{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T05:54:44Z","timestamp":1792130084055,"version":"4.4.0"},"reference-count":94,"publisher":"American Chemical Society (ACS)","issue":"41","license":[{"start":{"date-parts":[[2022,10,5]],"date-time":"2022-10-05T00:00:00Z","timestamp":1664928000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2022,10,5]],"date-time":"2022-10-05T00:00:00Z","timestamp":1664928000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2022,10,5]],"date-time":"2022-10-05T00:00:00Z","timestamp":1664928000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/100000082","name":"Division of Graduate Education","doi-asserted-by":"publisher","award":["DGE-2039656"],"award-info":[{"award-number":["DGE-2039656"]}],"id":[{"id":"10.13039\/100000082","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000057","name":"National Institute of General Medical Sciences","doi-asserted-by":"publisher","award":["F32GM139261"],"award-info":[{"award-number":["F32GM139261"]}],"id":[{"id":"10.13039\/100000057","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000057","name":"National Institute of General Medical Sciences","doi-asserted-by":"publisher","award":["R35 GM134893"],"award-info":[{"award-number":["R35 GM134893"]}],"id":[{"id":"10.13039\/100000057","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000057","name":"National Institute of General Medical Sciences","doi-asserted-by":"publisher","award":["R35 GM136271"],"award-info":[{"award-number":["R35 GM136271"]}],"id":[{"id":"10.13039\/100000057","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2022,10,19]]},"DOI":"10.1021\/jacs.2c07099","type":"journal-article","created":{"date-parts":[[2022,10,5]],"date-time":"2022-10-05T15:03:35Z","timestamp":1664982215000},"page":"18948-18958","source":"Crossref","is-referenced-by-count":39,"title":["Noncovalent Stabilization of Radical Intermediates in the Enantioselective Hydroamination of Alkenes with Sulfonamides"],"prefix":"10.1021","volume":"144","author":[{"given":"Eve Y.","family":"Xu","sequence":"first","affiliation":[{"name":"Department of Chemistry, Princeton University, Princeton, New Jersey 08544, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9648-5986","authenticated-orcid":true,"given":"Jacob","family":"Werth","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Utah, Salt Lake City, Utah 84112, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Casey B.","family":"Roos","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Princeton University, Princeton, New Jersey 08544, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andrew J.","family":"Bendelsmith","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Princeton University, Princeton, New Jersey 08544, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5746-8830","authenticated-orcid":true,"given":"Matthew S.","family":"Sigman","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Utah, Salt Lake City, Utah 84112, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1044-4900","authenticated-orcid":true,"given":"Robert R.","family":"Knowles","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Princeton University, Princeton, New Jersey 08544, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2022,10,5]]},"reference":[{"key":"ref1\/cit1","volume-title":"Comprehensive Asymmetric Catalysis","author":"Jacobsen E. N.","year":"1999"},{"key":"ref2\/cit2a","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.1006402107"},{"key":"ref2\/cit2b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201600547"},{"key":"ref2\/cit2c","doi-asserted-by":"publisher","DOI":"10.1039\/C6SC04157D"},{"key":"ref2\/cit2d","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.6b00613"},{"key":"ref2\/cit2e","doi-asserted-by":"publisher","DOI":"10.1038\/nature21701"},{"key":"ref3\/cit3a","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-020-00561-6"},{"key":"ref3\/cit3b","doi-asserted-by":"publisher","DOI":"10.1038\/nature25175"},{"key":"ref4\/cit4a","doi-asserted-by":"publisher","DOI":"10.1021\/jo00091a007"},{"key":"ref4\/cit4b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200461222"},{"key":"ref4\/cit4c","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201204573"},{"key":"ref4\/cit4d","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