOI":"10.1021\/ol401406m"},{"key":"ref24\/cit24a","doi-asserted-by":"publisher","DOI":"10.1021\/ja00799a061"},{"key":"ref24\/cit24b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.5b00965"},{"key":"ref25\/cit25a","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200305540"},{"key":"ref25\/cit25b","doi-asserted-by":"publisher","DOI":"10.1021\/ja00346a071"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201500238"},{"key":"ref27\/cit27a","doi-asserted-by":"publisher","DOI":"10.1021\/om00142a019"},{"key":"ref27\/cit27b","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)99582-2"},{"key":"ref27\/cit27c","doi-asserted-by":"publisher","DOI":"10.1021\/om00099a014"},{"key":"ref27\/cit27d","doi-asserted-by":"publisher","DOI":"10.1039\/dt9890000589"},{"key":"ref27\/cit27e","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(90)87136-2"},{"key":"ref27\/cit27f","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(91)80124-3"},{"key":"ref27\/cit27g","doi-asserted-by":"publisher","DOI":"10.1021\/om00021a037"},{"key":"ref27\/cit27h","doi-asserted-by":"publisher","DOI":"10.1021\/om9509711"},{"key":"ref27\/cit27i","doi-asserted-by":"publisher","DOI":"10.1021\/om970054q"},{"key":"ref27\/cit27j","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2005.04.036"},{"key":"ref27\/cit27k","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200600241"},{"key":"ref27\/cit27l","doi-asserted-by":"publisher","DOI":"10.1021\/ja075547t"},{"key":"ref27\/cit27m","doi-asserted-by":"publisher","DOI":"10.1021\/om900018y"},{"key":"ref27\/cit27n","doi-asserted-by":"publisher","DOI":"10.1021\/om200622q"},{"key":"ref27\/cit27o","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201501843"},{"key":"ref28\/cit28a","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201000037"},{"key":"ref28\/cit28b","doi-asserted-by":"publisher","DOI":"10.1055\/s-0036-1588540"},{"key":"ref29\/cit29a","doi-asserted-by":"publisher","DOI":"10.1021\/ar00010a002"},{"key":"ref29\/cit29b","doi-asserted-by":"publisher","DOI":"10.1080\/08893110310001621772"},{"key":"ref29\/cit29c","doi-asserted-by":"publisher","DOI":"10.1080\/0889311X.2012.674945"},{"key":"ref30\/cit30a","doi-asserted-by":"publisher","DOI":"10.1021\/ja00116a020"},{"key":"ref30\/cit30b","doi-asserted-by":"publisher","DOI":"10.1021\/om00011a061"},{"key":"ref30\/cit30c","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)00527-1"},{"key":"ref30\/cit30d","doi-asserted-by":"publisher","DOI":"10.1039\/b106456h"},{"key":"ref30\/cit30h","doi-asserted-by":"publisher","DOI":"10.1039\/b201647h"},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1021\/ja102262v"},{"key":"ref32\/cit32","doi-asserted-by":"publisher","DOI":"10.1002\/cjoc.202000019"},{"key":"ref33\/cit33","doi-asserted-by":"publisher","DOI":"10.1016\/S0277-5387(00)84091-7"},{"key":"ref34\/cit34a","doi-asserted-by":"publisher","DOI":"10.1002\/hlca.19920750702"},{"key":"ref34\/cit34b","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(98)00199-9"},{"key":"ref34\/cit34c","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20000901)39:17<2980::AID-ANIE2980>3.0.CO;2-#"},{"key":"ref34\/cit34d","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202005719"},{"key":"ref35\/cit35a","doi-asserted-by":"publisher","DOI":"10.1021\/ja3075049"},{"key":"ref35\/cit35b","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c06614"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.2c03614","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.2c03614","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,4,28]],"date-time":"2023-04-28T00:30:46Z","timestamp":1682641846000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.2c03614"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,5,3]]},"references-count":127,"journal-issue":{"issue":"19","published-print":{"date-parts":[[2022,5,18]]}},"alternative-id":["10.1021\/jacs.2c03614"],"URL":"https:\/\/doi.org\/10.1021\/jacs.2c03614","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,5,3]]}}}