b03243"},{"key":"ref4\/cit4e","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b09329"},{"key":"ref4\/cit4f","doi-asserted-by":"publisher","DOI":"10.1038\/nature20569"},{"key":"ref4\/cit4g","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201804445"},{"key":"ref4\/cit4h","doi-asserted-by":"publisher","DOI":"10.1126\/science.aar6376"},{"key":"ref4\/cit4i","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b00286"},{"key":"ref5\/cit5a","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201710070"},{"key":"ref5\/cit5b","doi-asserted-by":"publisher","DOI":"10.1039\/C1CS15165G"},{"key":"ref5\/cit5c","doi-asserted-by":"publisher","DOI":"10.1039\/D1SC01618K"},{"key":"ref6\/cit6a","doi-asserted-by":"publisher","DOI":"10.1126\/science.1124022"},{"key":"ref6\/cit6b","doi-asserted-by":"publisher","DOI":"10.1063\/1.2784558"},{"key":"ref6\/cit6c","doi-asserted-by":"publisher","DOI":"10.1021\/ja206890y"},{"key":"ref6\/cit6d","doi-asserted-by":"publisher","DOI":"10.1039\/C6CP03671F"},{"key":"ref6\/cit6e","doi-asserted-by":"publisher","DOI":"10.1002\/1439-7641(20020916)3:9<789::AID-CPHC789>3.0.CO;2-Z"},{"key":"ref7\/cit7a","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201411409"},{"key":"ref7\/cit7b","doi-asserted-by":"publisher","DOI":"10.1039\/C9OB01609K"},{"key":"ref7\/cit7c","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.1c00467"},{"key":"ref8\/cit8a","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c09668"},{"key":"ref8\/cit8b","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b11658"},{"key":"ref9\/cit9a","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.6b00272"},{"key":"ref9\/cit9b","doi-asserted-by":"publisher","DOI":"10.1007\/s41061-016-0030-6"},{"key":"ref9\/cit9c","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.1c00374"},{"key":"ref10\/cit10a","doi-asserted-by":"publisher","DOI":"10.1146\/annurev.physchem.55.091602.094446"},{"key":"ref10\/cit10b","doi-asserted-by":"publisher","DOI":"10.1021\/cr200177j"},{"key":"ref10\/cit10c","doi-asserted-by":"publisher","DOI":"10.1021\/ic100143s"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1021\/ja4100595"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b13616"},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c01332"},{"key":"ref14\/cit14a","doi-asserted-by":"publisher","DOI":"10.1021\/ja407410b"},{"key":"ref14\/cit14b","doi-asserted-by":"publisher","DOI":"10.1126\/science.1261043"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b11144"},{"key":"ref16\/cit16a","doi-asserted-by":"publisher","DOI":"10.1016\/j.jmr.2013.04.011"},{"key":"ref16\/cit16b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.8b00391"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b08398"},{"key":"ref18\/cit18a","doi-asserted-by":"publisher","DOI":"10.1038\/nature19811"},{"key":"ref18\/cit18b","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b09109"},{"key":"ref18\/cit18c","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b06834"},{"key":"ref19\/cit19a","doi-asserted-by":"publisher","DOI":"10.1021\/ja01176a030"},{"key":"ref19\/cit19b","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(00)00492-0"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200705241"},{"key":"ref21\/cit21a","doi-asserted-by":"publisher","DOI":"10.1039\/C6CS00475J"},{"key":"ref21\/cit21b","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b08276"},{"key":"ref22\/cit22","unstructured":"MacroModel, ver. 11.8; Schr\u00f6dinger,\nLLC: New York, NY, 2017."},{"key":"ref23\/cit23a","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.37.785"},{"key":"ref23\/cit23b","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevA.38.3098"},{"key":"ref23\/cit23c","doi-asserted-by":"publisher","DOI":"10.1063\/1.464913"},{"key":"ref24\/cit24a","doi-asserted-by":"publisher","DOI":"10.1063\/1.1677527"},{"key":"ref24\/cit24b","doi-asserted-by":"publisher","DOI":"10.1007\/BF00533485"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1007\/s00214-007-0310-x"},{"key":"ref26\/cit26a","doi-asserted-by":"publisher","DOI":"10.1063\/1.438980"},{"key":"ref26\/cit26b","doi-asserted-by":"publisher","DOI":"10.1063\/1.438955"},{"key":"ref26\/cit26c","doi-asserted-by":"publisher","DOI":"10.1063\/1.447079"},{"key":"ref26\/cit26d","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.540040303"},{"key":"ref27\/cit27a","doi-asserted-by":"publisher","DOI":"10.1021\/jp9716997"},{"key":"ref27\/cit27b","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.10189"},{"key":"ref28\/cit28","unstructured":"Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Petersson, G. A.; Nakatsuji, H.; Li, X.; Caricato, M.; Marenich, A. V.; Bloino, J.; Janesko, B. G.; Gomperts, R.; Mennucci, B.; Hratchian, H. P.; Ortiz, J. V.; Izmaylov, A. F.; Sonnenberg, J. L.; Williams-Young, D., Ding, F.; Lipparini, F.; Egidi, F.; Goings, J.; Peng, B.; Petrone, A.; Henderson, T.; Ranasinghe, D.; Zakrzewski, V. G.; Gao, J.; Rega, N.; Zheng, G.; Liang, W.; Hada, M.; Ehara, M.; Toyota, K.; Fukuda, R.; Hasegawa, J.; Ishida, M.; Nakajima, T.; Honda, Y.; Kitao, O.; Nakai, H.; Vreven, T.; Throssell, K.; Montgomery, J. A., Jr., Peralta, J. E.; Ogliaro, F.; Bearpark, M. J.; Heyd, J. J.; Brothers, E. N.; Kudin, K. N.; Staroverov, V. N.; Keith, T. A.; Kobayashi, R.; Normand, J.; Raghavachari, K.; Rendell, A. P.; Burant, J. C.; Iyengar, S. S.; Tomasi, J.; Cossi, M.; Millam, J. M.; Klene, M.; Adamo, C.; Cammi, R.; Ochterski, J. W.; Martin, R. L.; Morokuma, K.; Farkas, O.; Foresman, J. B.; Fox, D. J. Gaussian 16, Revision A.03; Gaussian, Inc.: Wallingford, CT, 2016."},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.12688\/f1000research.22758.1"},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1002\/poc.1606"},{"key":"ref32\/cit32","doi-asserted-by":"publisher","DOI":"10.1021\/ar700111a"},{"key":"ref33\/cit33","doi-asserted-by":"publisher","DOI":"10.1021\/ja3122137"},{"key":"ref34\/cit34","doi-asserted-by":"publisher","DOI":"10.1021\/jp3084309"},{"key":"ref35\/cit35","doi-asserted-by":"publisher","DOI":"10.1063\/5.0050993"},{"key":"ref36\/cit36a","doi-asserted-by":"publisher","DOI":"10.1021\/ja100936w"},{"key":"ref36\/cit36b","doi-asserted-by":"publisher","DOI":"10.1021\/ct100641a"},{"key":"ref37\/cit37","doi-asserted-by":"publisher","DOI":"10.1021\/cr5001496"},{"key":"ref38\/cit38","doi-asserted-by":"publisher","DOI":"10.1021\/cr100072x"},{"key":"ref39\/cit39","doi-asserted-by":"publisher","DOI":"10.1039\/b313104a"},{"key":"ref40\/cit40","doi-asserted-by":"publisher","DOI":"10.1007\/s00894-014-2136-5"},{"key":"ref41\/cit41a","doi-asserted-by":"publisher","DOI":"10.1039\/b818033b"},{"key":"ref41\/cit41b","doi-asserted-by":"publisher","DOI":"10.1021\/ja404504m"},{"key":"ref41\/cit41c","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC01460H"},{"key":"ref42\/cit42","doi-asserted-by":"publisher","DOI":"10.1039\/C4CP05536E"},{"key":"ref43\/cit43","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201007560"},{"key":"ref44\/cit44","unstructured":"Legault, C. Y. CYLview, ver. 1.0b; Universit\u00e9 de Sherbrooke: Sherbrooke, Quebec, 2009. http:\/\/www.cylview.org (accessed 2021-10-20)."},{"key":"ref45\/cit45","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.7b00739"},{"key":"ref46\/cit46","doi-asserted-by":"publisher","DOI":"10.1039\/b508541a"},{"key":"ref47\/cit47","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201707644"},{"key":"ref47\/cit47b","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c01637"},{"key":"ref48\/cit48","doi-asserted-by":"publisher","DOI":"10.1021\/ar3001124"},{"key":"ref49\/cit49a","first-page":"63","volume":"2","author":"Verloop A.","year":"1977","journal-title":"Pharmacochem Libr."},{"key":"ref49\/cit49b","first-page":"97","volume":"10","author":"Verloop A.","year":"1987","journal-title":"Pharmacochem Libr."},{"key":"ref49\/cit49c","doi-asserted-by":"publisher","DOI":"10.1039\/C7SC04679K"},{"key":"ref50\/cit50","doi-asserted-by":"publisher","DOI":"10.1021\/ci0001031"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.2c07099","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.2c07099","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,4,26]],"date-time":"2023-04-26T21:12:42Z","timestamp":1682543562000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.2c07099"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,10,5]]},"references-count":94,"journal-issue":{"issue":"41","published-print":{"date-parts":[[2022,10,19]]}},"alternative-id":["10.1021\/jacs.2c07099"],"URL":"https:\/\/doi.org\/10.1021\/jacs.2c07099","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,10,5]]}}}